A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.
The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of action is part of the reaction mechanism. Chemical reactions are described with chemical equations, which symbolically present the starting materials, end products, and sometimes intermediate products and reaction conditions.
Chemical reactions happen at a characteristic reaction rate at a given temperature and chemical concentration. Typically, reaction rates increase with increasing temperature because there is more thermal energy available to reach the activation energy necessary for breaking bonds between atoms.
Reactions may proceed in the forward or reverse direction until they go to completion or reach equilibrium. Reactions that proceed in the forward direction to approach equilibrium are often described as spontaneous, requiring no input of free energy to go forward. Non-spontaneous reactions require input of free energy to go forward (examples include charging a battery by applying an external electrical power source, or photosynthesis driven by absorption of electromagnetic radiation in the form of sunlight).
A reaction may be classified as redox in which oxidation and reduction occur or nonredox in which there is no oxidation and reduction occurring. Most simple redox reactions may be classified as combination, decomposition, or single displacement reactions.
Different chemical reactions are used during chemical synthesis in order to obtain a desired product. In biochemistry, a consecutive series of chemical reactions (where the product of one reaction is the reactant of the next reaction) form metabolic pathways. These reactions are often catalyzed by protein enzymes. Enzymes increase the rates of biochemical reactions, so that metabolic syntheses and decompositions impossible under ordinary conditions can occur at the temperatures and concentrations present within a cell.
The general concept of a chemical reaction has been extended to reactions between entities smaller than atoms, including nuclear reactions, radioactive decays, and reactions between elementary particles, as described by quantum field theory.
So i'm doing a project for school with the local firefighters and we have to help save time to rescue people from a fire.
So i had an idea, What if we made a transportable device that could contain the chemicals and stuff to create a decomposition reaction. I wanted to test my theory that...
My attempt:
Species fluid and solid phase balances for a tubular reactor in which there is a homogeneous first order reaction and a heterogeneous reaction on the external surface of non-porous catalyst coated along the reactor wall.
Mole balance equation for the fluid phase
The heterogeneous...
Hi
For a personal project, has the energy level diagram of the below reaction been derived? Voltage Applied4B+2LiNO3+C ------------->B4C+2LiNO2+O2
Thanks,
Conversion: 9.65 kg = 9650 g
Mass Al = 26.98 g/mol
Molar Mass Al2O3 = (2 x 26.98) + ( 3 x 16.00) = 101.96 g/mol
Mol Al2O3 = 9650 g / 101.96 g/mol = 94.65 mol
Mol Al Required = 94.65 mol x 2 = 189.3 mol
Mass 100% Al required = 189.3 mol x 26.98 g/mol = 5.107x103 g
Mass 80% Al required =...
Hello,
I mixed these today:
H3PO4
NaOH
Tetrahydrofuran CH₂)₄O
Cyklohexanon C6H10O
2-Butanon C4H8O
It started to generate smoke. Just wondering if this gas might have been dangerous to breath in? theories? experiences?
Thanks
Stan
Hi
I am trying to safely setup an experiment to measure a chemical reaction with a spectral detector. I was wondering how to setup the experiment safely in front of the spectral detector?
Do I have to perform some calculations based on the chemical reaction beforehand? Or what?
This is an...
Hi all,
Is this energy equation of any meaning if there is no chemical reaction
$$\triangle G= RT ln \frac{C_1}{C_2}$$
in compartments with concentrations $$C_1 \ and \ C_2$$
Thanks.
What is the definition of rate ##(-r_a)=-\frac{dCa}{dt}## or ##(-r_a)=-1/V\frac{dNa}{dt}## ? I think the general one is the second one and first one is for constant volume reaction system. Is the above written rate equation only valid to batch reactor? If not can we use this in a PFR or MFR? In...
The question arises in which procedure to follow, a balance by element or by compound?
The excersise is this:
A mineral of a process contains contains 90% FeS2 and 10% inerts by weight. This materialit is calcined with 25% excess air, according to the reaction:
FeS2 + 02 ► Fe203 + S02
The...
I’m a high school student, I generally get problem in chemical reactions. I understand all physical and chemical properties of a compound, for example carboxylic acid have all the acidic property and aldehydes are highly polar. But the problem comes in chemical reactions like shift of positive...
