Where Did I Mess Up In Solving This?

  • Thread starter JeweliaHeart
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In summary, the equilibrium constant for the reaction A + B ↔ C + D is K = 2x, where x is the volume of the container. This can be determined by setting up the problem with initial, change, and equilibrium concentrations and using the formula K = [C][D]/[A]. The equilibrium concentration for D is not 0, but rather 2/x since 4 moles of C are produced. Therefore, the correct equilibrium expression is [4/x]/[2/x^2].
  • #1
JeweliaHeart
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Homework Statement


For the reaction: A + B ↔ C + D

6.0 moles of A and 5.0 moles of B are mixed together in a suitable container. When equilibrium is reached, 4.0 moles of C are produced.

The equilibrium constant for this reaction is:

a. K = 1/8
b. K = 8
c. K = 30/16
d. K = 16/30

Homework Equations



K=[C][D]/[A]

The Attempt at a Solution



I set up the problem like this:


Initial Concentrations: [A] 6/x 5/x [C] 0 [D] 0

Change in Concentrations: [A] -4/x -4/x [C] +4/x [D] 0

Equlibirum Concentrations: [A] 2/x 1/x [C] 4/x [D] 0

I assigned the variables x myself:
x= volume of container

The reason I put 0 for D's concentration is b/c the problem did not say any amount of D was formed.

Therefore the equilibrium expression should look like this:
[4/x]/[2/x^2]
which further equates to 2x. I don't where I messed up or how to solve this. Any help would be appreciated. Thanks.
 
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  • #2
Well if 4 moles of C are produced, how many moles of D are produced? Also, if if it were 0, then you would find that the equilibrium constant is zero by the formula for K and you could not just ignore it.
 
  • #3
oh...duh *hits forhead*. Thanks so much. How silly of me to overlook that.
 

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