What is spin-orbit coupling: Definition and 1 Discussions
In quantum physics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–orbit interaction leading to shifts in an electron's atomic energy levels, due to electromagnetic interaction between the electron's magnetic dipole, its orbital motion, and the electrostatic field of the positively charged nucleus. This phenomenon is detectable as a splitting of spectral lines, which can be thought of as a Zeeman effect product of two relativistic effects: the apparent magnetic field seen from the electron perspective and the magnetic moment of the electron associated with its intrinsic spin. A similar effect, due to the relationship between angular momentum and the strong nuclear force, occurs for protons and neutrons moving inside the nucleus, leading to a shift in their energy levels in the nucleus shell model. In the field of spintronics, spin–orbit effects for electrons in semiconductors and other materials are explored for technological applications. The spin–orbit interaction is at the origin of magnetocrystalline anisotropy and the spin Hall effect.
For atoms, energy level splitting produced by the spin–orbit interaction is usually of the same order in size as the relativistic corrections to the kinetic energy and the zitterbewegung effect. The addition of these three corrections is known as the fine structure. The interaction between the magnetic field created by the electron and the magnetic moment of the nucleus is a slighter correction to the energy levels known as the hyperfine structure.
Below is the derivation of E1so, the first-order correction to the Hamiltonian due to spin-orbit coupling of the election in hydrogen atom. My question is whether it's valid to use [6.64] (see below). ##<\frac{1}{r^3}>## I believe is ##<\psi_{nlm}|\frac{1}{r^3}|\psi_{nlm}>##, but ##\psi_{nlm}##...