A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.
Homework Statement
The solubility of a gas in water decreases as temperature
increases, and increases as temperature decreases. Using
the kinetic molecular theory, explain why this is so.
I would like an opinion please on my answer below. Is it a sufficient explanation?
THANKS! :smile...
Homework Statement
6.0 cm^3 of a gaseous hydrocarbon was sparked with 34.5 cm^3 of oxygen. The volume of the gaseous products after cooling to room temperature was 22.5 cm^3. The volume was reduced to 4.5 cm^3 on passing the gases through aqueous potassium hydroxide. What is the molecular...
Hello sir and madam, I would be grateful if you can help me solve this question.
6.0 cm^3 of a gaseous hydrocarbon was sparked with 34.5 cm^3 of oxygen. The volume of the gaseous products after cooling to room temperature was 22.5 cm^3. The volume was reduced to 4.5 cm^3 on passing the gases...
This animation is amazing! It shows molecular interactions between DNA and other molecules.
http://uk.youtube.com/watch?v=4PKjF7OumYo&feature=related
How do you think they were able to get the information to create this animation? The molecular interactions could be mathematically...
Quote from Organic Chemistry, L.G. Wade, Jr.:
"Not all molecular vibrations absorb IR radiation."
"One of the component of an electromagnetic wave is E field. This field alternately stretches and compresses a polar bond."
"If this alternate stretching compressing of the bond occurs at the...
Hello,
If a magnetic field aligns the electron or nuclear spins can that have a macro effect of causing torque? So for example if we had a rod and we fixed one end but allowed it to freely rotate and then aligned electron or nuclear spins would that cause the rod to rotate?
Thanks,
Xerxes73
Does Maxwell Boltzmann hold for liquids? In the case of gases it does quite well for calculating the velocity distribution given a temperature. However, when the molecules are closer together in the case of liquids, how do the van der waals force and others effect the velocity distribution...
This may be obvious to some, but have you ever looked at yourself and went, "woah"? Self replicating strands of molecules have come an EXTREMELY long way.
Does anyone wonder, "why?" Its like there's some form of driving force. (I don't mean evolution, that is the "how") I mean, why do these...
Homework Statement
I just purified alkaline phosphatase, and my calculated molecular weight is 100000 g/mol, while literature value is 89000 g/mol. According to how others in my lab did calculations, my calculations are performed correctly, so I am left to explain why my purification is...
Helium has a molecular diffusivity three times greater than that for Argon. If a tank of water is charged with 0.5 atm of He and 0.5 atm of Ar and then allowed to stand in open contact wiht air, what percent of the Ar will have been lost when 10 percent of the He has been lost?
I was having a glass of wine over candlelight and I noticed that the liquid wax was completely transparent but turned opaque when when the wax solidified. Why does this happen? Clearly, when the molecules reorganize during the freezing phase transition they begin to interact with the light. What...
I've read info on it's operation but some questions are still unanswered. This is concerning reflux stills that create the reflux by condensing rising vapor at the top of the still.
How does the still work on a molecular level?
Homework Statement
Calculate the flux of oxygen across a square centimeter membrane [2\mu, or 2x10 ^{-6}m thick if the concentration on the right hand side of the membrane is 4mL/L and on the left side is 2mL/L.
Homework Equations
fick's first law of diffusion
Flux = dC/dx = D[C2-C1] where...
I'm studying astronomy and I'm have these problems to solve, but there are a few things I don't really understand, hopefully someone can explain these things to me.
1. Why are spectra of molecules more complex than spectra of atoms? Is it because molecules can be excited in different ways...
I have seen the frequency of the electron in the ground state of the hydrogen atom as 6.58 x 10^15 Hz, however I have never been able to find the ground state frequency of the electron in the hydrogen molecular ion (H+). The equilibrium separation of the two protons is given as twice the Bohr...
Hey all, I'm looking for some suggestions on topics concerning Molecular Simulation which I can research. I've been tasked with giving a talk and writing a report on one specific topic of this field but I'm unsure what to specialise in. Any and all advise and suggestions would be appreciated!
Hi everyone,
I came back to get some feedback from everyone. I am close to the time when my university requires that I choose a certain Subject POST or degree as some know it for my future three years in undergrad.
Now I always loved Molecular Biology/Biotechnology since they are very much the...
[SOLVED] molecular orbital wavefunctions
http://img255.imageshack.us/img255/7012/37626561fb6.jpg
starting with
Sz(total) = Sz1 + Sz2
Sz(alpha) = +(1/2)hbar(alpha)
Sz(beta) = -(1/2)hbar(beta)
I first found the determinant and then simplified
psi =...
Homework Statement
0.1 dm^3 of a gaseous hydrocarbon may require 0.45 dm^3 of oxygen for a complete combustion to give 300 cm^3 of Carbon dioxide. All volumes are measured in the same environment. Calculate the molecular formula of the hydrocarbon.
The Attempt at a Solution
i tried...
Molecular visualization software??
Hello,
I have recently started working in the field of biophysics and I need to produce some visualizations (pictures and movies) for the molecular coordinates that are produced by my simulation code. I am looking for visualization solutions for 1D, 2D...
I have one question about wave functions and molecular orbitals (MO). In the computational quantum chemistry scientists often use Linear Combination Atomic Orbitals (LCAO) to construct MO.
\varphi_{i\lambda\alpha}(\vec{r})=
\sum\limits_{p=1}^{N}\chi_{p\lambda\alpha}(\vec{r})
C_{i\lambda p}...
