Vaporization Definition and 80 Threads

Vaporization (or vaporisation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomenon.

Evaporation is a phase transition from the liquid phase to vapour (a state of substance below critical temperature) that occurs at temperatures below the boiling temperature at a given pressure. Evaporation occurs on the surface. Evaporation only occurs when the partial pressure of vapor of a substance is less than the equilibrium vapor pressure. For example, due to constantly decreasing pressures, vapor pumped out of a solution will eventually leave behind a cryogenic liquid.
Boiling is also a phase transition from the liquid phase to gas phase, but boiling is the formation of vapor as bubbles of vapor below the surface of the liquid. Boiling occurs when the equilibrium vapor pressure of the substance is greater than or equal to the environmental pressure. The temperature at which boiling occurs is the boiling temperature, or boiling point. The boiling point varies with the pressure of the environment.
Sublimation is a direct phase transition from the solid phase to the gas phase, skipping the intermediate liquid phase. Because it does not involve the liquid phase, it is not a form of vaporization.
The term vaporization has also been used in a colloquial or hyperbolic way to refer to the physical destruction of an object that is exposed to intense heat or explosive force, where the object is actually blasted into small pieces rather than literally converted to gaseous form. Examples of this usage include the "vaporization" of the uninhabited Marshall Island of Elugelab in the 1952 Ivy Mike thermonuclear test.At the moment of a large enough meteor or comet impact, bolide detonation, a nuclear fission, thermonuclear fusion, or theoretical antimatter weapon detonation, a flux of so many gamma ray, x-ray, ultraviolet, visual light and heat photons strikes matter in a such brief amount of time (a great number of high-energy photons, many overlapping in the same physical space) that all molecules lose their atomic bonds and "fly apart". All atoms lose their electron shells and become positively charged ions, in turn emitting photons of a slightly lower energy than they had absorbed. All such matter becomes a gas of nuclei and electrons which rise into the air due to the extremely high temperature or bond to each other as they cool. The matter vaporized this way is immediately a plasma in a state of maximum entropy and this state steadily reduces via the factor of passing time due to natural processes in the biosphere and the effects of physics at normal temperatures and pressures.
A similar process occurs during ultrashort pulse Laser ablation, where the high flux of incoming electromagnetic radiation strips the target material's surface of electrons, leaving positively charged atoms which undergo a coulomb explosion.

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  1. StarChem

    Vaporization Heat and the Heat Capacity of H20 comparison

    According to the Vaporization Heat table, the heat needed for 1 mol of H2O to evaporate at 100°C is 40.7KJ and 44.0KJ/mol is needed to evaporate H2O at 25°C. Thus 44.0-40.7=3.7KJ is the energy needed to heat H2O to 100°C from 25°C. However, according to the heat capacity of H2O, 3.7KJ will only...
  2. yecko

    Vaporization latent heat vs boiling point

    answer is 78oCdelta G = delta H - T delta S -235,310- (-277,690) = -38.56e3- T (282.59-160.70) T = -664K I am not sure if my concept is correct. May anyone help a little bit on that please? thank you
  3. A

    How to calculate change in pressure from LN2 phase change

    I am trying to calculate the increase in pressure caused by liquid nitrogen when it changes from liquid to vapor within a closed, constant volume at atmospheric pressure. How can this be done? Do I need to include the heat of vaporization?
  4. dromeascr

    What is the pressure surrounding a liquid at its boiling point?

    Hello everyone, before I start I just want to mention that I am not an expert in physics whatsoever, so please be as specific as you can get if you wish to provide an answer. (The question itself might be considered stupid to be honest) I read the definition of the boiling point recently and...
  5. PHstud

    How to find the heat of vaporization of ABS?

    Hello everyone ! I am currently looking for a way to find the heat of vaporization of Acrylonitrile butadiene styrene I can not find any papers or source about it, so maybe I thought there is some chemistery table that could help ? Do you have any ideas/sources ? Thank you !
  6. M

    B Why did the water drops bounce instead of vaporizing on the hot cooker?

