Equilibrium Constant: Multiplying Concentrations Explained

In summary, the conversation discusses the use of the equilibrium constant in a chemical equilibrium and the formula for calculating it. The question of why the concentrations are multiplied is raised, and it is explained that this is because the amount of collisions between molecules is directly proportional to the concentration.
  • #1
carrera901
2
0
Hey all

I have trouble understanding something about the Equilibrium constant.

If you have this chemical equilibrium:

pA + qB [tex]\Leftrightarrow[/tex] rC + sD

You can define the equilibrium constant with

[C]r [D]s
______ = K
[A]p q

I don't understand why you multiply the concentrations, can anyone explain?

I'm very sorry if this is a very dumb question and sorry for my english

And no idea why the arrow goes up :-p
 
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  • #2
Use LaTeX

[tex]K = \frac {[A]^p^q} {[C]^r[D]^s} [/tex]

I am not sure what you are asking about.

Are you asking why it is defined this way? Because it was defined this way :smile:

Are you asking why it works? That's a much better question. As a first approximation you may assume that's because to react molecules have to collide and amount of collisions is directly proportional to the concentration.

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FAQ: Equilibrium Constant: Multiplying Concentrations Explained

1. What is the equilibrium constant?

The equilibrium constant, denoted as Keq, is a measure of the equilibrium position of a chemical reaction. It is the ratio of the concentration of products to the concentration of reactants at equilibrium, with each concentration raised to the power of its coefficient in the balanced chemical equation.

2. How is the equilibrium constant calculated?

The equilibrium constant is calculated by dividing the concentration of products by the concentration of reactants at equilibrium. This can be determined experimentally or by using the equilibrium constant expression, which takes into account the stoichiometry of the reaction.

3. What is the significance of the equilibrium constant?

The equilibrium constant provides information about the direction and extent of a chemical reaction. A large equilibrium constant (>1) indicates that the reaction primarily proceeds in the forward direction, while a small equilibrium constant (<1) indicates that the reaction primarily proceeds in the reverse direction. The magnitude of Keq also indicates the relative concentrations of products and reactants at equilibrium.

4. How does multiplying concentrations affect the equilibrium constant?

Multiplying concentrations of reactants or products by a constant factor will result in a new equilibrium constant, which is the original equilibrium constant raised to the power of the constant factor. This is because the equilibrium constant takes into account the molar ratios of products and reactants, and multiplying one side of the equation by a constant will also change the molar ratios.

5. Why is it important to understand the concept of multiplying concentrations when calculating the equilibrium constant?

Understanding the concept of multiplying concentrations is important because it allows for the prediction of how changes in concentration will affect the equilibrium position of a reaction. It also helps in determining the appropriate equilibrium constant expression to use for a given reaction, as well as in solving equilibrium problems involving changing concentrations.

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