##dU = dw + dq ##
vs
##dU = dw + dq + µdN##
Which equation do we apply to a closed system involving chemical reaction? According to textbooks, the first equation holds for any closed system in the absence of fields and kinetic energy. However, later chapters use the second equation for...
Homework Statement
You may have noticed that water sometimes drips from the exhaust of a car as it is running. Is this evidence that there is at least a small amount of water originally present in the gasoline?
Homework Equations
not sure if there is one.
The Attempt at a Solution
I'm not...
I'm confused in the balancing of a reactor , let's say the inlet volumetric flow rate is ##v_○## and outlet volumetric flow rate is ##v_1##
Doubts:
1) How is the volumetric flow rate and volume of the reactor ##V## are related to each other ?
2) If the volumetric flow rate is constant (...
If I have a chemical reaction in closed system, how can I evaluate the change in T and P?
I have:
- one equation for the chemical equilibrium
- one equation for the energy balance
but I need an other one! entropy balance, maybe?
Thanks
Ric
Hi!
I've got this problem:
1,20 g of NaHSO4 is dissolved in water to 1,0 liters and pH=2,194. What is the acid dissociation constant for HSO-4?
I assume I have to start with writing the balanced reaction, but I don't get how I do that.
I know that I'm supposted to start with NaHSO4 + H2O , but...
Hi,
I'm hoping to get clear on some chemical nomenclature.
A "chemical reaction" is a process that involves some sort of chemical change. But a conformational change doesn't involve a chemical change, just a shape change, thus from what I understand, it cannot be termed a "chemical reaction"...
Homework Statement
In hydrogen atom ionization H→p+e show that ##μ_H=μ_p+μ_r##
Homework Equations
G=μN (N is the number of particles)
The Attempt at a Solution
(1) I think the question should say "Find chemical potential relation AT EQUILIBRIUM", don't you think?
(2) My professor said that...
I'm currently doing a literature review on ultracold chemistry with an emphasis on collisional theory and quantum phenomena. I'm an undergraduate physics major, and I'd start my discussion of this topic by moving from basic Newtonian conservation laws and concepts like Coulomb repulsion to the...
Hello, this is my first posting on this forum. I enjoyed Chemistry in high school, though the arts were where my abilities drew me.
I've learned that a ratio of 2 hydrogen to 1 oxygen, when ignited by a certain amount of heat, will create a small amount of water. I will give a brief outline on...
Homework Statement
Toluene, C7H8, is burned with 30% excess air. A bad burner cause 15% of the carbon to
form soot (pure C) deposited on the walls of the furnace, what is the Orsat analysis of the
gases leaving the furnace?Homework Equations
C7H8 + 9 O2 => 7 CO2 + 4 H2O
30% excess of air
What...
Homework Statement
The decomposition of phosphine 4PH3(g) + P4(g) + 6H2(g) is first-order with respect to phosphine with a rate constant k = 0.0155 s-l at 953 K. If the decomposition occurs in a constant-volume batch reactor at 953 K, calculate, for 40% conversion of PH3,
(a) the time...
here is the question (part I):
For part I, I need some assistance, I cannot figure out how to do the question. I know eventually what to do, it's just working out the equilibrium constants I'm having trouble with. So to start, I want to work out the K values at 600K and 800K, I do this by...
Not sure if this is well know but for some reason, I don't know if exactly same chemicals make chemical reactions with one another and if yes, how common that is?
Homework Statement
Homework Equations
The Attempt at a Solution
2(255) - [(1)(159) + (1)(243)]
= +108KJ
The answer key says its b) -108KJ. Am i doing something wrong or is the book wrong?
For organic chemistry we typically look at the stability of the end product to determine if the reaction will proceed. For instance for an Sn2 reaction we would check if the product anion is more stable or less stable than the nucleophile attacking - if the product anion is more stable than the...
I was doing a science experiment involving enzymes and hydrogen peroxide, and by adding heat to the catalase, it should have sped up the reaction, but instead it slowed it down. Is there a reason why this happened?? Isn't heat supposed to speed up the reaction, instead of slowing it?
Only particles that possesses enough energy to overcome the activation energy and orientated correctly will collide and form products. How about those particles which do not possesses enough kinetic energy to overcome the activation barrier? Does it mean that for a particular chemical reaction...
Hi,
My Modern Physics lecturer is of the opinion that the energy dissipated during exothermic reactions is due to infinitesimally small change in mass of the reactants. Similarly, he said that an infinitesimally small part of the food we eat gets converted into the energy using which we perform...
