Chemistry/physics-molar heat capacity?

In summary, the question is asking for the molar heat capacity of cobalt and gives information about the heat added and temperature change. Using the equation Q = n x c x T, the value of c is calculated to be 57.4 J mol-1 K-1. While the correct answer is D, it is noted that the change in temperature should not affect the calculation as it remains the same whether in Celsius or Kelvin.
  • #1
monarchus
Chemistry/physics--molar heat capacity?

Homework Statement



When 5.00 J of heat are added to 1.50 g of cobalt, its temperature rises by 3.42 degree celsius. What is the molar heat capacity o cobalt in J mol-1 K-1?

A) 0.710
B) 0.875
C) 2.30
D) 57.4


P.S. if your answer is A, please explain why you want to add 273 to the change of the temperature to make it Kelvin. Wasn't change of temperature is the same no matter it is in the form of degree Celsius or Kelvin?

thank you.


Homework Equations



Q = n x c x T

Q = heat evolved
n = number of moles
c = molar heat capacity
T = change in temperature



The Attempt at a Solution



5 = (1.5 / 58.9 ) x c x 3.42

c = 57.4



 
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  • #2


D is the correct answer. You are right, delta T is the same regardless of whether you use Kelvin or Celsius scale.
 
  • #3




I would like to first clarify the question and make sure we are using the correct units. The unit for molar heat capacity is J mol^-1 K^-1, so we need to make sure all the values are in the correct units.

In this case, the heat added (Q) is given in Joules (J), the mass (m) is given in grams (g), and the change in temperature (T) is given in degrees Celsius (°C). However, the units for molar heat capacity (c) are in Kelvin (K). This is why we need to convert the change in temperature from degrees Celsius to Kelvin by adding 273.15 (not just 273).

The reason for this is because the Kelvin scale is an absolute temperature scale where 0 K represents the lowest possible temperature (absolute zero). On the other hand, the Celsius scale is a relative temperature scale where 0°C represents the freezing point of water and 100°C represents the boiling point of water. Therefore, we need to use Kelvin in this equation to get the correct value for the molar heat capacity.

Now, to solve for the molar heat capacity, we can rearrange the equation to isolate c:

c = Q / (n x T)

We have all the values except for n (number of moles). To find n, we can use the molar mass of cobalt, which is 58.9 g mol^-1.

n = m / M = 1.50 g / 58.9 g mol^-1 = 0.0255 mol

Substituting all the values into the equation, we get:

c = 5 J / (0.0255 mol x 3.42 K) = 57.4 J mol^-1 K^-1

Therefore, the correct answer is D) 57.4.

In summary, as scientists, we must pay attention to the units used in our calculations and make sure they are consistent to get the correct results. In this case, we needed to convert the change in temperature from degrees Celsius to Kelvin to use the correct units for the molar heat capacity.
 

Related to Chemistry/physics-molar heat capacity?

1. What is molar heat capacity?

Molar heat capacity is a measure of how much heat energy is required to raise the temperature of one mole of a substance by one degree Celsius.

2. How is molar heat capacity different from specific heat capacity?

Molar heat capacity is the amount of heat energy required to raise the temperature of one mole of a substance, while specific heat capacity is the amount of heat energy required to raise the temperature of one gram of a substance. Molar heat capacity takes into account the molar mass of the substance, while specific heat capacity does not.

3. What factors affect the molar heat capacity of a substance?

The molar heat capacity of a substance is affected by its molecular structure, the number of atoms present, and the type of chemical bonds within the substance. It can also be influenced by temperature and pressure.

4. How is molar heat capacity measured?

Molar heat capacity is typically measured through experiments using a calorimeter. This involves measuring the temperature change of a substance when a known amount of heat energy is added to it. The molar heat capacity can then be calculated using the formula Q/(nΔT), where Q is the heat energy, n is the number of moles, and ΔT is the change in temperature.

5. Why is molar heat capacity important in chemistry and physics?

Molar heat capacity is important because it helps us understand how different substances behave when heat energy is added or removed. It also allows us to make predictions about the behavior of substances under different conditions, which is crucial in fields such as thermodynamics and materials science.

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