I understand the HH equation as:
##pH = pKa + log\frac{[A^-]}{[HA]}##
The Numerator of the fraction is the conjugate Base of the original acid.
The denominator is the undissociated/ unprotonated Acid.
I understand that when the pH equals the PkA, then the solution is 50% dissociated, so...
Suppose we put benzoic acid in a buffered solution at pH=2. In this condition, it will be almost completely unionized and therefore not very soluble. Conversely, if it is placed in a basic environment, the solubility will be high. But why does this happen? Is there a shift in the acid...
Good day all!
I have a question about groundwater chemistry on an island. We have datasets over the last 40+ years and what can be seen is that the eastern and western side of the island differ from each other. On the western side there has been a distinct drop in pH over the last decades, and...
Swimming pool test kits combine a few drops of an unknown chemical with about 10 mL of pool water and then check the color of the reaction.
I would like to know the chemistry behind this. I assume that the H+ and/or the OH- ions combine with some cheemical to produce the color to be checked...
Hello , the problem that i refer to is present when we try to calculate the pH of a solution without any assumption.
in a lecture entitled "calculating the pH of a strong acid/base solution " after adding a certain amount of HCl in water we are asked to calculate the pH
(the amount of HCl and...
How would I be able to calculate the pH of slime?
I learned how to "add" pH's, like I know how to get a new pH from adding one solution to another.
But I'm not sure on how to calculate the pH of slime.
From what i know so far, this is all I will be making to make the slime:
(Poly – Vinyl...
I calculated it and found that is approximately 610Kg needed of CaCO3 to bring the lake pH to a neutral level.
Is my calculation right 1st :)?
Then if this is right, 610kg of CaCO3 is not that much in a matter of cost or weight to help the bio-life of the lake. I'm wondering if we are applying...
Considering a fish breeder decided to breed small fishes which needs a pH between 6,0 to 7,0 to stay alive. He needs to adjust the water's pH that is 5,0 to a value of 6.5, having available only calcium carbonate. The mass in mg added to 5L of water is about:
A)2,5
B)5,5
C)6,5
D)7,5
E)9,5
A weak base is titrated with a strong acid.
I think that both B and C are correct. The endpoint volume will be lower than the actual equivalence point volume. When the student mistakenly assumes the endpoint volume is the equivalence point volume, the number of moles of strong acid is seen as...
Use the equivalence volume from the pH curve to calculate the concentration of the acid, HA.
I'm not sure which equation to use or how to approach this question (Attached).
Please elaborate on the steps on how to answer the question.
Thank you!
Hi everyone, I'm stuck in solving this problem. I have two solution of H2SO4 5M that needs two consequential pH increasing: the first from the natural pH of H2SO4 5M (around zero) to pH 2 and then from pH 2 to pH 7. The second solution from the natural pH of H2SO4 5M to pH 2 and then from pH 2...
I was looking into measuring the ph levels of a lake nearby where I live. I wanted to tie the experiment to my electronics coursework so I did some reasearch and found the wonder electronic that is the ISFET. Unfortunately, I cannot find anywhere to buy an ISFET transistor; I can easily find...
I've written out the half reaction
8e- + 9H+ + SO42- = HS- + 4H2O
and I know the logK = 4.25 (that's the constant mentioned in the prompt)
I've written out the equilibrium statement of 10^4.25 = ([x^1/8]*[H2O^1/2])/([10x^1/8]*[e-]*[(10^-8.2)^9/8]
However, from there, it seems like I have two...
Hi y'all,
I think this is my first time in the chemistry section of this forum, so thank you in advance for your patience with what is (I'm pretty sure) an elementary question. I've googled around for this a bit, but my last acid chemistry study was in 2002 or so, so the reading I am doing is...
In the world of Origin of Life hypothesizing, there now seem to be two main competing approaches. Life originating at alkaline hydrothermal vents and an origin in intermittent terrestrial pools (exposed to periods of drying) getting outflow from volcanically heated water sources.
The alkaline...
For finding the pH of the acid, I made use of the equilibrium law (or the law of mass action) to arrive at the degree of dissociation which I later used to get the [H+] concentration.
I am stuck in finding the pH of the salt solution.
##CH2ClOO^- + H2O <---> CHClOOH + OH^-##
Could you please...
So I have a problem with the equation: pH = pKa + log([A-]/[HA])
The textbook states that when [H+] = Ka, there will be 50% A- and 50% HA.
