How Does the London van der Waals Force Relate to the Casimir Effect?

In summary, the London van der Waals force is approximatly given by F=-c *a^-7 where a is the distance between two neutral atoms and c is something like this: C=-23*hbar*c/4pi*(alpha1*alpha2) where alpha1 and alpha2 =(epsilon-1)/(4pi*N) and N is the atom number density and epsilon the permittivity.
  • #1
Kruger
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The London van der Waals force is approximatly given by F=-c *a^-7 where a is the distance between two neutral atoms and c is something like this:

C=-23*hbar*c/4pi*(alpha1*alpha2)

where alpha1 and alpha2 =(epsilon-1)/(4pi*N)

and N is the atom number density and epsilon the permittivity.

--> Question 1: Does that mean if I have a body with 10^30 atoms the moledule number density is 10^30?

Now from the force between neutral atoms we can get to the Casimir-force. We can then just calclulate how much one atom of Plate A is attracted by the atoms of the other plates. Doing so with all atoms on Plate A we can sum over all the resulting forces and have the Casimir-Force.

Question 2: is this correct?
 
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  • #2
Kruger said:
The London van der Waals force is approximatly given by F=-c *a^-7 where a is the distance between two neutral atoms and c is something like this:
C=-23*hbar*c/4pi*(alpha1*alpha2)
where alpha1 and alpha2 =(epsilon-1)/(4pi*N)
and N is the atom number density and epsilon the permittivity.
--> Question 1: Does that mean if I have a body with 10^30 atoms the moledule number density is 10^30?
Now from the force between neutral atoms we can get to the Casimir-force.
The molecule number density cannot be dimensionless, so you have to divide 10^30 by the volume of the body.
 
  • #3
The Casimir force is related but not identical to the van der Waals force, a fact which was first explicitly demonstrated by E. M. Lif****z and later J. Schwinger in the 1950's. In particular, the Casimir force is strongly dependent on the geometry of the system and is actually repulsive between two metal hemispheres. This revelation spoiled Schwinger's attempt to explain sonoluminescence using the Casimir force.


Lif****z's Paper:
E. M. Lif****z, Sov. Phys. JETP 2, 73, 1956

A nice experiment and good discussion:
http://prola.aps.org/abstract/PRL/v78/i1/p5_1

Edit: Ha! This is somewhat absurd, I can't write Lif****z's name because it has **** in it.
 
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FAQ: How Does the London van der Waals Force Relate to the Casimir Effect?

What is London van der Waals force?

London van der Waals force, also known as dispersion force, is a type of intermolecular force that exists between all atoms and molecules. It is caused by temporary fluctuations in the electron density of a molecule, resulting in a temporary dipole moment and the attraction of nearby molecules.

How does London van der Waals force differ from other intermolecular forces?

London van der Waals force is the weakest type of intermolecular force and only exists between non-polar molecules. In contrast, other intermolecular forces such as hydrogen bonding and dipole-dipole interactions can exist between polar molecules.

What is the significance of London van der Waals force in chemistry and biology?

London van der Waals force plays a crucial role in determining the physical properties of substances, such as boiling point, melting point, and viscosity. In biology, it is responsible for the binding of molecules such as hormones and neurotransmitters to their receptors.

How is the strength of London van der Waals force affected by molecular size and shape?

The strength of London van der Waals force increases with increasing molecular size, as there are more electrons to contribute to the temporary dipoles. The shape of a molecule also affects the strength, with longer, more linear molecules experiencing stronger London van der Waals forces.

Can London van der Waals force be manipulated or controlled in any way?

While London van der Waals force cannot be directly manipulated, it can be affected by changing the temperature or pressure of a system. Additionally, adding functional groups or substituents to a molecule can alter its shape and therefore the strength of London van der Waals force between molecules.

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