Coupled Angular Momentum sates and probability

In summary, the conversation discusses the joint probability of finding two p electrons in the coupled angular momentum states with a specific m value. The conversation also mentions the application of the L- operator and the theorem of Clebsch & Gordan. The notation used includes |lml1l2> and |j,m>.
  • #1
Ed Quanta
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0
Two p electrons are in the coupled angular momentum states |lml1l2>=|2,-2,11>. What is the joint probability of finding the two electrons with L1z and L2z?

Here is my thinking,

With m1 + m2 =-2, the expansion becomes

|2,-2,11>= C0-2|1,0>1|1,-2>2 + C-20|1,-2>1|1,0>2 + C-1-1|1,-1>1|1,-1>2

Now I believe I am supposed to apply the L- operator to both sides since L-|2,-2,11>=0 and since L-=L1- + L2- and we apply this to the othner side of the equatio.

However what we get does not look very pretty.

Am I on the right track? And what should I be doing to get the right answer?
 
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  • #2
Remember |m| <= l, so we a state like l=1, m=-2 does not exist.. I think you should just have the last term in your expansion.. (someone correct me if I'm wrong, because it's been a while since I've done this.
 
  • #3
Thanks, you are totally right. I remembered l>=m but forgot that -m where m>l cannot exist. Then wouldn't it just be a 100 perent possibility that -h is the angular moment for L1 and L2?
 
  • #4
I didn't really undertstand much thing of your notation...It would be perfect,if were able to use the latex...
The theorem of Clebsch & Gordan states that
[tex] |j,m\rangle =\sum_{j_{1},j_{2},m_{1},m_{2}} \langle j_{1},m_{1},j_{2},m_{2}|j,m\rangle |j_{1},m_{1},j_{2},m_{2}\rangle [/tex]

,where i hope you're familiar with the notation...

Daniel.
 
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FAQ: Coupled Angular Momentum sates and probability

What is meant by "coupled angular momentum states"?

Coupled angular momentum states refer to the quantum mechanical states of a system where the angular momentum of individual particles is combined or "coupled" to create a total angular momentum for the system.

How are coupled angular momentum states represented mathematically?

In quantum mechanics, coupled angular momentum states are represented using the Clebsch-Gordan coefficients, which describe the relationship between the individual angular momenta of particles and the resulting total angular momentum.

What is the significance of coupled angular momentum states in atomic and molecular systems?

Coupled angular momentum states play a crucial role in determining the energy levels and transitions of atoms and molecules. They also provide insight into the orientation and alignment of these systems in different physical environments.

How does the probability of finding a system in a particular coupled angular momentum state change with time?

The probability of finding a system in a particular coupled angular momentum state is governed by the Schrödinger equation, which describes the time evolution of quantum mechanical systems. The probability can change over time due to the influence of external forces or interactions with other particles.

Can coupled angular momentum states be experimentally observed?

Yes, coupled angular momentum states can be observed through experiments such as spectroscopy, which involves studying the emission or absorption of electromagnetic radiation by atoms and molecules. These states can also be observed through the behavior of particles in magnetic fields or interactions with other particles.

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