Is Atomic Size the Key Factor in Determining Acidity Levels?

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In summary, the size of an acid's anion affects its stability and acidity. A smaller anion results in a more stable molecule, but it also dissociates more rapidly. Therefore, although HX would be more stable, HZ is actually more acidic due to the stability of its larger anion. This can be observed when comparing the acidity of HF, HCl, HBr, and HI, as the larger anion in HI makes it the most acidic.
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Suppose I have two acids HX and HZ. Say X is smaller then Z in atomic size. So then one would think that HX would be a more stable molecule then HZ since X has a higher charge density then Z (Both have same electronegativity) . HZ being a weaker molecule would dissociate more rapidly. Now my TA says that due to this HZ is more acidic then HX. Is this correct?
 
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Pretty much. Compare the acidity of HF, HCl, HBr and HI.
 
  • #3
Correct. Acidity is a related to the stability of the conjugate base. A larger anion is more stable on its own than a small one, so the equilibrium favors the dissociated H+ and Z-.
 

FAQ: Is Atomic Size the Key Factor in Determining Acidity Levels?

How does atomic size affect acidity?

The larger the atomic size, the less acidic the compound tends to be. This is because larger atoms have more electron shells, which leads to a weaker attraction between the positive nucleus and the negative electrons. This makes it easier for the atom to donate or share electrons, resulting in a weaker acid.

What is the relationship between atomic size and acid strength?

As atomic size increases, the strength of an acid decreases. This is because larger atoms have a weaker hold on their electrons, making it easier for them to donate or share electrons and less likely to form a strong acid.

Why do smaller atoms tend to be more acidic?

Smaller atoms have a stronger hold on their electrons and are less likely to donate or share them. This makes it more difficult for them to form a bond with a hydrogen ion, leading to a stronger acid.

How does electronegativity affect acidity?

Electronegativity is a measure of an atom's ability to attract electrons. The higher the electronegativity, the more likely an atom is to attract and hold onto electrons. This makes it more difficult for the atom to donate or share electrons, resulting in a weaker acid.

Can atomic size and electronegativity both affect acidity?

Yes, both atomic size and electronegativity can affect acidity. Generally, larger atoms have a weaker hold on their electrons and are less likely to form a strong acid. However, there are exceptions to this rule, as the electronegativity of an atom can also play a role in its acidity. For example, fluorine, which is a small atom with a high electronegativity, is one of the strongest acids known.

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