What is the Density of States for Electrons in Metal?

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The density of states for electrons in metals can be derived by treating them as a quantum ideal gas, leading to the expression N(E) = (πV/2)(8m/h²)^(3/2)√E. The factor of two in the final formula accounts for the two possible spin states of each electron. A user also seeks assistance in calculating the density of states from phonon dispersion relations after computing the vibrations of crystals. The discussion emphasizes the importance of recognizing spin states in density calculations. Overall, the conversation highlights the mathematical derivation and practical applications of density of states in solid-state physics.
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Consider electrons in metal as a quantum ideal gas, the quantized energy would be

<br /> E(n_x, n_y, n_z) = \frac{h^2}{8m}\left(\frac{n_x^2}{L_x^2} + \frac{n_y^2}{L_y^2} + \frac{n_z^2}{L_z^2}\right)<br />

Now, letting

<br /> \alpha = \frac{n_x}{L_x}, \qquad \beta = \frac{n_y}{L_y}, \qquad \gamma = \frac{n_z}{L_z}<br />

and

<br /> \rho^2 = \alpha^2 + \beta^2 + \gamma^2<br />

and setting up an coordinate with \alpha, \beta, \gamma. One could see that the volume b/w E-E+dE is proportional to the volume b/w \rho - \rho + d\rho

Note that the volume within \rho - \rho + d\rho is just one-eighth of the volume of the spherical shell with thickness d\rho, namely,

V_\rho = \frac{4\pi \rho^2 d\rho}{8}

Hence, the density of states within \rho - \rho + d\rho becomes

N(\rho)d\rho = \frac{V_\rho}{\textnormal{volume per state}} = \frac{4\pi\rho^2d\rho /8}{1/V} = \frac{\pi V \rho^2 d\rho}{2}

Well, we know that

E = \frac{h^2}{8m}\rho^2

in addition

<br /> N(\rho)d\rho = N(E)dE <br />

which gives

<br /> N(E) = \frac{1}{2}\frac{\pi V}{2}\left(\frac{8m}{h^2}\right)^{3/2}\sqrt{E}<br />

But the correct answer for density of state in energy should be (two times of the above reuslt), i.e.

<br /> N(E) = \frac{\pi V}{2}\left(\frac{8m}{h^2}\right)^{3/2}\sqrt{E}<br />

Where is the '2' come from?

Someone suggests

N(\rho)d\rho = 2\times\frac{\pi V \rho^2 d\rho}{2}

This will give the correct answer, but where is "2" come form?
 
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Each electron has two possible spin states.
 
Avodyne said:
Each electron has two possible spin states.

Oh, how can I forget that! Thanks a lot :)
 
Can someone help me calculating the density of states from phonon dispersion relations.
I have computed the phonon dispersion relations from considering the vibrations of crystals. Now as a next step, i want to compute the density of states. not sure how.
many thanks in advance for your help
 
Time reversal invariant Hamiltonians must satisfy ##[H,\Theta]=0## where ##\Theta## is time reversal operator. However, in some texts (for example see Many-body Quantum Theory in Condensed Matter Physics an introduction, HENRIK BRUUS and KARSTEN FLENSBERG, Corrected version: 14 January 2016, section 7.1.4) the time reversal invariant condition is introduced as ##H=H^*##. How these two conditions are identical?

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