A question concerning derivation of canonical ensemble's probability

In summary, the probability of the system in a microstate Ei with canonical ensemble is proportional to the multiplicity of the reservoir, and it is not a conditional probability. The probability of finding the system in a particular microstate is proportional to the multiplicity of the reservoir, which is the number of ways the reservoir can be arranged so that the total energy of the system and the reservoir is E.
  • #1
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In derivation of probability of system at energy E with canonical ensemble, one assumes that the probability of system in a microstate Ei is proportional to the multiplicity of reservoir. Is this probability the conditional probability by knowing that system is at energy Ei with knowing it is at state Ei? All I see is that probability of finding system in energy E is proportional to product of probabilities of system and reservoir. And for a given energy Ei for a micro state, it is possible that the system can rearrange it into a state which has the same energy but it is another microstate.

Thanks.
 
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  • #2
No, the probability of finding the system at energy Ei is not a conditional probability. It is the probability of finding the system in that microstate given that it has total energy E. The probability of finding the system in a particular microstate is proportional to the multiplicity of the reservoir, which is the number of ways the reservoir can be arranged so that the total energy of the system and the reservoir is E. There is no need to consider the rearrangement of the system into another microstate with the same energy.
 

FAQ: A question concerning derivation of canonical ensemble's probability

What is the canonical ensemble?

The canonical ensemble is a statistical mechanics model used to describe the behavior of a system in thermal equilibrium with a heat bath at a fixed temperature and volume.

What is the derivation of canonical ensemble's probability?

The derivation of canonical ensemble's probability is based on the assumption of equal a priori probabilities for all microstates of the system and the Boltzmann distribution, which relates the energy of a microstate to its probability of occurrence.

What is the importance of the canonical ensemble in statistical mechanics?

The canonical ensemble is important in statistical mechanics as it allows for the calculation of thermodynamic properties of a system in thermal equilibrium, such as the average energy and entropy, without needing to know the specific microstate of the system.

What are the limitations of the canonical ensemble?

The canonical ensemble assumes that the system is in thermal equilibrium and does not take into account any fluctuations or non-equilibrium behavior. It also assumes that all microstates are equally likely, which may not be the case for certain systems.

How does the canonical ensemble relate to other ensembles in statistical mechanics?

The canonical ensemble is one of the three main ensembles used in statistical mechanics, along with the microcanonical and grand canonical ensembles. Each ensemble is used to describe different types of systems and has its own set of assumptions and derivations.

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