Deriving Even Function Solutions to TISE

In summary, Daniel tried to prove that every solution to the time-independent Schrödinger equation is either even or odd, but he was unable to solve the equation. He then tried to prove that if the potential V(x) is an even function, then \psi(-x) is also a solution to same equation (same E and V). However, he was unable to show that the energies are nondegenerate.
  • #1
broegger
257
0
Suppose that [tex]\psi (x)[/tex] is some solution to the time-independent Schrödinger equation;

[tex]-\frac{h^2}{2m}\frac{\partial^2\psi(x)}{\partial x} + V(x)\psi(x) = E\psi(x)[/tex].​

I want to show that if the potential V(x) is an even function, then [tex]\psi(-x)[/tex] is also a solution to same equation (same E and V).

I know I'm supposed to combine the facts that [tex]\psi(x)[/tex] is a solution and that V(x) = V(-x), but I can't see how. I've noted that

[tex]\frac{\partial^2\psi(-x)}{\partial x} = \frac{\partial^2\psi(x)}{\partial x}[/tex],​

but that's pretty much it :confused:
 
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  • #2
Your last formula contains 2 typo's.You may want to repair it,because it's pretty important to the proof itself...

Daniel.
 
  • #3
Try simply making the substitution [tex]x\to-x[/tex] in the SWE, then using the fact that [tex]V(-x)=V(x)[/tex]. The new form should then show directly that [tex]\psi(-x)[/tex] is a solution as well, since it satisfies the wave equation.
 
  • #4
Yes,the way it's written and the condition imposed upon the potential energy,then the total Hamiltonian is parity invariant and of course the parity operator and the Hamiltonian commute,ergo they admit a complete set of eigenvectors...End proof... :wink:

Daniel.
 
  • #5
The proof also needs to show that the energies are nondegenerate.
 
  • #6
Galileo said:
The proof also needs to show that the energies are nondegenerate.

What?Please,explain...I may be tired and i may not see it...

Daniel.
 
  • #7
dextercioby said:
What?Please,explain...I may be tired and i may not see it...

Daniel.
Nevermind. I didn't read the actual question. I thought it said 'every solution to the SE is either even or odd'.
 
  • #8
I've tried the substitution-thing - that was my first approach, I couldn't make it work. I'm too tired now, maybe I'll work it out tomorrow - thanks for your replies.
 
  • #9
Weird,the way i see it,it's immediate... :rolleyes: Anyway,i see that u didn't noticed.
[tex] \frac{\partial^{2} \psi}{\partial x} [/tex]

is not correct.An essential "2" is missing...

Daniel.
 
  • #10
Oh, yea, of course. My problem is that I don't know exactly what to end up with actually. Should I prove this:

[tex]\frac{\partial^2\psi(-x)}{\partial x^2} + V(x)\psi(-x) = E\psi(-x)[/tex]​

or this:

[tex]\frac{\partial^2\psi(-x)}{\partial x^2} + V(-x)\psi(-x) = E\psi(-x)[/tex]​

The essential difference being the minus in the potential function. Maybe it's because I'm tired (I am!), but I can't quite figure out?
 
  • #11
They're equal,because the potential is parity invarint,viz.
[tex] V(x)=V(-x) [/tex]

Daniel.
 
  • #12
Oh, yea, I'm going to lie down now :smile:
 

FAQ: Deriving Even Function Solutions to TISE

What is the TISE equation and why is it important in science?

The Time-Independent Schrodinger Equation (TISE) is a mathematical equation used in quantum mechanics to describe the behavior of a particle in a given potential. It is important because it allows us to calculate the energy levels and wave functions of a quantum system, providing insight into the behavior of atoms, molecules, and other subatomic particles.

What does it mean for a solution to the TISE equation to be an even function?

An even function is a mathematical function that is symmetric about the y-axis, meaning that f(x) = f(-x). Therefore, an even function solution to the TISE equation would have a wave function that is symmetrical about the origin, indicating that the probability of finding the particle is the same at equal distances on either side of the origin.

How do you derive even function solutions to the TISE equation?

To derive even function solutions to the TISE equation, we must impose the condition that the potential energy function is an even function. This means that the potential energy must remain the same when the position of the particle is reflected across the y-axis. By solving the TISE equation with this condition, we can obtain the wave function for even states.

What are some examples of potential energy functions that would result in even function solutions to the TISE equation?

Examples of potential energy functions that would result in even function solutions to the TISE equation include the infinite square well potential, the harmonic oscillator potential, and the particle in a box potential. These potentials are symmetric about the origin and therefore satisfy the condition for even function solutions.

How are even function solutions to the TISE equation related to the symmetry of physical systems?

The even function solutions to the TISE equation are related to the symmetry of physical systems because they reflect the symmetrical nature of the potential energy function. This symmetry can be observed in the behavior and properties of atoms and molecules, providing insight into the underlying physical structures and processes at the quantum level.

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