Calculating Expectation Values and Uncertainties in Quantum Mechanics

In summary, the conversation discusses calculating the expectation values and uncertainties for a particle in a one-dimensional box in its first excited state. The equations for calculating <x>, <p>, and <E> are given, and the values are determined to be 0 for <x> and <p>, and h_bar*pi^2*n^2/2*m*a^2 for <E>. The question then arises for how to calculate the uncertainties, and the suggestion is made to use the definition of variance. The possibility of approximating the uncertainties using the relation delta(x)=h_bar/sqrt(2m(V0 - E)) is also discussed. It is noted that six expectation values must be calculated in order to determine the uncertainties, and
  • #1
ynuo
18
0

Homework Statement



Assume that a particle in a one-dimensional box is in its first excited state. Calculate the expectation values [x], [p], and [E], and the uncertainties
delta(x), delta(p), and delta(E). Verify that delta(x)*delta(p)>=h_bar/2.

Homework Equations



Psi=sqrt(2/a) cos(pi*x/a) e^(-i*E*t/h_bar)

[x]=Int(Psi_star x Psi, -a/2, a/2)

[p]=Int(Psi_star (-i*h_bar*d/dx) Psi, -a/2, a/2)

[E]=Int(Psi_star (i*h_bar*d/dt) Psi, -a/2, a/2)

The Attempt at a Solution



After evaluating the above integrals, I get:

[x]=0

[p]=0

[E]=h_bar*pi^2*n^2 / 2*m*a^2

I am trying to calculate the quantities delta(x), delta(p), and delta(E) but I am having trouble doing that. Can you please suggest some hints on how to proceed. Thank you.
 
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  • #2
What are the definitions of delta(x) and delta(p) in terms of expectation values?
 
  • #3
This is a trivial question, but would I be able to approximate it using the relations:

delta(x)=h_bar/sqrt(2m(V0 - E))
 
  • #4
ynuo said:
This is a trivial question, but would I be able to approximate it using the relations:

delta(x)=h_bar/sqrt(2m(V0 - E))

That's a new relation to me. Just look at the definition of the variance and follow the prescription.
 
  • #5
StatMechGuy said:
That's a new relation to me. Just look at the definition of the variance and follow the prescription.

Yep. You need to calculate six expectation values in order to calculate deltax, deltap and deltaE, and only three of them are <x>, <p> and <E>.
 
  • #6
Do you know a reason why [itex] \Delta E [/itex] is zero for this problem ? Besides the actual computation of it, which can be avoided by knowing this reason.
 

FAQ: Calculating Expectation Values and Uncertainties in Quantum Mechanics

What is quantum mechanics?

Quantum mechanics is a branch of physics that studies the behavior of particles at the atomic and subatomic level. It describes how particles such as electrons and photons behave and interact with each other.

How does quantum mechanics differ from classical mechanics?

Classical mechanics describes the behavior of objects on a macroscopic scale, while quantum mechanics explains the behavior of particles on a microscopic scale. Classical mechanics follows deterministic laws, while quantum mechanics introduces probability and uncertainty into the equations.

What are the key principles of quantum mechanics?

The key principles of quantum mechanics include superposition, where particles can exist in multiple states simultaneously, and entanglement, where particles can become linked and affect each other's behavior even at a distance. The Heisenberg uncertainty principle also states that it is impossible to know both the position and momentum of a particle with complete accuracy.

How is quantum mechanics applied in modern technology?

Quantum mechanics has many practical applications, including the development of transistors and computer chips, as well as advancements in cryptography and quantum computing. It also plays a role in fields such as materials science, medical imaging, and telecommunications.

What are the implications of quantum mechanics for our understanding of reality?

Quantum mechanics challenges our traditional understanding of reality by introducing concepts such as non-locality and the observer effect, where the act of observing a particle can change its behavior. It also suggests the existence of parallel universes and the idea that particles can exist in multiple states until observed or measured. These implications are still being studied and debated by scientists.

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