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jaumzaum
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I'm studying the Bohr's hydrogen atom and my teacher gave us a challenge question. When I was working in the problem I've got a couple of other questions that I don't know the answer.
The initial problem was the following:
Today we know the electrons are not the only particles moving inside the atom. The nucleus is moving too, but with a very smaller radius. In the Bohr hydrogen atom we can say the nucleus describes a circumference with the same angular velocity of the electron, and they are always "diametrically" opposed. The sum of the angular momentum of the nucleus and the electron is a integer multiple of h/2 π. Calculate the percentage deviation of the new Rydberg constant in this case.
OK, let's begin
Let:
Rp= proton orbital radius
Re = electron orbital radius
Vp = proton orbital velocity
Ve = electron orbital velocity
w = angular velocity of electron/proton
Mp = proton mass
Me = electron mass
q = charge of electron/proton
Rh = Rydberg constant
c = speed of light
ε = vacuum permittivity
We have:
Me w Re² + Mp w Rp² = n h/2π (I)
Me w² Re = Mp w² Rp = q²/4πε(Re+Rp)² (II)
From (II) Rp = Me Re/Mp
From (I) w Re² Me(Me+Mp)/Mp = n h/2π (squaring)
Re4 w² Me² (Me+Mp)²/Mp² = n²h²/4π² (substituting w)
Re4 Me² (Me+Mp)²/Mp² . q²/4πε(Re+Rp)² Me Re = n²h²/4π²
But (Re+Rp)² = Re² (Me+Mp)²/Mp²
Doing all the calculations,
Re = h² ε/π q² Me . n²
Rp = h² ε/π q² Mp . n² (that's because we don't wee the nucleus orbiting, its radius is 1836x smaller than the electron 's
Finding w:
w = Me Mp/(Me+Mp) . q4 π/2h³ε² . 1/n³
Now we have to calculate the energy of the electron.
But I don't think we can do Me Ve²/2 - q²/4πε (Re+Rp), because q²/4πε (Re+Rp) stand for the potential energy of the set electron+proton, and not only for the electron. The difference in q²/4πε (Re+Rp) will be responsible for a difference in electron AND proton kinetic energy. Is it right?
I did the following:
The difference of the electron kinetic energy is equal to the resultant work done on it. The work is negative for the electric force and positive for the photon.
So:
The variation in kinetic energy between levels n1 and n2 is:
ΔMe Ve²/2 = -Mp²/(Me+Mp)² . q4 Me/8ε²h² . (1/n1² - 1/n2²)
The work done by the electric force is
-2Mp ²/(Me+Mp)² . q4 Me/8ε²h² (1/n1² - 1/n2²)
So hc/ λ = q4 Me/8ε²h² (1/n1² - 1/n2²) . Mp²/(Me+Mp)²
And 1/λ = Rh (1/n1² - 1/n2²) Mp²/(Me+Mp)²
So the deviation is 1-Mp²/(Me+Mp)² = Me/(Me+Mp) = 1/1837 = 0.05443%.
Have I done it right?
Besides, the 1/ λ for the proton can be calculated too
1/λ' = 1/λ . (Me/Mp)
λ' = 1836 λ
This equation says in every atomic electron transition in the hydrogen atom, the nucleus emits waves in the range of 10-4 to 10-3 m. Is it right? Do this waves have any special name?
--------CORRECTION---------
Deviatio n = 1-Mp²/(Me+Mp)² = Me(Me + 2Mp)/(Me+Mp)² = 3673/1837² = 0.1088%
The initial problem was the following:
Today we know the electrons are not the only particles moving inside the atom. The nucleus is moving too, but with a very smaller radius. In the Bohr hydrogen atom we can say the nucleus describes a circumference with the same angular velocity of the electron, and they are always "diametrically" opposed. The sum of the angular momentum of the nucleus and the electron is a integer multiple of h/2 π. Calculate the percentage deviation of the new Rydberg constant in this case.
OK, let's begin
Let:
Rp= proton orbital radius
Re = electron orbital radius
Vp = proton orbital velocity
Ve = electron orbital velocity
w = angular velocity of electron/proton
Mp = proton mass
Me = electron mass
q = charge of electron/proton
Rh = Rydberg constant
c = speed of light
ε = vacuum permittivity
We have:
Me w Re² + Mp w Rp² = n h/2π (I)
Me w² Re = Mp w² Rp = q²/4πε(Re+Rp)² (II)
From (II) Rp = Me Re/Mp
From (I) w Re² Me(Me+Mp)/Mp = n h/2π (squaring)
Re4 w² Me² (Me+Mp)²/Mp² = n²h²/4π² (substituting w)
Re4 Me² (Me+Mp)²/Mp² . q²/4πε(Re+Rp)² Me Re = n²h²/4π²
But (Re+Rp)² = Re² (Me+Mp)²/Mp²
Doing all the calculations,
Re = h² ε/π q² Me . n²
Rp = h² ε/π q² Mp . n² (that's because we don't wee the nucleus orbiting, its radius is 1836x smaller than the electron 's
Finding w:
w = Me Mp/(Me+Mp) . q4 π/2h³ε² . 1/n³
Now we have to calculate the energy of the electron.
But I don't think we can do Me Ve²/2 - q²/4πε (Re+Rp), because q²/4πε (Re+Rp) stand for the potential energy of the set electron+proton, and not only for the electron. The difference in q²/4πε (Re+Rp) will be responsible for a difference in electron AND proton kinetic energy. Is it right?
I did the following:
The difference of the electron kinetic energy is equal to the resultant work done on it. The work is negative for the electric force and positive for the photon.
So:
The variation in kinetic energy between levels n1 and n2 is:
ΔMe Ve²/2 = -Mp²/(Me+Mp)² . q4 Me/8ε²h² . (1/n1² - 1/n2²)
The work done by the electric force is
-2Mp ²/(Me+Mp)² . q4 Me/8ε²h² (1/n1² - 1/n2²)
So hc/ λ = q4 Me/8ε²h² (1/n1² - 1/n2²) . Mp²/(Me+Mp)²
And 1/λ = Rh (1/n1² - 1/n2²) Mp²/(Me+Mp)²
So the deviation is 1-Mp²/(Me+Mp)² = Me/(Me+Mp) = 1/1837 = 0.05443%.
Have I done it right?
Besides, the 1/ λ for the proton can be calculated too
1/λ' = 1/λ . (Me/Mp)
λ' = 1836 λ
This equation says in every atomic electron transition in the hydrogen atom, the nucleus emits waves in the range of 10-4 to 10-3 m. Is it right? Do this waves have any special name?
--------CORRECTION---------
Deviatio n = 1-Mp²/(Me+Mp)² = Me(Me + 2Mp)/(Me+Mp)² = 3673/1837² = 0.1088%
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