Homework Statement
The entropy change of surrounding is greater than that of the system in a/an
(A) exothermic process
(B) endothermic process
(C) both (A) and (B) are correct
(D) none of these are correct
Homework EquationsThe Attempt at a Solution
ΔStot = ΔSsys + ΔSsurr
For a spontaneous...
I have been reading about how NaOH (Sodium Hydroxide) reacting with HF (Hydrofluoric Acid) yields the products H20 (Water) and NaF (Sodium Fluoride). If I were to do this, would I need the EXACT same quantity of NaOH as HF to get H20 and NaF?
Hi guys I was wondering of someone on here could briefly enlighten me on the chemical reactions that would occur with a Teflon Coated high carbon steel hook and a lead sinker while underwater? I am looking into the signals that may or may not be given off by these items both separately and with...
Dear PF Forum,
Do anybody know the 'Wolfram Alpha' for chemistry?
For example.
If I enter: HCl + NaOH
The website will produce something like
HCl + NaOH -> NaCl + H2O (+ or - energy would be preferable)
or if I enter: C6H12O6 + O2
The website will produce something like:
Do you mean: C6H12O6 +...
.. reaction.
This may seem a nonsensicle question but I'll go ahead anyway.
Say if I have a process that has an emission spectra dominated by excited state molecular emission, can I relate this in any way to the amount / number of chemical reactions occurring?
Thanks for any help
Hello,
"Reversible processes are at equilibrium : Driving force is only infinitesimally greater than the opposing force Process occurs in a series of infinitesimal steps, and at each step the system in at equilibrium with the surroundings It would take an infinite amount of time to carry out...
Homework Statement
Problem 18B.13 from Transport Phenomena, BSL.
Tarnishing of metal surfaces. In the oxidation of most metals the volume of oxide produced is greater than that of the metal consumed. This oxide thus tends to form a compact film, effectively insulating the oxygen and metal from...
Example, I have a mixture of 5 grams of oxygen and 10 grams of hydrogen. I ignite them. How much force will the explosion do?
Yes, I did think about posting this in the chem category but this is about forces, right?
Homework Statement
I am having trouble on knowing what products are formed in a chemical reaction, such as these :
i) aluminium oxide and sodium hydroxide
Al2o3 + 2NaOH + 3H2O -> NaAl(OH)4
How do we know that we have to add H2O? And how we know that the product is NaAl(OH)4 ? Why can't it be...
im reading a chemistry text and its says in daltons law chemicals can not change into atoms during a chemical reaction.but if fusion is a chemical reaction then this is wrong beacuse in stars for example hydrogen combine with hydrogen to form helium .i guest i need a little clarification of...
Hi,
I have a very interesting but challenging question. Consider any chemical reaction that involves gas production (e.g. H2 gas is produced in KOH etching silicon). As we know, the produced gas will detach from the surface and reaction can continue. What if the gas doesn't detach from the...
Does anybody know where I could find worksheet to practice naming the state of matter in chemical reactions (with answers in the worksheet to check) as I have problems with that. Especially deciding when it is aqueous. I know (well at least i am right) that when you have acid as reactants it has...
Homework Statement
A certain pyrite ore contains 85% of FeS2 and 15% of inerts. This ore is introduced into a roasting furnace with 20% excess air, in order to oxidize the FeS2 in the reaction:
\textrm{FeS}_2 + \frac{11}{4}\textrm{O}_2 \rightarrow \frac{1}{2}\textrm{Fe}_2 \textrm{O}_3 +...
This is a very basic question. When I see a chemical formula, like for example combustion of methane: $CH_4+2O_2->CO_2+2H_20$ and I compute the standard enthalpy of reaction $H_r$, do I have always to think about this value $H$ and about the chemical reaction as describing a "certain amount"...
Homework Statement
A simple and very violent chemical reaction is H + H -> H_2 + 5 eV (1eV = 1.6x10^-19 J, a healthy amount of energy on the atomic scale). However, when hydrogen atoms collide in free space they simply bounce apart! The reason is that it is impossible to satisfy the laws of...
I was thinking about this:
Let's consider a dissociation of some chemical that can run in both directions:
AB\rightleftharpoons A^{+}+B^{-}
Dissociated form is soluble in a solvent and undissociated form is not - it precipitates.
Then the reaction proceeds to the left much faster than to the...