Angle calculation from Atomic Term Symbol

In summary, the task is to calculate the smallest angle (in degrees) that the total angular momentum of an atom in a 7D term can make with the z-axis. To do so, we first find all possible resultant J values for the term, which are 5, 4, 3, 2, 1. Then, we need to determine the possible values of the total angular momentum and the projection of the angular momentum along the z axis. By maximizing the ratio of jz to ||j||, we can minimize the angle that the total angular momentum makes with the z axis.
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Homework Statement


Calculate the smallest angle (in degrees) that the total angular momentum of an atom in a 7D term can make with the z-axis.


Homework Equations



2S+1LJ

The Attempt at a Solution



Given that the total angular momentum of the atom is defined by the quantum number J, I started by finding all possible resultant J values for the term:

7D:

2(S)+1 = 7
S = 3

D = L = 2

J = { (L+S),(L+S-1), ... , (L-S) }
Thus, J = 5, 4, 3, 2, 1

This is where I'm stuck, I literally have no clue how to go further in the angle calculation. This is a review problem for an exam, and it was never covered in class. Hopefully someone can share some insight. Thanks for any help!
 
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  • #2
Your work is correct so far. When you measure the total angular momentum, what are the possible values? When you measure the projection of the angular momentum along the z axis, what are the possible values? You want the ratio of jz to ||j|| to be as high as possible, in order to minimize the angle that the total angular momentum makes with the z axis.
 

FAQ: Angle calculation from Atomic Term Symbol

How is the angle calculated from an atomic term symbol?

The angle in an atomic term symbol is calculated using the Russell-Saunders coupling scheme, which takes into account the spin and orbital angular momentum of electrons in an atom. The angle represents the orientation of the total angular momentum vector in relation to an external magnetic field.

What does the angle in an atomic term symbol represent?

The angle in an atomic term symbol represents the orientation of the total angular momentum vector, which is the sum of the spin and orbital angular momenta, in relation to an external magnetic field. It is also known as the quantum number J, and it determines the energy levels and spectral lines of an atom.

How is the angle related to the energy levels of an atom?

The angle, or J quantum number, is directly related to the energy levels of an atom. As the angle increases, the energy levels also increase, resulting in higher energy spectral lines. This is due to the fact that the total angular momentum of an atom is related to its energy and stability.

Can the angle be determined experimentally?

Yes, the angle in an atomic term symbol can be determined experimentally through spectroscopic techniques. By analyzing the spectral lines of an atom, the angle can be calculated and used to understand the energy levels and properties of the atom.

How does the angle affect the properties of an atom?

The angle in an atomic term symbol affects the properties of an atom in several ways. It determines the energy levels and spectral lines of the atom, which in turn affects its reactivity, chemical bonding, and overall behavior. It also plays a role in determining the magnetic properties of an atom.

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