Why does the temperature is invariant on phase transitions?

In summary, the conversation touches on the concept of energy distribution and its relationship to temperature. It is mentioned that energy is needed to break intermolecular bonds and that this energy is then transformed into potential energy rather than kinetic energy. The idea of temperature being based on statistics and the concept of systems having the same temperature in their most probable state is also discussed. The question of whether a phase transition can occur without a change in temperature is raised, specifically in regards to adiabatic processes.
  • #1
FG_313
17
1
Hello there, this is a fact that I can't understand thinking about it... Energy has to be given so that the inter molecular bonds can be broken, and energy goes in when there are formed (even though that sounds very counter intuitive to me), but why is the energy all distributed to potential energy (bonds) and it stops going to kinetic energy in the process?
 
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  • #2
Temperature is not kinetic energy! This is only true for an ideal gas.

Temperature is based on statistics. Two systems have the same temperature when the combined system is in its most probable state. This means that the subsystems have the same relative change in their multiplicity (numbers of microstates) with a small exchange of energy.
 
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  • #3
Maybe another perspective to look into the question is: is it valid to ask, does there exist a phase transition where some other quantity remains unchanged while temperature suddenly drops say?
 
  • #4
In an adiabatic process, this might happen ...? But for an adiabatic process, can there be a phase transition?
 

Related to Why does the temperature is invariant on phase transitions?

1. Why does the temperature remain constant during a phase transition?

The temperature remains constant during a phase transition because energy is being absorbed or released by the substance as it changes from one phase to another. This energy is used to break or form intermolecular bonds, rather than increasing the temperature.

2. What factors determine the temperature at which a phase transition occurs?

The temperature at which a phase transition occurs is determined by the strength of intermolecular forces in the substance, as well as external factors such as pressure and the presence of impurities.

3. Can the temperature at which a phase transition occurs be changed?

Yes, the temperature at which a phase transition occurs can be changed by altering external factors such as pressure or the presence of impurities. However, the strength of intermolecular forces in the substance will ultimately determine the temperature range over which the phase transition can occur.

4. Why do some substances have multiple phase transitions at different temperatures?

Some substances have multiple phase transitions at different temperatures because they may have different phases with different intermolecular forces. These different phases will transition at different temperatures depending on the strength of their respective intermolecular forces.

5. Is the temperature always constant during a phase transition?

No, the temperature is not always constant during a phase transition. In some cases, a substance may absorb or release enough energy to cause a change in temperature during a phase transition. This is known as a latent heat of fusion or vaporization, and can be observed in substances like water during the phase transitions between solid, liquid, and gas.

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