Compare final T of reversible/irreversible equations

In summary, the two equations for the final temperature when two bodies are put into thermal contact, (2.93) and (2.109), have different forms when CA = CB = C. Simplifying the equations by replacing both CA and CB with C, it can be seen that (2.93) yields a higher value for the final temperature compared to (2.109), suggesting that one process may result in a higher final temperature than the other. However, without specific values for TA and TB, it is difficult to determine which process will yield a higher final temperature solely based on the equations.
  • #1
accountkiller
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Homework Statement


Suppose CA = CB = C in equations 2.93 and 2.109 (shown below). Compare the form of expressions for the final temperature.


Homework Equations


(2.93) [itex]T = \frac{C_{A}T_{A} + C_{B}T_{B}}{C_{A} + C_{B}}[/itex]
(2.109) [itex]T = T_{A}^{\frac{C_{A}}{(C_{A}+C_{B})}} T_{B}^{\frac{C_{B}}{(C_{A}+C_{B})}}[/itex]

(2.93) is for an irreversible process
(2.109) is for a reversible process
T is the final equilibrium temperature when two bodies are put into thermal contact.
C is specific heat capacity


The Attempt at a Solution


The problem is that I don't know where to start. I'm told in the sentence before equation (2.93) that in that equation, TA > TB. Other than that, I'm not sure exactly how or what I'm supposed to be deducing about the final temperature just from looking at the two equations. I'm told the answer is that the final temperature will be TA but have no idea why. What's my first step? How should I start thinking about it?

I'd appreciate any guidance. Thanks :)
 
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  • #2
I'd say that...
If we suppose CA = CB = C, as you're told to, start by just replacing both CA and CB with C, and simplify the formulas:

(2.93) [itex]T = \frac{C T_{A} + CT_{B}}{2C}= \frac{C( T_{A} + T_{B})}{2C}= \frac{ T_{A} + T_{B}}{C}[/itex].

(2.109) [itex]T = T_{A}^{\frac{C}{(2C)}} T_{B}^{\frac{C}{(2C)}}=T_{A} \ ^{\frac{1}{C}} \cdot T_{B} \ ^{\frac{1}{C}}[/itex]

Do you have any further ideas now ?

mbradar2 said:

Homework Statement


Suppose CA = CB = C in equations 2.93 and 2.109 (shown below). Compare the form of expressions for the final temperature.

Homework Equations


(2.93) [itex]T = \frac{C_{A}T_{A} + C_{B}T_{B}}{C_{A} + C_{B}}[/itex]
(2.109) [itex]T = T_{A}^{\frac{C_{A}}{(C_{A}+C_{B})}} T_{B}^{\frac{C_{B}}{(C_{A}+C_{B})}}[/itex]

(2.93) is for an irreversible process
(2.109) is for a reversible process
T is the final equilibrium temperature when two bodies are put into thermal contact.
C is specific heat capacity

The Attempt at a Solution


The problem is that I don't know where to start. I'm told in the sentence before equation (2.93) that in that equation, TA > TB. Other than that, I'm not sure exactly how or what I'm supposed to be deducing about the final temperature just from looking at the two equations. I'm told the answer is that the final temperature will be TA but have no idea why. What's my first step? How should I start thinking about it?

I'd appreciate any guidance. Thanks :)
 
  • #3
mstud said:
I'd say that...
If we suppose CA = CB = C, as you're told to, start by just replacing both CA and CB with C, and simplify the formulas:

(2.93) [itex]T = \frac{C T_{A} + CT_{B}}{2C}= \frac{C( T_{A} + T_{B})}{2C}= \frac{ T_{A} + T_{B}}{C}[/itex].

(2.109) [itex]T = T_{A}^{\frac{C}{(2C)}} T_{B}^{\frac{C}{(2C)}}=T_{A} \ ^{\frac{1}{C}} \cdot T_{B} \ ^{\frac{1}{C}}[/itex]

Do you have any further ideas now ?

If by [itex]\frac{T_{A} + T_{B}}{C}[/itex], you mean [itex]\frac{T_A} + T_{B}}{2}[/itex] for the first one... and replace the C by 2 again in the second one, then yes I realize I can do that. I didn't think to use it here but I did use that in the next question in the homework assignment.. I suppose it would have made more sense to do it here, thanks.

But no, I don't have any further ideas from that. In the next question on the homework, we're given values for TA and TB and I find that plugging them into 2.93 yields a higher resulting value than plugging the same numbers into 2.109, so that tells me something. But without numbers and just looking at the equations above reduced so the C is gone... am I just supposed to be able to deduce from that that one process is higher than the other simply based on math?
 

FAQ: Compare final T of reversible/irreversible equations

What is the main difference between reversible and irreversible equations?

The main difference between reversible and irreversible equations is the direction of the reaction. In reversible reactions, the reaction can proceed in both the forward and reverse directions, while in irreversible reactions, the reaction proceeds only in one direction.

How does the final temperature differ in reversible and irreversible equations?

The final temperature in reversible reactions is usually lower than in irreversible reactions. This is because reversible reactions are able to reach a state of equilibrium where the forward and reverse reactions occur at the same rate, resulting in a lower overall temperature change.

Can the final temperature of a reversible reaction be the same as an irreversible reaction?

No, the final temperature of a reversible reaction can never be the same as an irreversible reaction. This is because reversible reactions reach a state of equilibrium, while irreversible reactions do not, resulting in different final temperatures.

How does the rate of reaction affect the final temperature in reversible and irreversible equations?

The rate of reaction has a significant impact on the final temperature in both reversible and irreversible equations. In reversible reactions, a slower rate of reaction will result in a lower final temperature, as it allows for more time to reach equilibrium. In irreversible reactions, a faster rate of reaction will result in a higher final temperature, as there is no equilibrium state to reach.

Are reversible or irreversible reactions more common in scientific experiments?

Reversible reactions are more common in scientific experiments. This is because they allow for more control and adjustment of the reaction, as well as the ability to study equilibrium states. Irreversible reactions are often used in industrial processes where a specific product is desired and equilibrium is not necessary.

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