    After completing an experiment observing a glass of water on a switched-on cooker with an infrared camera, some water drops accidentally landed on the surface of the hot cooker and started to bounce from one point to another until they finally vaporized. I wonder why the drops instead of...
  7. U

    Filter Material which Blocks Volatile Liquid, Passes Vapor

    Hi, All. Given a scenario of a closed volume of volatile liquid and it's associated vapor above boiling point (ex. butane in a can at room temp.) which is dispensed through some tube or line: Is there some filtering medium capable of ensuring that only vapor may pass through the line, producing...
  8. H

    Heat of Evaporation: Melting Ice to Boil Nitrogen

    Homework Statement A 0.035 kg ice cube at its melting point is dropped into an insulated container of liquid nitrogen. How much nitrogen evaporates if it is at its boiling point of -196 C? Nitrogen has heat of vaporization of 200000 J/kg Ice's specific heat is 2100 J/kg*C Homework Equations...
  9. Ian Baughman

    Change in internal energy during water vaporization

    According to the first law of thermodynamics, dQ = dU + dW and you can find dU = nCvdT If this is the case then when water at 100°C vaporizes to steam at 100°C shouldn't the change in internal energy be zero because it is dependent on temperature change?
  10. J

    How much perspiration must vaporize per hour to dissipate extra energy

    Homework Statement During the game, the metabolism of basketball players often increases by as much as 30.0 W. How much perspiration must a player vaporize per hour to dissipate this extra thermal energy? Assume that perspiration is simply pure water and that perspiration starts at temperature...
  11. henrco

    Meteor impact - Heat vaporization and capacity

    I believe my attempt below is correct but I'm not 100% sure, any guidance welcome. 1. Homework Statement Suppose a meteor of volume 1000 km3, density 5000 kg m-3 and speed 30000 km hr-1 crashed into the ocean and 10% of the impact energy was converted directly into heat. i) Estimate the...
  12. B

    Air pressure vs post-fuel pump vaporization chamber

    My question is harder to explain than I would imagine it will be to answer. I'm trying to vaporize a non-combustible fuel source with an internal radiant coil surrounding a small vaporization chamber consisting of a heat-resistant cotton-like material being fueled by a constant drip fuel pump...
  13. D

    Is it more energy efficient to evaporate water or boil it?

    Homework Statement If I have a pot of water that I want to bowl so that there won't be any water left then the energy that I have to add is: E=c*m*delta T E=l(vaporization) * m But if I have wet clothes and want the water to evaporate then the energy needed is: E=l(vaporization)m So from...
  14. E

    Acetone in water influence its enthelpy of vaporization

    Hi Everyone, I'm currently developing a waste heat recovery device as a side project. The system I've created uses a solution of acetone and water. One step in the process involves vaporizing acetone from the water at a low grade heat temperature (note: acetone does not form an azeotrope with...
  15. H

    Lattice energy and energy required to vaporize MgO ?

    I understand that the lattice energy is the energy released when an solid ionic compound forms or it is the energy required to separate completely a mole of a solid ionic compound into its gaseous ions. So is second definition the same thing as vaporizing an ionic compound and so we can...
  16. C

    Lower and Higher Heating Values of Coal: Why do they exist?

    Hello friends, The balanced chemical equation for the combustion of carbon is: C(solid) + O2(gas) -> CO2(gas) Now, the lower and higher heating value of hydrocarbon fuels (such as methane) exists because in the LOWER heating value, you are subtracting away the latent heat of vaporization of...
  17. T

    T-dependence of heat of vaporization near critical point

    The Wikipedia page on the heat of vaporization has a nice graph showing the heat of vaporization going to zero at the critical points of various substances. Is there a known form for the heat of vaporization as a function of temperature near the critical point? I imagine it is probably a power...
  18. N

    Calculating Heat of Vaporization for Ethyl Alcohol at 65°C

    Homework Statement How many kilocalories of heat are needed to change 143N of ethyl alcohol at 65°C to vapour? Homework Equations Lv = Q/m The Attempt at a Solution I'm really stuck. I have no idea how to work the units of N with heat problems. I've looked online and in my book and have no...
  19. Z

    Vaporization and Energy absorption

    In modern nanotechnologies, metals can be vapourized to coat onto the surface of another material as a thin but hard protective layer. How much energy would it take to heat 0.55 kg of iron from 1400oC to vapour at 2050oC?
  20. H

    Internal energy and heat of vaporization

    1. One gram of water occupies a volume of 1 cm3 at atmospheric pressure. When this amount of water is boiled, it becomes 1671 cm3 of steam. Calculate the change in internal energy for this vaporization process. The heat of vaporization for water is 2.26 x 106 J/kg. 2. w = -PΔV, E = q + w...
  21. N

    Heat of vaporization conceptual problem

    When I'm doing the Physics homework the problem for heat of vaporization uses Q=mcΔT and Q=mLv. How do I know when to use which equation through out the problem?
  22. Teemo

    Internal Energy Change: Homework Solutions

    Homework Statement Internal Energy Change Homework Equations N/A The Attempt at a Solution If internal energy change equals enthalpy change, then I am looking for the reaction which has the enthalpy change closest to zero. I know it cannot be A, as the formation of water is highly exothermic...
  23. U

    Is an asthma inhaler (MDI) an example of vaporization?

