Why should the quantum number m be less than equal to l.

In summary, the article discusses the solution of the angular part of the wavefunction for hydrogen. It explains the use of a substitution and the assumption of a polynomial form for Y(y) in order to arrive at a recursion formula. The article then states that for the series to converge, a specific condition must be met, which involves the maximum value of n and the values of m and l. The author also mentions that this condition can be easily understood from a physical perspective. A question is asked about the possibility of a projection of a vector being larger than the magnitude of the vector, but this is not addressed in the article.
  • #1
sanalsprasad
6
0
I was reading the following article regarding solution of wavefunction of hydrogen :
http://skisickness.com/2009/11/22/

To solve the angular part they gave the substitution of [itex] y = \sin \theta [/itex] and then assumed that Y is a polynomial i.e. [itex] Y(y) = \sum b_n x^n [/itex] and then arrived at the recursion formula :
[itex] b_{n-2} = - \frac{n^2 - m^2}{l(l+1) - (n-1)(n-2) }b_{n} [/itex] , where [itex]l[/itex] is maximum value of [itex]n[/itex] for which [itex]b_n[/itex] is non-zero.

Then they say that :
" There must be a minimum value of n; otherwise, the series will diverge at y=0. Given l, for the series to converge, it is necessary that |m|=l-2k, with k greater than or equal to zero and less than or equal to l/2. For even or odd l, this series gives l+1 solutions. This solution gives the eigenfunctions with both odd or both even m and l. "

I did not understand why the series converges only for this particular condition. Is it something to do with starting with [itex]b_l[/itex] and then finding [itex]b_{l-2}[/itex] and then [itex]b_{l-4}[/itex] and so on in terms of [itex]b_l[/itex].
Thanks for help!
 
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  • #2
I don't care to post the mathematical reasoning because the physical reason is easy to understand.

How can a projection of a vector on any arbitrary axis (angular momentum in the case) be larger than the magnitude of the vector?
 
  • #3
sanalsprasad said:
I did not understand why the series converges only for this particular condition.

When you use that recursive formula to generate polynomials (so called Legendre polynomials), every term in the resulting polynomial has coefficient larger than 1, and the coefficients only grow when going to higher-power terms. There's no way how that kind of a series could converge unless it terminates at some point. And the series terminates only if m ≤ l (with that condition, all coefficients are zero after some term).
 

FAQ: Why should the quantum number m be less than equal to l.

1. Why is the quantum number m always less than or equal to l?

The quantum number m represents the magnetic quantum number, which describes the orientation of an electron's orbital in a specific energy level. The value of m can range from -l to +l, where l is the orbital angular momentum quantum number. This means that m must always be less than or equal to l, as it is a subset of the possible values of l.

2. What happens if the value of m is greater than l?

If the value of m is greater than l, it would imply that the electron's orbital is in a higher energy state than the one described by the given l value. This violates the laws of quantum mechanics and is not physically possible.

3. Can the value of m be negative?

Yes, the value of m can be negative. As mentioned earlier, m can range from -l to +l, so it can take on negative values for certain values of l. This corresponds to the different orientations of the electron's orbital in relation to an external magnetic field.

4. How does the value of m affect the shape of an electron's orbital?

The value of m does not directly affect the shape of an electron's orbital. This is determined by the value of the principal quantum number, n, which describes the size of the orbital. However, the orientation of the orbital in space is influenced by the value of m, as different values of m correspond to different orbital orientations.

5. Why is it important for m to have a maximum value of l?

The maximum value of m being equal to l is necessary for the proper classification and organization of electron orbitals. It allows for a systematic way of describing the different orientations and energies of orbitals, which is crucial for understanding the behavior of electrons in atoms and molecules. Additionally, this relationship between m and l is a fundamental principle of quantum mechanics that has been experimentally verified.

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