AC Stark shift in a 3 level system

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In summary, the AC Stark shift in a three-level system refers to the energy level shifts that occur in quantum systems due to the presence of an oscillating electromagnetic field. This phenomenon arises from the interaction between the field and the atomic states, leading to changes in the energy levels and transition probabilities. It is particularly important in understanding how external fields influence atomic and molecular behavior, impacting applications in quantum optics, laser manipulation, and atomic clocks. The shifts depend on factors such as the frequency and intensity of the field, as well as the specific properties of the three-level system being studied.
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BillKet
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Hello! I want to make sure I got this right. Say we have a 3 level system ordered such that ##E_1<E_2<<E_3## with ##\omega_0 = E_2-E_1##. I use a laser to measure ##\omega_0## (e.g. I scan the laser frequency across the expected location of the resonance and fit that with a Voigt profile, we can ignore any systematic effects of the measurement). If I had just a 2 level system, the center of the peak would be exactly at ##\omega_0##. Now, let's say that the electric field can also couple ##E_2## and ##E_3## (but ##E_1## and ##E_3## can't be coupled in the electric dipole approximation). The formula for the AC Stark shift in this case is given by

$$E_{\mathrm{Stark}} = \frac{\Omega^2\omega}{2(\omega^2-\omega_0^2)}$$

where ##\Omega## is the Rabi frequency of the field between ##E_2## and ##E_3## and ##\omega = E_3-E_2##. In our limit this becomes:

$$E_{\mathrm{Stark}} = \frac{\Omega^2}{2\omega}$$
So the ##E_2## levels gets pushed down (towards the ##E_1##) by this amount. So the resonant frequency in this case will appear to be at:

$$\omega_0-\frac{\Omega^2}{2\omega}$$

Is this right (at least to first order in perturbation theory as the 2 pair of levels are treated independently)? Thank you!
 

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