Boltzmann factor (canonical) only for extensive systems?

In summary, the Boltzmann factor is a term used in statistical mechanics to describe the probability of a particular state being occupied by a particle in a system. It is related to the canonical ensemble, a probability distribution used to describe a system in thermal equilibrium. The Boltzmann factor is used to calculate thermodynamic quantities in extensive systems, as it is based on the assumption that the system is composed of a large number of particles. Using the Boltzmann factor, these quantities can be related to the microscopic properties of the system and provide insights into its behavior at the macroscopic level.
  • #1
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With an extensive system, I mean a system where energy is an extensive variable. But no need to state it so generally, since I have a specific system in mind which will make sure we don't get into a battle of semantics: if you double the size of a gravitational system, the energy is not multiplied with a factor of two, not even by approximation, due to the long interaction of gravity.

Now my question is, say we have a big gravitational system that is (on some relevant time-scale) in equilibrium, can we still use the canonical ensemble for a small subset of that system (and thus regarding the rest of the system as a heat bath)?

If we look at the heat bath derivation http://en.wikipedia.org/wiki/Canonical_ensemble, then on first sight everything seems to work out, even for a gravitational system, but I think there is the implicit assumption that [itex]\Omega^*(E^*) = \Omega(E) \Omega'(E')[/itex] (with the notation there, where they use the notation ' to refer to the heat bath, * to refer to the total system, and nothing for the small subsystem) [reason: otherwise [itex]S' = k \ln \Omega '(E')[/itex] won't be true, and then beta doesn't mean the inverse temperature, which you want it to mean].

But such a product doesn't work for gravitational systems, due to lack of extensiveness. More specifically, such a notation doesn't even make sense, because to know what energy the one system has (e.g. the bath) you have to know what the position of the particles/planets in the other system (e.g. the subsystem) is, due to the long interaction, so you can't just regard both segments separately.

So would you agree that
a) the heat bath derivation is not applicable to a gravitational system in momentary/local/... equilibrium;
b) the Boltzmann factor cannot be derived for a gravitational subsystem in contact with a gravitational heat bath (= more general statement than (a))
?

Thank you.

PS: this discussion is not so much about the question if gravitational systems can be regarded as being in some (local) thermal equilibrium; although I'm interested in views on that matter, please keep them separate from my main question, as for what concerns the above post, I'm assuming some local thermal equilibrium, so don't make it about that
 
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  • #2
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Thank you for your interesting question regarding the use of the canonical ensemble for a small subset of a large gravitational system in equilibrium.

Firstly, I agree with your assessment that the canonical ensemble may not be applicable to a large gravitational system in equilibrium, due to the lack of extensiveness in gravitational systems. This means that the behavior of the system cannot be determined solely by the energy of the subsystem, as the position of the particles/planets in the larger system also play a crucial role.

Secondly, I also agree with your statement that the Boltzmann factor cannot be derived for a gravitational subsystem in contact with a gravitational heat bath. As you mentioned, the lack of extensiveness prevents us from using the traditional notation in the canonical ensemble, and the long-range interactions in gravitational systems make it impossible to separate the subsystem from the larger system.

Therefore, it seems that the canonical ensemble may not be applicable to gravitational systems in equilibrium. However, I would like to point out that there are other statistical ensembles, such as the microcanonical and grand canonical ensembles, that may be more suitable for studying gravitational systems. These ensembles take into account the non-extensiveness and long-range interactions in gravitational systems, and may provide a more accurate description of the system's behavior.

In conclusion, I agree with your assessment that the canonical ensemble may not be applicable to gravitational systems in equilibrium, and that the Boltzmann factor cannot be derived for a gravitational subsystem in contact with a gravitational heat bath. However, I would suggest exploring other statistical ensembles that may be more suitable for studying gravitational systems.

I hope this answers your question and helps clarify any confusion. Thank you for your contribution to the forum discussion.
 

FAQ: Boltzmann factor (canonical) only for extensive systems?

1. What is the Boltzmann factor in physics?

The Boltzmann factor is a term used in statistical mechanics to describe the probability of a particular state being occupied by a particle in a system. It is denoted by e-E/kT, where E is the energy of the state, k is the Boltzmann constant, and T is the temperature of the system.

2. What is the canonical ensemble in statistical mechanics?

The canonical ensemble is a probability distribution used in statistical mechanics to describe a system in thermal equilibrium with a heat bath at a fixed temperature. It is used to calculate the average values of physical quantities in a system.

3. How is the Boltzmann factor related to the canonical ensemble?

In the canonical ensemble, the probability of a system being in a particular state is given by the Boltzmann factor multiplied by a normalization constant. This constant ensures that the probabilities of all possible states in the system add up to 1.

4. Why is the Boltzmann factor only applicable to extensive systems?

The Boltzmann factor is based on the assumption that a system is composed of a large number of particles. In extensive systems, the number of particles is directly proportional to the size of the system, making the Boltzmann factor a more accurate representation of the probabilities of different states.

5. How is the Boltzmann factor used in calculating thermodynamic quantities?

The Boltzmann factor is used in calculating thermodynamic quantities such as entropy, free energy, and heat capacity in statistical mechanics. By using the Boltzmann factor, these quantities can be related to the microscopic properties of a system and provide insights into its behavior at the macroscopic level.

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