    I am trying to give some context to medical vaporizers in a literature review I am composing and initially decided to give asthma inhalers and nasal inhalers as examples. I realized however, that some sources on-line were referring to these metered dose inhalers as vaporization devices when...
  24. A

    Vaporization pressure in a fuel can

    A normal behavior of a plastic jerry can used for gasoline is that it expands by the pressure caused by vaporization of the gas. Which option below will be the best alternative to reduce the pressure caused by vaporization in a jerry can during storage? : - Fill up the can as much as possible...
  25. R

    Enthelpy of vaporization of hexane

    Homework Statement The normal boiling point of hexane is 69.0°C. Estimate (a) its enthalpy of vaporization The Attempt at a Solution In order to solve for ΔHvap in the Clausius-Clapeyron equation I need a reference T and p point. I extracted it from the triple point (T=178K and p=1,23Pa)...
  26. J

    Why the heat of vaporization decreases with increasing temperature ?

    Heat of vaporization of water slightly decreases with temperature. https://en.wikipedia.org/wiki/Enthalpy_of_vaporization Does anybody know of a simple explanation of this fact based on molecular theory? Or any explanation whatsoever. The Wikipedia article says " The heat of...
  27. 1

    Vapor pressure given boiling point and heat of vaporization?

    Homework Statement What is the vapor pressure of benzene at 50.0 C? Benzene's boiling point is 80.1 C and its heat of vaporization is 31 kJ/mol Homework Equations The Attempt at a Solution I don't want to be that guy who just says "I don't know" but.. All I know is that: ln P...
  28. F

    Refridgeration, Boyle's law or enthelpy of vaporization?

    I've curious about how an air conditioner or refrigerator make's cold air. I've read two different descriptions how cold is "made", or how heat is removed from a system. Some descriptions I've read say that air conditioners use expanding gas in it's coils, hence the use of Boyle's law. Other...
  29. C

    Calculating Enthelpy of Vaporization using Clapeyron Equation

    Hi everyone. I am having a problem that hopefully someone here can help me with. For the purposes of flash calculations, I’m trying to find the enthalpy of vaporization of a compound using the Antoine equation and Clapeyron equation. I am using heptane at 15.5597 psia as an example. For the...
  30. L

    Calculate Heat of Vaporization and normal boing point (in degree C).?

    Using line equation y = -4058.7x + 16.10 with the experiment pressure measured in kPa instead of atm. I already solved for heat of vaporization thus: (-4058.7K)(-8.314 J/mol \astK)=heat of vaporization = 33444 J/mol = 33.44 kJ/mol. Also, the vapor pressure for normal boiling point...
  31. H

    Flash vaporization balance - ODEs, deviation variables, linearization

    Homework Statement Given the attached figure, a) Develop an ordinary differential equation that describes the dynamic height h(t) in the flash tank in terms of \dot{m}_{i}, \dot{m}_{l},\dot{m}_{v}, \rho_{i}, \rho_{l}, \rho_{v}, and A. b) Given the fact that the process is isenthalpic...
  32. T

    Help with Thermo Problem, vaporization of water into evacuated vessel

    one mole of liquid water (100 deg C, vapor pressure = 1 atm) in a container is introduced into an evacuated vessel maintained at 100 deg C and allowed to evaporated. The volume of the vessel is such that the final pressure of the gaseous water is 0.1 atm. Given the (normal) latent heat of 9,730...
  33. G

    Can water be instantly vaporized without reaching its boiling point?

    Hello, I recall watching a show that discussed several personal flying devise the military had invented over the years. One of them was the Hiller's flying platform, but there was another that they mentioned. It was a jet pack of sorts (I can't recall it's name) and it used steam. I don't...
  34. M

    Chemical potential in Thermodynamics to find latent heat of vaporization

    Homework Statement The latent heat of vaporization of a substance is defined as the amount of heat required to transform the substance from its liquid into its vapor phase. A certain material has a boiling point of 700K and its molecules have three degrees of freedom in the liquid phase but...
  35. P

    Calculations Lab: Heats of Fusion and Vaporization

    Homework Statement Hi, I am answering Question #3, and using the formula and variables above scratch area as reference on how to answer the question. Could someone please have a look and see if the problem I worked out came out correct. Homework Equations The Attempt at a Solution First I...
  36. J

