Potential Step (wave amplitude)

This energy is not fixed, it depends on the potential and the shape of the step.In summary, when an incident wave is coming from the left-hand side and the electron energy is equal to V0, the amplitude on the right-hand side is partially transmitted and partially reflected. Due to the distribution of electron energies, the question of what happens to the wave amplitude when the electron is not moving is not well-defined. Additionally, the energy at which the wavevectors on both sides of the step are equal in magnitude is not fixed and depends on the potential and shape of the step.
  • #1
solas99
69
1
1. If the incident wave is coming from LHS,
what happens to the wave amplitude on the RHS when electron energy is equal V0?

2. the wavevectors on both sides of the step are different (generally), is there an energy at which the have the same magnitude?

thanks for any help..
 
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  • #2
solas99 said:
1. If the incident wave is coming from LHS,
what happens to the wave amplitude on the RHS when electron energy is equal V0?
The usual way to analyse this problem uses assumptions about the electrons which cannot be satisfied in reality (especially: electrons with a single, fixed energy). And here you have a case where you can see this flaw.
If you have a free electron which "moves", it cannot have a single energy value, it has some distribution. The parts above V0 can (partially) go through, the other parts are reflected. If your electron does not "move", the question is ill-defined.

2. the wavevectors on both sides of the step are different (generally), is there an energy at which the have the same magnitude?
With low energy, everything gets reflected, with high energy, nearly everything is transmitted. So somewhere in between, you have 1/2 on both sides.
 

FAQ: Potential Step (wave amplitude)

What is a potential step?

A potential step is a sudden change in the potential energy of a system, typically caused by an external force or stimulus. In electrochemistry, a potential step refers to a sudden change in the applied voltage to an electrode, creating a change in the wave amplitude of an electrochemical reaction.

How does a potential step affect an electrochemical reaction?

A potential step affects an electrochemical reaction by changing the energy level of the electrons at the electrode. This change in energy can either increase or decrease the rate of the reaction, depending on the direction and magnitude of the potential step.

What causes a potential step in electrochemistry?

A potential step in electrochemistry can be caused by a variety of factors, such as changes in the electrode material, changes in the electrolyte solution, or the application of an external voltage source.

What is the relationship between potential step and wave amplitude?

The potential step and the resulting change in wave amplitude are directly related in electrochemistry. A larger potential step will result in a larger change in wave amplitude, while a smaller potential step will result in a smaller change in wave amplitude.

How is a potential step experimentally measured?

A potential step can be experimentally measured using techniques such as cyclic voltammetry or chronoamperometry. These techniques involve applying a voltage step to the electrode and measuring the resulting change in current or potential, which can then be used to calculate the wave amplitude.

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