I have a possibility to simulate Molecular dynamics (MD). I want to find someone who need it. I propose to simulate ab initio quantum mechanical molecular dynamics (MD) using pseudopotentials and a plane wave basis set. The interaction between ions and electrons is described using ultrasoft...
when some molecules in a liquid gain enough energy to overcome attractive forces by surrounding molecules, they escape from the liquid surface. but when the vapor pressure becomes equal to atmospheric pressure, boiling is said to take place and all the molecules seem to gain sufficient energy...
Hi I was wondering if anyone can tell me how to find the bond order from a molecular orbital diagram.
For example i found one on this website
attached...
"Comparison of the above energy level diagram wit hthat for nitrogen - you can see that the 2sg level lies lower than pu. Here...
[SOLVED] molecular orbital model
I have a few quick questions:
consider the structure of glycine
a) indicate the hybridizations at each N and C atom in the molecule?
I got sp3, sp3, and sp2
I don't have a problem with that question
b) what is the total number of bonds in the...
http://www.jmeagle.com/plastic-pipe/pvc-pipe/ultra%20blue.html
This is a product that I helped to develop. :approve: The expansion process is terribly tricky but we finally nailed it!
It always gives me a thrill to see these things hit the market.
What is the difference between gram molecular mass and the molar mass?
My book says that the gram molecular mass of oxygen is 32 grams and the molar mass is 16. Since a mole is equal to the gram molecular mass shouldn't they be the same?
This problem was proposed to us by our Chemistry professor. Consider a sample of a hydrocarbon at 0.959atm and 298K. Upon combusting the entire sample in oxygen, you collect a mixture of gaseous carbon dioxide and water vapor at 1.51atm and 375K. This mixture has a density of 1.391 g/L and...
Homework Statement
Start with the kinetic theory formula for the molecular condensation flux, \Phi_cond = 1/4 n_v*c_v, where n_v is the number density of vapor molecules just above a liquid water surface and c_v is the mean speed of the vapor molecules. Derive an expression for calculating...
Hey!
This is for a 4th year undergrad project in Applied Molec Bio.
I need an idea for a molecular biology-based, laboratory research plan.
It needs to be an "original" idea but I'm having trouble of picking one... I will not actually be performing any experiments.
It will contain...
Advanced Molecular Biology - HELP NEEDED!
I am currently enrolled in an advanced Molecular Biology course and we have been assigned the task of creating a novel (not yet proved or studied) hypothesis regarding something related to the course. Additionally, we are required to provide an...
Not sure if this is the right place for this.The new nanotechology articles are fascinating.
They said it is like a switch that is able to turn on and off without altering its shape.
I was also reading that they had solved the puzzles of the mobius strip. are these discoveries related...
"A compound contains only carbon, hydrogen, and oxygen. Combustion of 10.68 mg of the compound yields 16.01 mg CO2 and 4.37 mg H2O. The molar mass of the compound is 176.1 g/mol. What are the empirical and molecular formulas of the compound."
I saw an earlier post but it wasn't solved yet...
Hi,
I have a question regarding the contribution of some molecular orbitals (e.g HOMO, LUMO) to the total density of states of a two-probe system.
How exactly are the contributions of the MO ( that look similar to the DOS plots ) calculated, do they have something to do with the local...
What happens at a "molecular" level?
Supose we titrate Acetic acid with Sodium hydroxide. When acetate ion begins his hydrolyzation?
-Immediately after titration begins?
or
only when all initial acetic acid is ionizaed and titrated?
Homework Statement
Show that the molecular speed probability distribution is normalizedHomework Equations
Molecular speed probability distribution
P(C)dC = 4pi[m/2pikt]3/2exp[-mC2/2kT]C2dC
The Attempt at a Solution
I have tried many steps but i keep getting stuck. I tried using the same metods...
Homework Statement
The standard Gibb's free energy for the reaction N2+3H2<--->2NH3 is -33.0 KJ at 298 K. Everything is a gas. Calculate Kp for this reaction.
Homework Equations
I have in my notes that Keq=e^(-Delta G/RT) where R is the constant 0.008314 KJ/K. I also have a formula...
Homework Statement
An ideal gas is in a container at temperture 300 degrees. What fraction of its moelcules will have speeds in the range 1.95v and 2.05v where v is the most probable molecular speed?
Assume dN is constant in the range around 2v
Homework Equations
Maxwell velocity...
hi
i'm a pharmacy student and need ur help please
i have an assignment with the title(diagnosis of viral infections using molecular biology techniques)
can u please give me useful websites on the subject
thanks a heap :smile:
1. Determine the shapes of Br2 (2 Bromine atoms) and HBr. Which is more polar and why?
2. No equations.
3. Okay, I know that Br2 and HBr molecule shapes are linear (I know how to draw them) but I do not get how to find which one is more polar. :confused:
I don't think the problems I'm going to post are very difficult, but I'm totally clueless regarding chemistry, so they're pretty difficult for me ^^;; I also have a lot of questions to ask, so I hope you don't mind my sticking them all into one topic. I'm looking forward to your help. You don't...
I have looked for the answer but I haven't found it. Why does a fluid ends up being pushed upward in the presence of a higher density fluid? How is it explained at the molecular level?
According to molecular orbital theory, which of the following species is the most likely to exist?
a) H_{2}^{-2}
b) He_{2}
c) Li_{2}
d) Li_{2}^{-2}
e) Be_{2}
I think the answer is c), due to it having a bond order of 1, but I just wanted to make sure.
So, I've read that cutting is essentially where the edge of the knife (or whatever cutting instrument) applies enough force to overcome the intermolecular forces in the object. A more dense object will have greater molecular forces, hence more difficult to cut (in the conventional cutting sense...