Degenerate Perturbation: Calculating Eigenvalues

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In summary, the conversation discusses a model hamiltonian with unperturbed eigenvalues E1 and E2 = E3 that is subjected to a perturbation V with specific matrix elements. The problem at hand is to calculate the corrected eigenvalues, but in the degenerate subspace, diagonalizing V seems to be impossible due to all matrix elements being zero. It is suggested that a higher order correction may be needed to lift the degeneracy. The conversation ends with a suggestion to use the usual method of diagonalization by solving the characteristic equation, which results in three non-degenerate eigenvalues.
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ergospherical
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Say a model hamiltonian with unperturbed eigenvalues E1 and E2 = E3 is subjected to a perturbation V such that V12 = V21 = x and V13 = V31 = x2, with all other elements zero. I'm having trouble calculating the corrected eigenvalues. In the degenerate subspace spanned by |2> and |3> I need to diagonalise V, but all of these matrix elements are zero?
 
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It sounds like the first-order correction is zero, and you'll need to go to higher orders to lift the degeneracy.
 
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If I understand you correctly, you have a perturbed matrix of the form $$H=\begin{pmatrix}
E_1 & V_{12} & V_{13} \\
V_{12}& E_2 & 0 \\
V_{13} & 0 & E_2
\end{pmatrix}.$$Why can you not diagonalize the usual way? Just say$$\det\begin{bmatrix}
E_1-\lambda & V_{12} & V_{13} \\
V_{12}& E_2-\lambda & 0 \\
V_{13} & 0 & E_2-\lambda
\end{bmatrix}=0$$ and solve the characteristic equation. That is easy to do because it factors into ##(E_2-\lambda)## times a quadratic in ##\lambda.## You get three non-degenerate eigenvalues.
 
  • #4
First of all, there is no reason not to make a rotation in the degenerate subspace such that ##V_{13} = 0##. After that rotation it should be clear that ##E_2## is still an eigenvalue for one state. You can then apply non-degenerate perturbation theory to the remaining 2-dimensional subspace.
 

FAQ: Degenerate Perturbation: Calculating Eigenvalues

What is degenerate perturbation theory?

Degenerate perturbation theory is a method used in quantum mechanics to handle systems where two or more eigenstates of the unperturbed Hamiltonian have the same eigenvalue, i.e., they are degenerate. The perturbation can lift this degeneracy, leading to a splitting of the energy levels. This theory helps in calculating the new energy levels and the corresponding eigenstates when a small perturbation is applied to such a system.

How do you identify degeneracy in a Hamiltonian?

Degeneracy in a Hamiltonian is identified when two or more eigenstates share the same eigenvalue. Mathematically, if the Hamiltonian H has eigenstates |ψ_i⟩ and |ψ_j⟩ such that H|ψ_i⟩ = E|ψ_i⟩ and H|ψ_j⟩ = E|ψ_j⟩ with E being the same for both states, then the system is said to be degenerate with respect to the eigenvalue E.

What is the first step in applying degenerate perturbation theory?

The first step in applying degenerate perturbation theory is to identify the degenerate subspace of the unperturbed Hamiltonian. This involves finding all the eigenstates that correspond to the same eigenvalue. Once the degenerate subspace is identified, one constructs the perturbation matrix within this subspace using the perturbing Hamiltonian.

How do you construct the perturbation matrix in the degenerate subspace?

To construct the perturbation matrix in the degenerate subspace, you take the perturbing Hamiltonian H' and compute its matrix elements between the degenerate states. If |ψ_i⟩ and |ψ_j⟩ are the degenerate eigenstates of the unperturbed Hamiltonian, the matrix elements are given by H'_{ij} = ⟨ψ_i|H'|ψ_j⟩. This results in a matrix that can be diagonalized to find the corrections to the energy levels and the new eigenstates.

How are the new energy levels and eigenstates determined in degenerate perturbation theory?

The new energy levels and eigenstates are determined by diagonalizing the perturbation matrix constructed within the degenerate subspace. The eigenvalues of this matrix give the first-order corrections to the degenerate energy levels, and the corresponding eigenvectors provide the new eigenstates in the presence of the perturbation. This process effectively lifts the degeneracy and provides a more accurate description of the system under the influence of the perturbation.

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