Colloid complex refractive index from UV-vis spec

In summary, the study investigates the determination of the complex refractive index of colloidal systems using UV-visible spectroscopy. It emphasizes the relationship between light interaction and the optical properties of colloids, highlighting the importance of analyzing absorption and scattering data to derive accurate refractive index values. The findings suggest that this method provides insights into the size, composition, and behavior of colloidal particles in various applications.
  • #1
CheesyG
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Can I determine the complex refractive index (n + ik) of a colloid via UV-vis spectroscopy?
Hi everyone,

I am wondering, can I use the damped wave approximation for light travelling through a medium along with Beers law to spectroscopically determine a colloid complex refractive index.
Thanks!

Absorbance = exp (- 2πkx/λ) = ecl
 
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  • #2
I think it's possible. You could extract k as a function of wavelength, and then fit a series of Lorentz oscillators to it. This would then give you n. Beware though, if you don't understand the physics of your material, then I'd say that you could end up with numbers that aren't a good match to reality.
 
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