Spontaneous emission

Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light we see all around us; it is so ubiquitous that there are many names given to what is essentially the same process. If atoms (or molecules) are excited by some means other than heating, the spontaneous emission is called luminescence. For example, fireflies are luminescent. And there are different forms of luminescence depending on how excited atoms are produced (electroluminescence, chemiluminescence etc.). If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission.
Spontaneous emission cannot be explained by classical electromagnetic theory and is fundamentally a quantum process. The first person to derive the rate of spontaneous emission accurately from first principles was Dirac in his quantum theory of radiation, the precursor to the theory which he later called quantum electrodynamics. Contemporary physicists, when asked to give a physical explanation for spontaneous emission, generally invoke the zero-point energy of the electromagnetic field. In 1963, the Jaynes–Cummings model was developed describing the system of a two-level atom interacting with a quantized field mode (i.e. the vacuum) within an optical cavity. It gave the nonintuitive prediction that the rate of spontaneous emission could be controlled depending on the boundary conditions of the surrounding vacuum field. These experiments gave rise to cavity quantum electrodynamics (CQED), the study of effects of mirrors and cavities on radiative corrections.

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