However, this won't work when the coefficients of the reactants to the products are not the same. The equation only works for reactions where it is a 1:1...
Do following half-reactions have electrode potential that depends on pH? I know H+ or OH- ions wouldn't be included in Nernst equation for these, but would pH affect chemical balance in these reactions, and therefore electrode potentials?
Br2+2e- -> 2Br-
Cl2+2e- -> 2Cl-
I2+2e- -> 2I-
S2O8+2e-...
Here I used Henderson Hesselbach equation in both the cases , I.e
pH= pKa + log( [(PO4)3-]/ [H3PO4]) here pKa of phosphoric acid is 2.16 but the problem Is in both the cases the log part is same and Pka is also same so both will cancel out, and how can we solve? It is confusing.
I have the following molecule: benzotriazole. It has pka=12. At pH=6 which form prevails?
a) neutral
b) anionic
c) cationic
d) none of the above.
I thought the correct answer was c) cationic: pH<pka, benzotriazole has basic functional groups (amines).
Hi everyone, hoping for some quick help.
I’m trying to get the chemistry right for an aquaponics garden I’m building. I screwed up pretty bad the first time and just swapped out almost 100% of the water (there was a residual 2-3 gallons in the bottom of the growbed).
Last night added in about...
Hi everyone. I'm doing the multi-step problem above, and I've found myself stuck at part 3.
For step 1, I determined that the equation that we're dealing with is:
$$CH_3CH_2CO_2H + H_2O ⇔ CH_3CH_2CO_2^- + H_3O^+$$
I've also determined that the molar mass of propanoic acid is about 74.08g/mol...
Homework Statement
I am just a little confused about how the question is worded. It asks:
Which of the following solutions would have the highest pH? Assume that they are all
0.10 M in acid at 25 C. The acid is followed by its Ka value.
the bolded is what I don't understand. I don't know what...
Hi, I'm trying to calculate the slope of a pH probe using 7.0 and 10.0 buffer solutions. I've been searching for hours but all examples use 7.0 and 4.0. I've calibrated my probe using the 7.0 and 4.0 buffers and calculated the slope, then I used 7.0 and 10.0, used the same math for the slope and...
Homework Statement
How many of the following would you NOT expect to be more soluble in acid than in pure water?
FeS, CuCN, AlPO4, BaCO3, AgCl
Homework Equations
None necessary
The Attempt at a Solution
So we know that anything with OH- or anything that has the conjugate base of a weak acid...
Homework Statement
The question asks, how many of the following statements is/ are correct. I want to know which ones are right (I don't know the answer, but I will give a guess).
BaCl2 added to an HCL solution does not change the pH
NaBr added to an HBr solution will raise the pH.
NaC2H3O2...
Homework Statement
The relationship between pH and pOH, for pure water, at 25 ◦C is
14 = pH + pOH
What is the corresponding relationship between pH and pOH, for pure water, at 70 ◦C?
Homework Equations
Le Châtelier's principle?
[H+][OH-] = 10-14
[10-7][10-7] = 10-14 (25 ◦C)
[10-n][10-m] =...
Hello
I have a problem when I dissolves NaCl in deionized water. I have a pH probe in my deionized water (lets say 1 L). Then I add 40 g of NaCl, imidiately the pH-value rises to about 9.0 (i'm logging hte pH value as a function of time). Then slowly the pH-value lowers, and after 11 hours ...
Homework Statement
There are four things to be calculated:
-pH of 0.00196M solution of HCl in water, without taking ionic strength into account,
-The same thing but taking ionic strength into account
-pH of 0.00196M solution of HCl in Na2SO4, without taking ionic strength into account,
-And...
Homework Statement
to 1 L solution containing 0.1 mole each of NH3 and NH4Cl, 0.05 moles of NaOH is added. The change in pH will be? (pK for NH3=4.74)
The Attempt at a Solution
I have the solution and the answer is 0.48. The following was the first step
calculated initial pH from henderson's...
Homework Statement
Calculate pH of a solution containing 0.1 mole of Ch3cooh, 0.2 mol of CH3COONa and 0.05 mol of naoh in 1 L. (Pka for Ch3cooh=4.74).
2. The attempt at a solution
The 0.05 mol of NaOH will react with the 0.10 mol CH3COOH to produce 0.05 mol CH3COONa , and there will bve 0.05...
I'm going over applications of logarithms in my College Algebra class and I'm at a part where it talks about pH scales, and it shows the pH concentration of a substance to be the negative logarithm of hydronium ions.