    Vaporization of Mixture at constant temperature

    How is it possible to completely vaporize a mixture at constant temperature? I have seen listed values for ΔH(Vaporization); however, this doesn't quite make sense to me. If a mixture (with two largely diffent boiling points) is at its boiling point in the liquid state and I want to completely...
  37. N

    Enthelpy of vaporization from Clausius–Clapeyron

    Homework Equations d ln(Psat) / d (1/T) = -ΔHvap/R (Clausius-Clapeyron) The Attempt at a Solution When solving for the enthalpy of vaporization using the Clausius-Clapeyron equation, is the resulting value an average over the temperature range? I assume this is the case, because...
  38. M

    Enthelpy of Vaporization vs. Latent heat of vaporization

    I am having confusion with the difference between these two, or are they synonymous terms?
  39. S

    Exploring Enthalpies of Vaporization

    Hey guys, I was just hoping to clear something up regarding enthalpies of vaporization. The idea of the heat of vaporization for a substance being "temperature dependent" is confusing me, as I had been under the impression that these quantities were only considered at the boiling point of...
  40. S

    Heat of vaporization ( thermal physics) helppp pleasee ?

    A student suspects that the power rating on an immersion heater is 50 W but he is not sure.He sets up an apparatus as shown. After the liquid has been brought to its boiling point, he finds that 3.5g of vapor escaped each minute through the outlet tube.The boiling point of the liquid is 80...
  41. H

    Chemical potential in thermodynamics to find latent heat of vaporization

    Doing some fun problems in Keith Stowe's 'An Introduction to Thermodynamics and Statistical Mechanics'. Good book. Problem statement: A certain material vaporizes from the liquid phase at 700 K. In both phases, the molecules have three degrees of freedom. If u_{0} in the liquid phase is...
  42. S

    Latent heat vaporization vs fusion

    Why is the latent heat of vaporisation greater than that of fusion(melting)? I mean in liquid state,atoms are already far apart, so it must require less energy to make them gas(far apart) as forces(electric in nature) between molecules decrease with distance.
  43. W

    Latent Heat of Vaporization /w Temperature

    Hi, I would like to ask, why is it that the specific latent heat of vaporization of water at, say 10 degrees Celsius, is considerably higher that at 100 degrees Celsius? It would be great if you could provide an explanation from the molecular view. Thanks.
  44. P

    Entropy/enthelpy/gibbs for vaporization of water

    This is a question from a quiz in my physical chemistry class For 1 mole of H20, calculate \Delta{S_{sys}}, \Delta{S_{surr}}, \Delta{S_{univ}}, and \Delta{G_{sys}} for the following transition at 1 atm pressure and 95 degrees Celcius H20 (l) ---------> H20 (g) Right now, what I'm confused...
  45. J

    Latent heat of vaporization & pressure

    I'm making my way through some workbooks at my job (coal-fired power plant) and I've hit a stumbling block. I could just memorize what the books says, but I really want to understand, so here goes... One question states: "As the pressure exerted on a steam/water mixture increases, (answer...
  46. P

    Specific Latent Heat of Vaporization vs Evaporation

    Hi, When studying and thinking about the concept of Specific Latent Heat of Vaporization I keep falling in the trap of confusing it with evaporation - in the end, in both cases water in the liquid state is being changed into vapor. Could anyone help me differentiate the two ideas...
  47. F

    Disconnect between Lennard-Jones and Heat of Vaporization

    I'm trying to understanding "Heat of Vaporization" in fundamental terms. People say that processes like evaporation and boiling are endothermic because chemical bonds are being broken, but for actual cooling to occur there must a loss in translational kinetic energy of the molecules involved...
  48. P

    Calculating Heat of Vaporization for Substance X using Vapor Pressure Data

    Homework Statement Using the following vapor pressure data solve for the heat of vaporization for substance x. T VP 20 100 30 175 40 325 Homework Equations ln (P1/P2) = -Heat of vap/RT (1/T2 - 1/T1) The Attempt at a Solution I know the answer is...
  49. N

    Is a New Liquid with Lower Latent Heat More Convenient for Boiling Eggs?

    Homework Statement A new liquid is discovered that has the same boiling point and specific heat as water but a latent heat of vaporization of 10 calories per gram. Assuming that this new liquid is safe to drink, would it be more or less convient than water for boiling eggs? Why? The...
  50. S

    Complete vaporization time of water into superheated steam - DESUPERHEATER

    Hi to all...i've a problem. i have to calculate the position and the time of complete evaporation of a continuous water flow which is injected trough a nozzle into a continuous flow of steam in superheated condition. The position (and than the time) at which I'm sure that there aren't water...
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