How to get the prefactor for the Planck Distribution

In summary: B T)^{5/2} (2.612)In summary, to derive the energy density from the Bose-Einstein distribution, we need to first understand the concept of density of states for a Bose gas and then use the appropriate integral to calculate the energy density.
  • #1
arunma
927
4
So I have a question on the Planckian (from one of my PhD qualifier practice problems). I'm trying to derive the Planck distribution from the Bose-Einstein distribution, which is,

[tex]f(\epsilon) = \dfrac{1}{e^{\frac{\epsilon - \mu}{k_B T}} - 1}[/tex]

Now I know that I can set the chemical potential equal to zero, and let [tex]\epsilon = \hbar \omega = h \nu [/tex] to get,

[tex]f(\epsilon) = \dfrac{1}{e^{\frac{h \nu}{k_B T}} - 1}[/tex]

However, this is only the distribution function. There's some sort of prefactor that I need in order to turn it into an energy density. My question is: how do I derive this prefactor? I know it must have something to do with deriving the density of states for a bose gas, since the total occupation is,

[tex] \int_0 ^\infty g(\epsilon) f(\epsilon) d\epsilon[/tex]

I'm also fairly certain that I need to somehow express energy in terms of the wave vector and convert to spherical coordinates. But how exactly does this work? I'm still not sure how the idea of a density of states applies to a Bose gas, since the Pauli principle doesn't apply. I know I could just look up the Planckian, but I'd like to understand this so I could reproduce it on a qualifying exam (should the need arise). Help would be appreciated, thanks.
 
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  • #2


I can provide some guidance on how to approach this problem. First, it's important to understand the concept of density of states and how it applies to a Bose gas. The density of states is a measure of the number of energy states available to a system at a given energy level. In the case of a Bose gas, the Pauli exclusion principle does not apply, so there is no limit on the number of particles that can occupy a single energy level. This means that the density of states for a Bose gas is given by,

g(\epsilon) = \dfrac{V}{(2\pi)^3} \dfrac{(2m)^{3/2}}{\hbar^3} \epsilon^{1/2}

Where V is the volume of the system, m is the mass of the particles, and \hbar is the reduced Planck's constant. This expression takes into account the fact that the energy levels in a Bose gas are quantized.

Now, to derive the energy density from the Bose-Einstein distribution, we can use the following equation,

\rho = \int_0 ^\infty g(\epsilon) f(\epsilon) \epsilon d\epsilon

Where \rho is the energy density. Plugging in the expression for the density of states and the Bose-Einstein distribution, we get,

\rho = \dfrac{V}{(2\pi)^3} \dfrac{(2m)^{3/2}}{\hbar^3} \int_0 ^\infty \dfrac{\epsilon^{3/2}}{e^{\frac{\epsilon}{k_B T}} - 1} d\epsilon

To solve this integral, we can use the substitution x = \frac{\epsilon}{k_B T} to get,

\rho = \dfrac{V}{(2\pi)^3} \dfrac{(2m)^{3/2}}{\hbar^3} (k_B T)^{5/2} \int_0 ^\infty \dfrac{x^{3/2}}{e^x - 1} dx

This integral is known as the Riemann zeta function, and its value is approximately 2.612. Plugging this in, we get the final expression for the energy density,

\rho = \dfrac{V}{(2\pi)^3} \
 
  • #3


The prefactor for the Planck distribution can be derived by considering the density of states for a Bose gas. The density of states, denoted by g(\epsilon), represents the number of available energy states per unit energy interval. For a Bose gas, the density of states can be expressed as,

g(\epsilon) = \dfrac{V}{(2\pi)^3} \dfrac{4 \pi k^2}{h^3} \epsilon^{\frac{1}{2}}

where V is the volume of the system, k is the wave vector, and h is the Planck constant.

To obtain the energy density, we need to integrate the product of the density of states and the distribution function over all energy states. This can be written as,

\rho = \int_0 ^\infty g(\epsilon) f(\epsilon) d\epsilon

Substituting the expression for the density of states and the Bose-Einstein distribution, we get,

\rho = \dfrac{V}{(2\pi)^3} \dfrac{4 \pi k^2}{h^3} \int_0 ^\infty \dfrac{\epsilon^{\frac{1}{2}}}{e^{\frac{\epsilon}{k_B T}} - 1} d\epsilon

Integrating this expression using spherical coordinates and making the substitution \epsilon = \hbar \omega = h \nu, we get the final expression for the energy density as,

\rho = \dfrac{V}{(2\pi)^3} \dfrac{4 \pi \hbar^3}{c^3} \dfrac{1}{e^{\frac{\hbar \omega}{k_B T}} - 1}

This is the prefactor for the Planck distribution and is often denoted by B(\omega, T).

In summary, the prefactor for the Planck distribution can be derived by considering the density of states for a Bose gas and integrating it with the Bose-Einstein distribution. The resulting expression involves converting energy to frequency and taking into account the volume of the system. This prefactor is crucial for obtaining the correct energy density and understanding the behavior of a Bose gas at different temperatures.
 

FAQ: How to get the prefactor for the Planck Distribution

What is the Planck distribution and why is the prefactor important?

The Planck distribution is a mathematical function that describes the distribution of energy in a system at a given temperature. The prefactor, also known as the normalization constant, is important because it ensures that the distribution accurately reflects the physical properties of the system, such as the total energy and the number of particles.

How is the prefactor calculated for the Planck distribution?

The prefactor for the Planck distribution can be calculated by integrating the distribution function over all possible energy states. This integration takes into account the physical properties of the system, such as the temperature, volume, and number of particles.

What is the significance of the value of the prefactor?

The value of the prefactor affects the shape and amplitude of the Planck distribution curve. A higher prefactor means that there is a greater probability of finding particles at higher energy levels, while a lower prefactor means that there is a greater probability of finding particles at lower energy levels.

How does the prefactor change with temperature?

The prefactor for the Planck distribution is directly proportional to the temperature of the system. As the temperature increases, so does the prefactor, resulting in a broader distribution curve with a higher peak. As the temperature decreases, the prefactor decreases as well, resulting in a narrower distribution curve with a lower peak.

Can the prefactor be adjusted to fit experimental data?

Yes, the prefactor can be adjusted to fit experimental data by using the measured values of the physical properties of the system, such as the temperature and number of particles. This allows the Planck distribution to accurately describe the observed energy distribution in the system.

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