Coordination compounds Definition and 46 Threads

A coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those of transition metals (d block elements), are coordination complexes.

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  1. J

    Synthesis of Coordination Compounds and the Role of Charcoal

    Homework Statement I performed a lab that has the main objective of reacting a cobalt(II) chloride solution through a series of steps to achieve the following two compounds: Compound A - Purple - [Co(NH3)5Cl]Cl2 Compound B - Orange - [Co(NH3)6]Cl3 The only difference when performing the...
  2. Co-ordination chemistry by Prof. D. Ray (NPTEL):-Introduction

    Co-ordination chemistry by Prof. D. Ray (NPTEL):-Introduction

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  3. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Definition

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Definition

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  4. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Classification of Ligands - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Classification of Ligands - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  5. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Classification of Ligands - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Classification of Ligands - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  6. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Ligands - 3 and Nomenclature - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Ligands - 3 and Nomenclature - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  7. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Nomenclature - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Nomenclature - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  8. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  9. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  10. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 3

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 3

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  11. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 4

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Number - 4

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  12. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Isomerism - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Isomerism - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  13. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Isomerism - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Isomerism - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  14. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Equilibria - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Equilibria - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  15. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Equilibria - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Coordination Equilibria - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  16. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  17. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  18. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 3

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 3

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  19. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 4

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Bonding in Complexes - 4

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  20. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Jahn-Teller Effect

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Jahn-Teller Effect

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  21. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Spin Crossover and Colour

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Spin Crossover and Colour

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  22. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Optical Spectra

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Optical Spectra

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  23. Co-ordination chemistry by Prof. D. Ray (NPTEL):- d-d Transitions

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- d-d Transitions

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  24. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Charge Transfer

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Charge Transfer

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  25. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Orgel Diagram

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Orgel Diagram

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  26. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Tanabe Sugano Diagram

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Tanabe Sugano Diagram

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  27. Co-ordination chemistry by Prof. D. Ray (NPTEL):- MLCT Transitions

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- MLCT Transitions

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  28. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Application of CFT

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Application of CFT

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  29. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Spinels

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Spinels

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  30. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetochemistry

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetochemistry

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  31. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetic Properties

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetic Properties

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  32. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetic Measurements

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Magnetic Measurements

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  33. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Ligand Field Theory

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Ligand Field Theory

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  34. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Sigma Orbitals

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Sigma Orbitals

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  35. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Pi Orbitals

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Pi Orbitals

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  36. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 1

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 1

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  37. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechniasm - 2

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechniasm - 2

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  38. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 3

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 3

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  39. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 4

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 4

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  40. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 5

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Reaction Mechanism - 5

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  41. Co-ordination chemistry by Prof. D. Ray (NPTEL):- Biological Inorganic Chemistry

    Co-ordination chemistry by Prof. D. Ray (NPTEL):- Biological Inorganic Chemistry

    Copyright strictly reserved to Prof. D. Ray and NPTEL, Govt. of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/104105033/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=104105033
  42. AdityaDev

    D2sp3 and sp3d2 Configurations of [Cr(NH3)6]3+ Ligand Complex

    [Cr(NH3)6]3+ has Cr3+ ion and the ligand is weak field. Hence the configuration of Cr ion is 3d3,4s0 My doubt is,will the ligands donate electrons starting from 3d to form d2sp3 or will it start from 4s and use 4p and 4d to form sp3d2? I know the 3 electrons of chromium are still unpaired but...
  43. AdityaDev

    How is the Electron Configuration of Central Atoms in Complex Salts Determined?

    I am confused with the electron configuration of central atoms in complex salts eg. ##[Fe(CN)_6]^{2-}## configuration just Fe atom is Now the complex is low spin so the configuration becomes, Now we have 6CN. where will they donate their electrons? Will the donate electrons in the remaining...
  44. B

    Isomerism in coordination compounds

    Can someone outline a comprehensive way to figure out and write all the different isomers of square planar and octahedral single-centre coordination compounds, without needing to be able to see them in 3D (and without a computer)? Questions come up all the time on my exams and a proper way of...
  45. R

    Preparation and naming of coordination compounds

    Homework Statement Hi. The combination of Fe(II), H2O, Cl- y NH4+ yields 3 coordination compounds, one of which is: [Fe(H2O)6]Cl2 Which are the other ones? Homework Equations The Attempt at a Solution Even though I sort of know how the compounds could be formed I don't why or rather , how...
  46. A

    Double Salts and Coordination Compounds

    This is an excerpt from the book I'm referring: "...when solutions containing two or more salts in stoichiometric (simple molecular) proportions are allowed to evaporate, crystals of new compounds separate out. These compounds are of two types : (1) Double Salts and (2) Coordination compounds."...
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