Carbon dioxide as an oscillator; normal modes.

In summary, the conversation discussed setting up and solving equations for the two normal modes of oscillation for a CO2 molecule. The equations were then rearranged in matrix form to find the determinant, which led to the discovery of the two angular frequencies. The first frequency corresponds to a translation of the molecule as a whole, while the other frequency must be solved for using the condition that (w^2m_2-2k)(w^2m-k)-2k^2=0.
  • #1
novop
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Homework Statement



Consider the CO2 molecule as a system made of a central mass [tex]m_2[/tex] connected by equal springs of spring constant k to two masses [tex]m_1[/tex] and [tex]m_3[/tex]

a) set up and solve the equations for the two normal modes in which the masses oscillate along the line joining their centers (the x-axis).

b) putting [tex]m_1[/tex] = [tex]m_3[/tex] = 16 units and [tex]m_2[/tex] = 12 units, what would be the ratio of the frequencies of the two normal modes?

The Attempt at a Solution



I made x_1,x_2 and x_3 the displacement to the right from equilibrium position.

a)
[tex]m_3\frac{d^2x_3}{dt^2} = -k(x_3-x_2)[/tex]
[tex]m_2\frac{d^2x_2}{dt^2} = -k(x_2-x_1) -k(x_2-x_3)[/tex]
[tex]m_1\frac{d^2x_1}{dt^2} = -k(x_1-x_2)[/tex]

Assuming [tex]x_1 = C_1cos(wt), x_2=C_2cos(wt)[/tex] etc...
solving for the double time derivatives and plugging them in above gives:

[tex]w^2C_1m_1=k(x_1-x_2) [/tex]
[tex]w^2C_2m_2=k(x_2-x_1) + k(x_2-x_3) [/tex]
[tex]w^2C_3m_3=k(x_3-x_2)[/tex]

Where do I go from here?
 
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  • #2
Plug in the assumed solution for al xi-s.

ehild
 
  • #3
[tex]w^2C_1m_1=k(C_1-C_2) [/tex]
[tex]w^2C_2m_2=k(2C_2-C_1-C_3)[/tex]
[tex]w^2C_3m_3=k(C_3-C_2)[/tex]

So that's just replacing the x's with C's, considering the cos(wt) terms cancel.
 
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  • #4
Anyone?
 
  • #5
You have a system of linear equations with the unknowns C1, C2, C3. Group the unknowns and arrange the equations in matrix form. [itex]w^2[/itex] is the parameter you have to find so the system of equations has non-zero solution. For that, the determinant of the matrix has to vanish.

ehild
 
  • #6
This is pretty foreign to me; if I make a matrix with columns C1, C2 and C3, for my determinant to be zero, the following must hold true:

[tex](w^2m_1-k)(w^2m_2-2k)(w^2m_3-k)=0[/tex]

How do I solve this? Am I on the right track? I should have added that I need to solve for "w" before plugging in the masses.
 
  • #7
novop said:
This is pretty foreign to me; if I make a matrix with columns C1, C2 and C3, for my determinant to be zero, the following must hold true:

[tex](w^2m_1-k)(w^2m_2-2k)(w^2m_3-k)=0[/tex]

How do I solve this? Am I on the right track? I should have added that I need to solve for "w" before plugging in the masses.

For that equation to hold true, the LHS has to equal the RHS, 0.

If A*B*C=0 then A=0 or B=0 or C=0.
 
  • #8
So then my two modes are [tex]w_1^2=\frac{k}{m_1}=w_3^2[/tex] and [tex]w_2^2=\frac{2k}{m_2}[/tex]?

If this is the case, the ratio between these two frequencies isn't giving me what the textbook says.
 
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  • #9
novop said:
This is pretty foreign to me; if I make a matrix with columns C1, C2 and C3, for my determinant to be zero, the following must hold true:

[tex](w^2m_1-k)(w^2m_2-2k)(w^2m_3-k)=0[/tex]

Some terms are missing.

[tex]D=(w^2m_1-k)(w^2m_2-2k)(w^2m_3-k)-k^2(w^2m_1-k)-k^2(w^2m_3-k)=0[/tex]

m1=m3=m, so

[tex]D=(w^2m-k)(w^2m_2-2k)(w^2m-k)-2k^2(w^2m-k)=0[/tex]

Factor out w^2m-k.

[tex]D=(w^2m-k)((w^2m_2-2k)(w^2m-k)-2k^2)=0[/tex]

w^2m-k=0 gives the first angular frequency.

The other possibilities come from the condition that

[tex](w^2m_2-2k)(w^2m-k)-2k^2=0[/tex]

Simplify and solve. One root is w^2=0. This corresponds to a translation of the molecule as a whole. You need the other frequency.

ehild
 
  • #10
Thanks that's perfect.
 

FAQ: Carbon dioxide as an oscillator; normal modes.

What is carbon dioxide as an oscillator?

Carbon dioxide is a molecule that can vibrate in different ways, similar to a pendulum or a spring. This vibration is known as an oscillator and is caused by the movement of the atoms within the molecule.

What are normal modes in carbon dioxide oscillation?

Normal modes refer to the specific patterns of vibration that carbon dioxide molecules can undergo. These modes are determined by the number and arrangement of atoms within the molecule.

How does carbon dioxide act as an oscillator?

Carbon dioxide can act as an oscillator because it contains three atoms that are connected by chemical bonds. These bonds act like springs and allow the molecule to vibrate in different ways.

What are the applications of studying carbon dioxide as an oscillator?

Studying carbon dioxide as an oscillator can help us understand the behavior of molecules and their interactions with energy. This knowledge can be applied in fields such as chemistry, atmospheric science, and material science.

How does the frequency of carbon dioxide oscillation affect its properties?

The frequency of carbon dioxide oscillation is directly related to its properties, such as its ability to absorb and emit infrared radiation. This is important in understanding the role of carbon dioxide in the Earth's climate and atmosphere.

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