Dirac Notation for Operators: Ambiguity in Expectation Values?

In summary, the notation can be slightly ambiguous when dealing with non-Hermitian operators and it is important to specify the operator explicitly to avoid confusion.
  • #1
dyn
773
62
Hi
If A is a linear operator but not Hermitian then the expectation value of A2 is written as < ψ | A2| ψ >. Now if i write A2 as AA then i have seen the expectation value written as < ψ | A+A| ψ > but if i only apply the operators to the ket , then could i not write it as < ψ | AA | ψ > ? In other words is the notation slightly ambiguous ?
Thanks
 
Physics news on Phys.org
  • #2
dyn said:
Hi
If A is a linear operator but not Hermitian then the expectation value of A2 is written as < ψ | A2| ψ >. Now if i write A2 as AA then i have seen the expectation value written as < ψ | A+A| ψ > but if i only apply the operators to the ket , then could i not write it as < ψ | AA | ψ > ? In other words is the notation slightly ambiguous ?
Thanks
If A is not Hermitian, then ##AA \neq A^{\dagger} A##, so you can't write it that way.

-Dan
 
  • Like
Likes vanhees71
  • #3
I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
 
  • #4
dyn said:
I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
The same way you did in the OP:
##\langle A^2 \rangle = \langle \psi \mid A^2 \mid \psi \rangle \equiv \langle \psi \mid AA \mid \psi \rangle##

You would have to calculate ##\mid \phi \rangle = A \mid \psi \rangle##, then ##\mid \zeta \rangle = A \mid \phi \rangle##, then finally ##\langle \psi \mid \zeta \rangle##.

That's as far as you can go until you specify what the operator A looks like.

-Dan
 
  • Like
Likes malawi_glenn and dyn
  • #5
topsquark said:
The same way you did in the OP:
##\langle A^2 \rangle = \langle \psi \mid A^2 \mid \psi \rangle \equiv \langle \psi \mid AA \mid \psi \rangle##

You would have to calculate ##\mid \phi \rangle = A \mid \psi \rangle##, then ##\mid \zeta \rangle = A \mid \phi \rangle##, then finally ##\langle \psi \mid \zeta \rangle##.

That's as far as you can go until you specify what the operator A looks like.

-Dan
Alternatively, you can calculate
$$
\begin{align*}
\ket{\phi} &= A \ket{\psi} \\
\ket{\chi} &= A^\dagger \ket{\psi} \\
\braket{\psi | A^2 | \psi} &= \braket{\chi| \phi}
\end{align*}
$$
 
  • Like
Likes topsquark and malawi_glenn
  • #6
dyn said:
I might be confusing myself here but if A is not Hermitian and A2 = AA and A3 = AAA then how do i write the expectation values of these 2 quantities ?
For a pure state, represented by a normalized vector ##|\Psi \rangle## expectation value is
$$\langle f(\hat{A}) = \langle \Psi|f(\hat{A}) \Psi \rangle=\langle f(\hat{A})^{\dagger} \Psi|\Psi \rangle,$$
for an arbitrary function ##f(\hat{A})##. It doesn't matter whether the operator is self-adjoint or not for the identity of the two expressions. Of course, such an operator cannot represent an observable to begin with, and you might argue that it doesn't make sense to call this expression an "expectation value" in the first place.
 
  • Like
Likes topsquark

FAQ: Dirac Notation for Operators: Ambiguity in Expectation Values?

What is Dirac notation and how is it used in quantum mechanics?

Dirac notation, also known as bra-ket notation, is a standard mathematical notation used to describe quantum states and operators in quantum mechanics. It uses symbols such as |ψ⟩ (ket) to represent state vectors and ⟨φ| (bra) to represent dual vectors. This notation simplifies the representation of complex quantum states and operations, making it easier to perform calculations involving inner products, outer products, and expectation values.

What are operators in the context of Dirac notation?

In Dirac notation, operators are mathematical entities that act on quantum states to produce other quantum states. They are often denoted by symbols such as  or Ĥ. Operators can represent physical observables like momentum, position, or energy. When an operator acts on a ket |ψ⟩, it transforms it into another ket, and when it acts on a bra ⟨φ|, it transforms it into another bra. Operators are essential for calculating measurable quantities in quantum mechanics.

What is an expectation value in quantum mechanics?

An expectation value is the average value of a physical quantity that one would expect to measure in a quantum system. It is calculated using the operator corresponding to that physical quantity and the quantum state of the system. In Dirac notation, the expectation value of an operator  in a state |ψ⟩ is given by ⟨ψ|Â|ψ⟩. This value provides important information about the probable outcomes of measurements on the quantum system.

What causes ambiguity in expectation values in Dirac notation?

Ambiguity in expectation values can arise from several sources, such as improper definition of the operator, issues with the domain of the operator, or the presence of degeneracies in the quantum state. Additionally, if the quantum state is not properly normalized or if the operator is not Hermitian, the calculation of expectation values can become ambiguous. Ensuring that operators are well-defined and states are properly normalized is crucial to avoid such ambiguities.

How can ambiguities in expectation values be resolved?

To resolve ambiguities in expectation values, it is important to ensure that operators are Hermitian, as Hermitian operators have real expectation values and correspond to observable quantities. Additionally, the quantum states should be properly normalized, and the operators should be well-defined within the domain of the states they act upon. Careful mathematical rigor and adherence to the principles of quantum mechanics can help in resolving these ambiguities.

Similar threads

Replies
8
Views
473
Replies
1
Views
1K
Replies
57
Views
5K
Replies
6
Views
4K
Replies
9
Views
2K
Replies
1
Views
1K
Back
Top