- #1
sachin123
- 121
- 0
Hey folks.
The orders given are stated in my book.I'm here to ask why.
basicity: p-methyl aniline>m-()>aniline>o-()
p exerts hyperconjugation and +I,m only +I ,but ortho exerts hyperconjugation and higher +I.
Shouldn't o-methyl aniline have high basicity?
basicity: aniline>m-nitro()>p-nitro()>o-nitro()
Why is o- at last?Shouldn't it move NH2 out of plane so that no -R takes place?
And is the ortho effect applicable to all substituents?Can you clear this for me?
Thank You.
The orders given are stated in my book.I'm here to ask why.
basicity: p-methyl aniline>m-()>aniline>o-()
p exerts hyperconjugation and +I,m only +I ,but ortho exerts hyperconjugation and higher +I.
Shouldn't o-methyl aniline have high basicity?
basicity: aniline>m-nitro()>p-nitro()>o-nitro()
Why is o- at last?Shouldn't it move NH2 out of plane so that no -R takes place?
And is the ortho effect applicable to all substituents?Can you clear this for me?
Thank You.