Evaluating the Coulomb Integral for a two-electron atom

In summary, the Direct Integral C in the theory of the 2-electron atom can be evaluated by using the ground state for both particles and expanding the \frac{1}{\left|\vec{r}_1-\vec{r}_2\right|} term. The variational principle may also be helpful in solving this problem.
  • #1
yelneerg
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Homework Statement



Evaluate the so-called Direct (or Coulomb) Integral, C, which occurs in the theory of the 2-electron atom.


C=[itex]\int\int d\vec{r}_1d\vec{r}_2\left|\phi_a(1)\right|^2\left|\phi_b(2)\right|^2 \frac{e^2}{\left|\vec{r}_1-\vec{r}_2\right|}[/itex]

You may assume that both particles are in the ground state.

Homework Equations



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The Attempt at a Solution



I'm really just at a loss as to how to get started. I'm guessing that being in the ground state simplifies something. Maybe expand the [itex]\frac{1}{\left|\vec{r}_1-\vec{r}_2\right|}[/itex] bit?
 
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  • #2
I think I may need to use variational principle?
 

FAQ: Evaluating the Coulomb Integral for a two-electron atom

What is the Coulomb Integral for a two-electron atom?

The Coulomb Integral for a two-electron atom is a mathematical expression that calculates the potential energy between two electrons in an atom. It takes into account the electrostatic interaction between the electrons and the distance between them.

How is the Coulomb Integral calculated?

The Coulomb Integral is calculated using a specific formula that takes into account the charge of the electrons, their distance from each other, and other parameters such as atomic number and nuclear charge.

Why is evaluating the Coulomb Integral important in studying atoms?

Evaluating the Coulomb Integral is important because it helps us understand the interactions between electrons in an atom. This is crucial in understanding the electronic structure of atoms and how they behave in different environments.

Are there any limitations to evaluating the Coulomb Integral?

Yes, there are limitations to evaluating the Coulomb Integral. It is based on certain assumptions and approximations, such as the electrons being in a static state and the effects of relativity and quantum mechanics being neglected.

Can the Coulomb Integral be used to study multi-electron atoms?

Yes, the Coulomb Integral can be used to study multi-electron atoms. However, the calculations become more complex as the number of electrons increases, and additional factors such as electron-electron repulsion must be taken into account.

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