Enthalpy: A Measure of Total Energy in a System

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In summary, enthalpy is a measure of the total energy of a thermodynamic system, including the internal energy and the energy required to establish its volume and pressure. The energy required to combine constituent elements to form a substance is known as standard enthalpy of formation in chemistry. However, the concept of enthalpy itself can be confusing, as seen in various definitions from sources such as Wikipedia and textbooks.
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boobybobble
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Hi, i was studying about enthalpy earlier and found its definition to be confusing

"Enthalpy is a measure of the total energy of a thermodynamic system. It includes the internal energy, which is the energy required to create a system, and the amount of energy required to make room for it by displacing its environment and establishing its volume and pressure. "

i don't understand the italicized part...how can internal energy create a system?? :confused:
 
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Hello boobybobble, welcome to Physics Forums.

Your definition of enthalpy was a bit unusual, where did it come from?

In respect of your actual question this probably refers to the use of enthalpy in chemistry where there is a standard enthalpy of formation for every substance.
This is the energy required to combine the various constituent elements to form the substance.

http://en.wikipedia.org/wiki/Standard_enthalpy_of_formation

go well
 
  • #3
Studiot said:
Hello boobybobble, welcome to Physics Forums.

Your definition of enthalpy was a bit unusual, where did it come from?

In respect of your actual question this probably refers to the use of enthalpy in chemistry where there is a standard enthalpy of formation for every substance.
This is the energy required to combine the various constituent elements to form the substance.

http://en.wikipedia.org/wiki/Standard_enthalpy_of_formation

go well

thanks Studiot :smile:

http://en.wikipedia.org/wiki/Enthalpy -->thats where i got the definition from

As for the link you posted, it elaborates on "enthalpy of formation", which is something like enthalpy of -evaporation condensation and blah blah...but I'm talking about the entity enthalpy itself, which is pretty confusing given the definition in wikipedia and a lot of other websites(and my book too).
 

FAQ: Enthalpy: A Measure of Total Energy in a System

What is enthalpy?

Enthalpy is a thermodynamic property that measures the total energy of a thermodynamic system. It is commonly denoted as H and is a combination of the system's internal energy and the product of its pressure and volume.

How does enthalpy create a system?

Enthalpy does not create a system, rather it is a property that describes the energy of a system. The system itself can be created through various processes such as chemical reactions or phase changes.

What role does enthalpy play in chemical reactions?

Enthalpy is an important factor in determining the direction and extent of chemical reactions. Reactions that release energy (exothermic) have a decrease in enthalpy, while reactions that require energy (endothermic) have an increase in enthalpy.

How is enthalpy measured?

Enthalpy is typically measured in joules (J) or kilojoules (kJ) in the SI system. It can also be measured in calories (cal) in the cgs system. Enthalpy changes can be determined experimentally through calorimetry or calculated using thermodynamic equations.

Can enthalpy be negative?

Yes, enthalpy can be negative. A negative enthalpy indicates an exothermic process, where energy is released from the system. This can occur in reactions such as combustion or in phase changes from gas to liquid.

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