Calculating Expectation Value of Particle in Square Potential Well

In summary: If V is negative, then k is imaginary and the integral would be infinite. In summary, the particle is likely outside the potential well if its wavefunction has a positive value outside of the well, and imaginary if the wavefunction has a negative value outside of the well.
  • #1
cscott
782
1
I'm confused re a particle of energy E < V inside a square potential of width 'a' centered at x = 0 with depth V.

They give the wavefunction for outside the well as [tex]\Psi(x) = Ae^{k|x|}[/tex] for |x| > a/2

and [tex]k^2 = -\frac{2ME}{\hbar^2}[/tex] => [tex]k = i\frac{\sqrt{2ME}}{\hbar}[/tex] ?

I need the probability that the particle is outside the potential well. So I integrate [tex]\int{\Psi(x)\Psi^*(x)dx}[/tex] from a/2 to infinity if I take x to be positive and then multiply by 2 for symmetry?

But isn't [tex]\Psi(x)^*\Psi(x) = A[/tex]? So my integral is infinity but shouldn't it be 0?
 
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  • #2
cscott said:
I'm confused re a particle of energy E < V inside a square potential of width 'a' centered at x = 0 with depth V.

They give the wavefunction for outside the well as [tex]\Psi(x) = Ae^{k|x|}[/tex] for |x| > a/2

and [tex]k^2 = -\frac{2ME}{\hbar^2}[/tex]

I need the probability that the particle is outside the potential well. So I integrate [tex]\int{\Psi(x)\Psi^*(x)dx}[/tex] from 0 to infinity if I take x to be positive and then multiply by 2 for symmetry?

But isn't [tex]\Psi(x)^*\Psi(x) = A[/tex]? So my integral is infinity but shouldn't it be 0?
you must integrate from a/2 to infinity, not from 0.

Because the exponential is real then Psi Psi^* does not give a constant (that only happens for imaginary exponentials)
 
  • #3
Sorry I meant so say from a/2 to infinity.

But doesn't k have to have an i in it because k squared is negative?
 
  • #4
cscott said:
Sorry I meant so say from a/2 to infinity.

But doesn't k have to have an i in it because k squared is negative?

I am a bit confused by your choice of zero for the potential. You are doing a bound state, right? If you set V =0 outside of the well, then it means E < 0 (but E > -V where I am assuming V is a positive number). Then k is real.
 

FAQ: Calculating Expectation Value of Particle in Square Potential Well

How do you calculate the expectation value of a particle in a square potential well?

To calculate the expectation value of a particle in a square potential well, you need to use the formula:

Eavg = -aa Ψ*HΨ dx / -aa Ψ*Ψ dx

What is a square potential well?

A square potential well is a simplified model used in quantum mechanics to describe a particle trapped in a one-dimensional box with infinite potential walls on either side. It is a commonly used example to study quantum mechanical systems.

What is the significance of calculating the expectation value of a particle in a square potential well?

The expectation value of a particle in a square potential well is important because it gives us an average of the particle's energy in the given system. It can also provide information about the probability of finding the particle in certain energy states.

How does the width of the square potential well affect the expectation value?

The width of the square potential well can affect the expectation value by changing the energy levels of the particle. A wider well will have lower energy levels and a narrower well will have higher energy levels. This can be seen in the equation for the expectation value, where the limits of integration (-a and a) represent the width of the well.

Can the expectation value of a particle in a square potential well be negative?

No, the expectation value of a particle in a square potential well cannot be negative. This is because the expectation value represents the average energy of the particle, which cannot be negative. However, it is possible for the particle to have negative energy in certain energy states within the well.

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