X-ray crystallography Definition and 11 Threads

In my x-ray crystallography data for a single crystal of NaCl using x-rays generated by Cu k alpha (154 pm), there are three peaks identified at angles of 14.155, 31.475 and 53.5 degrees. According to http://www.nada.kth.se/~fabo02/solid/xray.pdf, these peaks must correspond to only even values...

I am able to find methods on how to index Bragg peaks for powder diffraction, and was wondering if the method is the same for single cubic crystals of NaCl? I have tried and cannot get the expected sequence of allowed reflections for cubic lattices (h^2 + k^2 + l^2= 3, 4, 8, 11, 12, 16, 19...

I am trying to experimentally determine the atomic scattering factors for NaCl using Laue photography. For an NaCl crystal, the intensity of the wave scattered at the unit cell is proportional to (4⋅(fCl+fNa))2 if h,k,l are even and to (4⋅(fCl-fNa))2 if h,k,l are odd. fNa and fCl are the atomic...

I have some precipitate samples that I wish to analyze for XRD. I collected them by filtration of a slurry. Through the filtration, the precipitates "cemented" on the surface of the filter pad so the samples I collected are not exactly in powdered form, which I believe is the ideal form to do...

Hi,I've been doing a lab cycle on X-ray crystallography. We are using Cu X-ray source on chloride salt crystals. It seems that the Bragg peak profile are commonly acknowledged to be a Voigt function, which is a convolution of Gaussian and Lorentzian. I am wondering what's the physical reason for...

Homework Statement I have done a simple lab experiment to find the lattice constant for NaCl. Using a diffractometer, radioactive counts were measured as a function of crystal orientation angle for electron voltages of 20 and 30 kV. The average lattice constant found wasclose to the accepted...

Hello, I need to learn how Solid State NMR and X-ray Crystallography work (theory and practical application). I'm primary interested in how those experimental techniques are used to determine molecular structures. I'm an undergrad physics student and I need this to pass my final exam. So if some...

Homework Statement Hello, i have the following task in my homework: When doing an X-ray crystallography experiment to determine the structure of biomolecules (protein/DNA), why do consider interpreting an electron-density map (EDM) instead of directly using the diffraction data? 2. The...

X-ray crystallography is now 100 years old so this question is probably pretty simple. Is the diffraction coming from the nucleons or the electrons in the sample? Ie. The electrons occupy a more diverse location within the sample (depending on what level/shell they occupy, in fact some may be...

I'm trying to figure out how Braggs law is useful for analysing crystal structures. So here's the equation: nλ = 2dsinθ where λ is the wavelength of incident radiation, d is the distance between each layer of atoms in the crystal and θ is the angle of incidence. So to keep things simple let's...

I had recently stumbled upon a computer program that can automatically add missing hydrogen atoms to protein structures from files from the protein data bank. (due to the hydrogen atom having only 1 electron, hence making its electron density too low to be detected by X-ray crystallography...