I want to know why the logarithm is negative, so I googled it and the answers...
Homework Statement
How does a pH probe work?
Homework EquationsThe Attempt at a Solution
A combined pH probe is comprised of 2 electrodes a measuring and reference electrode. The measuring electrode is composed of glass with a silver alloy electrical wire submerged into a neutral KCl solution...
Homework Statement
>Which of the following aqueous solutions would test closet to 7 on the pH scale?
$a) NaCl$, $b) Na_2CO_3$, $c) NaH_2PO_4$, $d) NaCN$
Homework EquationsThe Attempt at a Solution
I don't understand this. So I tried writing chemical equations like for a), NaCl + H20 --> NaOH +...
For an upcoming research project, I intend to apply different solutions to cultures of cells. How would I determine if the cells are incurring damage from the solutions due to the pH of the solutions as I observe them under my compound microscope?
Homework Statement
Calculate the pH of the following solutions: (caution: these are hydrolysis reactions)
a. an 0.30 M solution of NaF
Homework Equations
I think by hydrolysis reactions they mean that each of the given compounds is combined with $H_2O$.
Then for
a) NaF + HF <-->...
Homework Statement
Calculate the pH of a 0.20 M solution of iodic acid ##(HIO_3)##. ##K_a## for iodic acid is 0.17
Homework Equations
##K_a = \frac{[H^+][IO_3^-]}{[HIO_3]}##
The Attempt at a Solution
##[HIO_3] = 0.20## M.
The concentration of ##[H^+]## and ##[IO_3^-]## should be the same...
i want to be able to test the ph of foods and drinks so I purchesed a digital ph tester for water. Is there a better ph tester option ? If I wanted to test the ph of something like mayonnaise would I just stick the tester into the mayo or would I need to mix the mayo with water first?
Homework Statement
When 100.0 mL of weak acid HA was titrated with 0.09381M NaOH, 27.63mL were required to reach the equivalence point. The pH at the equivalence point was 10.99. What is the pKa of HA
Homework Equations
pH=pKa+log([A]/[HA]
[OH]-10^(-pOH)
The Attempt at a Solution...
I made an account to ask this. I have looked and could not understand any of the formulas I came across. I even looked for calculators, but did not understand how to use them.
Milk has a pH of 6.5 to 6.7 (lets use 6.7)
And I wish to lower the milk's pH to 4.9 (as an example)
How do I...
Homework Statement
Hello everybody,
How can I calculate pH value of 4.41 M HCl water solution? Is it possible for such a solution to exist?
Thank you very much for your help,
CroSinus
Homework EquationsThe Attempt at a Solution
When I try to find - log 4.41 I get a negative value. I do not...
We lyophilized 50mg/ml mAb with PI of 7.5 in a 10mM His buffer pH 6.2. Upon reconstitution the pH is 6.5. Does anyone have an explanation for this? I am under the impression His is much less susceptible to pH change during lyophilization as opposed to something like a phosphate buffer. Thanks.
The question I have been given:
Draw the dominant forms of each of the compounds below and state which, if any, would be expected to extract from aqueous solution into hexane at (a) pH 12 and (b) pH 2. CH3CH2COOH CH3CH2NH2 CH3CH2CH2OH H2NCH2CH2COOH
From my understanding, I can tell what the...
I understand that pH affect the tertiary structure as it will change the ionic interactions between the COO- and NH3+ groups, however, as the secondary structure is caused by hydrogen bonds, how does pH affect it? Is it because the change in tertiary structure will alter the shape of the protein...
Hello, I just had my first exam yesterday, and I'm always tripped with this question that combines neutralization with buffer solution. The task is to find the pH. I did try to understand the general concept behind it. From my understanding, if CH3COOH reacts with NAOH and the acid has a higher...
For a lab I need to create a 0.1M solution of NaOAc buffer at pH 5
It's been a while since I worked with buffers. I'm struggling to find a way to get both the proper morality and proper pH.
My first though was to create a 0.2M solution of acetic acid and titrate it to pH 5 using sodium...
The recipe for luminol solution that I found on the internet is:
0.2g luminol, 4.0g Na2CO3, 24.0g NaHCO3, 0.5g (NH4)2CO3, 0.4g CuSO4 dissolved in 1 dm3 of water.
How can I alter the pH of the solution to get a range of pH values from 7 to 14 without affecting the chemisty of the solution?