Calculate the bonding energy of two ions

In summary, the conversation discusses differentiating and setting equations equal to zero in order to solve for a variable. The conversation also addresses an error in taking the derivative and provides the correct solution. The final result is that ##r = \sqrt[n-3]{\frac{Bn}{A}}## is the correct solution for the equation being discussed.
  • #1
Jaccobtw
163
32
Homework Statement
$$E_N = \frac{-A}{r} + \frac{B}{r^{n}}$$

Calculate the bonding energy ##E_0## in terms of the parameters A, B, and n using
the following procedure:
1. Differentiate ##E_N## with respect to r, and then set the resulting expression equal
to zero, because the curve of ##E_N## versus r is a minimum at ##E_0##.
2. Solve for r in terms of A, B, and n, which yields ##r_0##, the equilibrium interionic
spacing.
3. Determine the expression for ##E_0## by substituting ##r_0## for r
Relevant Equations
$$E_N = \frac{-A}{r} + \frac{B}{r^{n}}$$
1.) So first I differentiate and set it equal to 0 and get:
$$\frac{A}{r^2} -\frac{Bn}{r^{n-1}} = 0$$

2.) When solving for r, I'm not quite sure how to take away the exponent so I get up to the second to last step:

$$r^{n-3} = \frac{Bn}{A}$$

Would it be:

$$r = \sqrt[n-3]{\frac{Bn}{A}}$$

?

Am I doing this problem correctly?

Thank you
 
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  • #2
Correct. You can note the result as ##r_0##, i.e.,
$$
r_0 = \left( \frac{Bn}{A} \right)^{1/(n-3)}
$$
 
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  • #3
Jaccobtw said:
$$E_N = \frac{-A}{r} + \frac{B}{r^{n}}$$
1.) So first I differentiate and set it equal to 0 and get:
$$\frac{A}{r^2} -\frac{Bn}{r^{n-1}} = 0$$
2.) When solving for r, I'm not quite sure how to take away the exponent so I get up to the second to last step:
$$r^{n-3} = \frac{Bn}{A}$$
Would it be:
$$r = \sqrt[n-3]{\frac{Bn}{A}}\ \ \ ?$$
Am I doing this problem correctly?

Thank you
You made an error in taking the derivative.

Writing ##E_N## as ##\displaystyle \quad \quad E_N= -A\,r^{-1} + B\,r^{-n} \quad## may help.

Then ##\displaystyle \quad \quad \dfrac{E_N}{dr}= A\,r^{-2} - B\,r^{-n-1} = A\,r^{-2} - B\,r^{-(n+1)}##

##\displaystyle \quad \quad \quad \quad \quad \quad = \dfrac{A}{r^2} - \dfrac{nB}{r^{(n+1)}} \quad##
 
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FAQ: Calculate the bonding energy of two ions

What is bonding energy in the context of ionic bonds?

Bonding energy, also known as bond dissociation energy, is the amount of energy required to break an ionic bond between two ions in a molecule, separating them into individual, neutral atoms. It is a measure of the strength of the bond.

How do you calculate the bonding energy of two ions using Coulomb's Law?

The bonding energy of two ions can be calculated using Coulomb's Law, which is given by the formula: \( E = \frac{k \cdot Q_1 \cdot Q_2}{r} \), where \( E \) is the bonding energy, \( k \) is Coulomb's constant (\( 8.99 \times 10^9 \, \text{N m}^2 \text{C}^{-2} \)), \( Q_1 \) and \( Q_2 \) are the charges of the ions, and \( r \) is the distance between the centers of the two ions.

What units are typically used for measuring bonding energy?

Bonding energy is typically measured in electron volts (eV) or kilojoules per mole (kJ/mol). When using Coulomb's Law, the energy is often derived in joules (J), which can then be converted to eV or kJ/mol for practical use in chemistry and materials science.

How does the distance between ions affect the bonding energy?

The distance between the ions inversely affects the bonding energy. As the distance \( r \) between the ions increases, the bonding energy decreases. This inverse relationship is described by Coulomb's Law, where the bonding energy is inversely proportional to the distance between the ions.

Can environmental factors influence the bonding energy of two ions?

Yes, environmental factors such as temperature, pressure, and the presence of other substances can influence the bonding energy of two ions. For instance, in a solvent, the effective distance between ions can change due to solvation effects, which can alter the bonding energy. Additionally, thermal agitation at higher temperatures can affect the stability of the ionic bond.

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