Distillation Definition and 73 Threads

Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation. Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids). Dry distillation may involve chemical changes such as destructive distillation or cracking and is not discussed under this article. Distillation may result in essentially complete separation (nearly pure components), or it may be a partial separation that increases the concentration of selected components in the mixture. In either case, the process exploits differences in the relative volatility of the mixture's components. In industrial applications, distillation is a unit operation of practically universal importance, but it is a physical separation process, not a chemical reaction.
Distillation has many applications. For example:

The distillation of fermented products produces distilled beverages with a high alcohol content, or separates other fermentation products of commercial value.
Distillation is an effective and traditional method of desalination.
In the petroleum industry, oil stabilization is a form of partial distillation that reduces the vapor pressure of crude oil, thereby making it safe for storage and transport as well as reducing the atmospheric emissions of volatile hydrocarbons. In midstream operations at oil refineries, fractional distillation is a major class of operation for transforming crude oil into fuels and chemical feed stocks.
Cryogenic distillation leads to the separation of air into its components – notably oxygen, nitrogen, and argon – for industrial use.
In the chemical industry, large amounts of crude liquid products of chemical synthesis are distilled to separate them, either from other products, from impurities, or from unreacted starting materials.An installation used for distillation, especially of distilled beverages, is a distillery. The distillation equipment itself is a still.

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  1. A

    Distillation question on finding q

    hi guys ive been given a problem and I've worked most of it out but I am not sure whether my answer for the feed line (q) is correct can i get somebody to re assure me on how to plot it onto the graph and get it correctly. here's the question below. A mixture containing 40 mole% heptane and...
  2. S

    Distillation Lab Recipe for Beginner Chemistry Students

    I am looking for a recipe for a good mixture for beginning chemistry students to separate by distillation. I have tried water/ethanol mixtures, but there is not a clear definition between the two. Also, I would like something more visual. I have heard rumors of a separation of dyes, but I...
  3. O

    Chemistry Question - Distillation - Why tilt the condenser?

    Homework Statement Give two reasons why the cooling water is led into the lower end rather than the upper end of the condenser? Homework Equations We were distilling a Cobalt III solution. The Attempt at a Solution I think one reason may be to prevent air pockets forming in the...
  4. G

    Simple Distillation Homework: Methanol, Pentanol, & Azeotrope

    Homework Statement So I did a simple distillation lab and discovered that my unknown was methanol (boiling point was around 65). But, I just wanted to check something: since the alcohol was impure, shouldn't the boiling point range of the unknown be above pure methanol's boiling point and...
  5. J

    What Does a Slight Temperature Increase Indicate in Simple Distillation?

    HELP NEEDED! regarding distillation... Hi I am in need of desperate help with chemistry... So we did a simple distillation of an unknown alcohol and after the distillation, we were to identify what the alcohol is.. My result was that i got my first drop of distillate at around 89degrees and...
  6. J

    Simple Distillation of Azeotrope: Propanol + Water

    What happens to an azeotrope during simple distillation?? for example 1-propanol + water... which I have asked here before.. but still not clear... but also, when you graph the boiling point-composition diagram and look at a specific composition, you read off when the liquid equilibrium is...
  7. J

    Distillation Analysis of Unknown Alcohol

    Hi, I think this is a simple enough question for all the chemists out there~ but for me it's tough... :( so we did a simple distillation experiment. We were given an unknown alcohol to identify. I found the boiling point to be about 89degrees which matched the boiling point of the...
  8. J

    Alcohol Boiling Points & Distillation Basics

    boiling point?? What is a literature boiling point?? Is it the same thing as just normal boiling point? What does this temperature tell us in regards to distillation of alcohol? (alcohol properties)
  9. J

    Why is distillation used and what are its purposes?

    What are the three purposes of distillation?? I only know the main purpose of distillation, which is to separate liquid mixture into two or more products with different compositions... I can't come up with three purposes! :(
  10. V

    Difference in simple and fractional distillation

    I found on the internet that fractional is used when the differences in boiling points are below 25C, and that there are more than 2 or 3 substances in the mixture, but i didn´t figure out what's the difference in apparatus or how the substances are purified in fractional distillation. Could...
  11. D

    How Does the 12% Efficiency Factor Influence Theoretical Yield in Distillation?

    Hey everybody, I just completed a small distillation lab for my high school chemistry class. We took a sucrose/water solution, added yeast to ferment it, and distilled it into ethanol for about an hour in the lab. I'm trying to write my lab report, and I've hit a huge stumbling block! One of...
  12. jim mcnamara

    Low temp distillation of metals

    Is practical to employ fractional distillation methods on a mixture of two metallic elements with low BP - for example Hg and Zn? And no, I'm not trying to do this.
  13. S

    Fractional Distillation and Normal distillation

    Homework Statement What are the Differences Between Fractional Distillation and Normal distillation? *This is my First Post in this forum, so Forgive me if I did something wrong*
  14. A

    Batch Distillation: Packing vs Plates for Reboiler of 250 Litres

    I need to know a few things. I am doing my internship and have been given a problem with very limited information. I have to decide whether to use packing or plates. The tower is to be used for several different mixtures. So everytime it has to be washed completely, whenever a new separation is...
  15. S

    Designing a Distillation Column

    If you were to design a distil col and didn't know the feed conditions how would you go about starting. You know xd, xb, xf, R, Eq data. Theres 5 potential q's. Also how would u make enthpy diagram for PS. Thanks.
  16. P

    How are the plates in a Fractional Distillation Tower regulated?

    My teacher can't explain it. My textbook is awful at it. So can someone explain clearly what the role of the fractionnating columns are; in the Fractional Distillation Tower.
  17. J

    In general, what is the best type of column used for fractional distillation?

    Many university organic course laboratories use Liebig columns packed with glass beads. This is what I use, but I would like to know if there are better columns that can be used instead of this. I had a problem with this type of apparatuse before. The glass beads shot right through the $30...
  18. O

    How Does Fractional Distillation Separate Different Hydrocarbons in Crude Oil?

    In the case of oil is that it contains hundreds of different types of hydrocarbons all mixed together can all be separated by distillation. To me is not clear why for a fractional distillation column when is used the differences in boiling temperature in the lower part are collected those...
  19. M

    Distillation Techniques: Lab Safety and Best Practices

    I am planning on doing some distillation in the very near future; however, it has occurred to me that I have had no formal training in proper laboratory distillation techniques. Since I would very much like to avoid damaging my beautiful new glassware on my first attempt, I figured I would try...
  20. O

    A distillation procedure, product safe to drink?

    Im attempting to make a distillation procedure with tap water so that i can drink it pure. I got a small can of pvc primer, i emptied it, and scrubbed it clean as best i could. Its sitting on a stop top right now getting as hot as it can possibly get so that all of the alcohols will evaporate...
  21. G

    Ester be separated from other liquids using fractional distillation?

    After esterification, can the ester be separated from other liquids using fractional distillation?
  22. C

    Why do different fractions form from fractional distillation?

    Fractions of distillation... Some of the fractions which result from fractional distillation seem to share carbons of the same length - yet these form different fractions. Why? Eg - Petrol is carbon chain length 4 - 12, naptha is 7 - 14 and kerosine is 11 -15; why the overlap when they boil...
  23. M

    What is the Procrustean method for entanglement distillation?

    Please explain what's entanglement distillation and what's entanglement concentration. I'm mistaken to think that these two techniques are related somehow?
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