Recent content by AVRA

  1. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Hi Charles: Hope you are doing well. I would like to know whether the absorbance efficiency of 532 nm laser used in Raman spectroscopy is independent of temperature. If it is dependent on temperature, then how ?
  2. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you very much Charles. Looking forward to discuss with you more. Have a great day ! Best Regards, Avra
  3. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Hi Charles: As you mentioned that a slit width b will introduce Δθ=b/f, can you provide me any schematic of the same how the angle is being calculated ? Like, I have searched many optical articles regarding it which is showing a incident ray and a reflected ray with the angles and planes with a...
  4. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Hi Charles: I would like to know the significance of 'd' in this equation. Is it the the same as the interplanner distance in Bragg's law ? Thanks. Regards, Avra
  5. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Hi Charles: The formula that you mentioned for constructive interference, i.e., m λ = d ( sin ( θ i ) + sin ( θ r ) ) mλ=d(sin⁡(θi)+sin⁡(θr)) , can I use m λ = d sin θ for simplification following Bragg's law ?
  6. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Ok Thank you so much. I will look forward to read the article.
  7. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you so much for the response. It really helped me clearing my concept regarding this. i will figure out the slit width and the length of the spectrometer to calculate the instrument broadening. I would like to seek your help in resolving another query. Do you know how to determine the...
  8. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you very much for the reply. One additional query I would like to know from you and that is Thank you very much for the link and response. I would like to know mention here one thing that is that the Rama Thank you very much for the link and response. I would like to know mention here...
  9. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Ok, I got it. There was a mistake in my calculation. So, if the value of instrument broadening is small, can I say that the linewidth measurement is correct ? And can you give me any reference of these formula, it will be helpful for me to dig deep into these. Thank you so much for helping me...
  10. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you for the response. The concept is getting clearer for me. So the instrument broadening unit will be 1/nm according to the formula ? and if the value of instrumental broadening is very small, can I say that the FWHM measurement is nearly accurate ?
  11. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you again for the explanation. Actually I am new in this subject, so trying to connect the dots. I already measured the Raman peaks and calculated the FWHM from those measurements. Now, I am trying to figure out if the instrumental broadening is small enough not to influence the variation...
  12. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thanks for the reply. I would like to know, what is the formula of the instrument broadening here ? I mean is it Δλ/λ ? and the value should be as small as possible for accurate linewidth measurement in Raman peaks ? and lastly, are 'w' and slit width 'b' instrument specific ?
  13. A

    The effect of instrumental broadening on FWHM in Raman peaks

    What is the value 'f' here ?
  14. A

    The effect of instrumental broadening on FWHM in Raman peaks

    Thank you Charles for the response. I have some questions regarding the formula you mentioned. I use 1800gr/mm for the Raman measurement. Does that mean N will be equals 1800 here ? How will I determine the 'm' ? and how will I get the slit width 'd' ? Thanks.
  15. A

    The effect of instrumental broadening on FWHM in Raman peaks

    I would like to know how to extract the instrumental broadening effect in Raman spectrometer using solid angle of the objectives, slit width or spectrometer length. I am calculation the FWHM in Raman peaks and I would like to know the effect of instrumental broadening on Raman line width and how...
Back
Top