Deducing the solution of the von Neumann equation

In summary: The first step is to form the Hamiltonian, which is just the sum of the functional derivatives of the wavefunction. The second step is to determine the eigenvalues and eigenvectors of the Hamiltonian. The third step is to find the wavefunction that corresponds to the eigenvalues and eigenvectors. The fourth step is to solve the wavefunction equation for the given perturbation. The last step is to find the energy of the system.
  • #1
xyver
6
0

Homework Statement


[tex] \hat{\rho}(t)=? [/tex] [tex]
|\psi(t)\rangle=U(t,t_{0})|\psi(t_{0})\rangle [/tex] [tex]
\imath\hbar\partial_{t}\hat{p}=[\hat{H},\hat{\rho}]
[/tex]

Homework Equations


[tex]
\imath\hbar\partial_{t}\hat{p}=[\hat{H},\hat{\rho}] \Leftrightarrow\imath\hbar\partial_{t}\hat{p}=\hat{H}\hat{\rho}-\hat{\rho}\hat{H}
[/tex]

The Attempt at a Solution



I already know the solution: [tex]\hat{\rho}(t)=\hat{U}\hat{\rho}(0)\hat{U}^{+}[/tex]
But where do I get this from? How do I know that I have to write the time evolution operator multiplied once in front of the density operator and once the Hermitian conjugate after it?

Also, I tried to verify the solution:
[tex]\Rightarrow\imath\hbar\partial_{t}\hat{U}\hat{\rho}(0)\hat{U}^{+}=\hat{H}\hat{U}\hat{\rho}(0)\hat{U}^{+}-\hat{U}\hat{\rho}(0)\hat{U}^{+}\hat{H}=[H,\hat{\rho}(t)][/tex]
Can't I take any other operator instead of the time evolution operator at this place, since in my attempt to verify the solution the [itex]\hat{U}[/itex] goes away again?

Or is this just guessing as one way to solve a differential equation. Then, still, how do you get the idea?
 
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  • #2
Why don't you use the definition of the von Neumann density operator ?
 
  • #3
The definition should be [itex]\hat{\rho}=\sum_{i}p_{n}|\psi(t)\rangle\langle\psi(t)|[/itex]
I can do with that:
[tex]\partial_{t}\hat{\rho}=\partial_{t}\sum_{i}p_{n}| \psi(t)\rangle\langle\psi(t)|+ \sum_{i} p_{n}|\psi(t) \rangle\partial_{t}\langle\psi(t)| \Leftrightarrow[/tex][tex]

\partial_{t}\hat{\rho}=\frac{1}{\imath\hbar}Hp_{n}|\psi(t)\rangle\langle\psi(t)|+\sum_{i}p_{n}|\psi(t)\rangle\frac{1}{\imath\hbar}H\langle\psi(t)| \Leftrightarrow[/tex][tex]
\partial_{t}\hat{\rho}=\frac{1}{\imath\hbar}\hat{H}p_{n}|\psi(t)\rangle\langle\psi(t)|+\frac{1}{ \imath\hbar}\sum_{i}p_{n}|\psi(t)\rangle\langle \psi(t)\hat{H}|[/tex]
 
  • #5


As a scientist, it is important to understand the underlying principles and reasoning behind a solution, rather than just memorizing it. In this case, the solution to the von Neumann equation can be deduced from the fact that it describes the time evolution of a quantum system. The time evolution operator, \hat{U}, is defined as the operator that transforms a state at time t_0 to a state at time t. Therefore, it makes sense that it would be involved in the solution to the von Neumann equation, as it represents the time evolution of the system.

Furthermore, the von Neumann equation is essentially a differential equation, and the solution to a differential equation involves finding an operator that satisfies the equation. In this case, the time evolution operator, \hat{U}, satisfies the equation and therefore can be used as the solution.

As for your attempt to verify the solution, it is important to remember that the time evolution operator, \hat{U}, is not just any operator, but specifically the operator that describes the time evolution of the system. Therefore, it is the only operator that can be used in the solution to the von Neumann equation.

In summary, the solution to the von Neumann equation can be deduced from the principles of quantum mechanics and the fact that it is a differential equation. The time evolution operator, \hat{U}, is an integral part of the solution as it represents the time evolution of the system.
 

FAQ: Deducing the solution of the von Neumann equation

What is the von Neumann equation?

The von Neumann equation is a mathematical equation that describes the time evolution of a quantum mechanical system. It was developed by physicist John von Neumann in the 1920s and is used to study the behavior of quantum systems.

What does the von Neumann equation represent?

The von Neumann equation represents the evolution of a quantum state over time. It describes how the state of a quantum system changes in response to external influences, such as measurements or interactions with other systems.

How is the von Neumann equation used in science?

The von Neumann equation is used in many areas of science, including quantum mechanics, quantum chemistry, and quantum information theory. It is a fundamental tool for understanding the behavior of quantum systems and is essential for predicting and analyzing their properties.

What are some important implications of the von Neumann equation?

One of the most important implications of the von Neumann equation is that it shows how measurements can affect the state of a quantum system. It also demonstrates the concept of superposition, where a system can exist in multiple states simultaneously.

Are there any limitations to the von Neumann equation?

Yes, there are some limitations to the von Neumann equation. It assumes that the quantum system is in a pure state and does not take into account external factors such as environmental noise. It also does not fully explain the collapse of the wave function, which is a phenomenon observed in quantum measurements.

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