OK, that makes sense, thanks very much, and yes it was the addition of angular momenta for a two particle system, my mistake.
For the third state ##\psi_c = \sqrt{\frac{1}{3}}\psi_{211\downarrow} + \sqrt{\frac{2}{3}}\psi_{210\uparrow}##
##m_1 \neq m_2 ## so I would guess its not an eigenstate...