Factors of interaction between atoms

In summary, the strength of interactions between two atoms is determined by several factors including electronegativity, orbital completion and octet rule, acid/base properties, symmetry, redox potential, and the distance between atoms. Other nearby atoms may also affect the interaction, particularly in the case of enzymes and catalysts. However, the specifics of these factors can vary greatly, making it a complex and extensive topic in physical and computational chemistry.
  • #1
mather
146
0
hello!

I want to know which factors determine the strength of interactions between two atoms (which both or one or none can be a part of a bigger molecule)

thanks
 
Chemistry news on Phys.org
  • #2
this gets very complicated very fast. It is not a simple problem at all. But in general the greater the difference of electronegativity between 2 atoms, the stronger their bond will be.
 
  • #3
what is complicated about it?
I just need a complete list of all the factors, not explanation of each one
 
  • #4
because there's a lot of exceptions especially for transition metals.

but in general these are useful:

electronegativity
orbital completion and octet rule
acid/base
symmetry
redox potential
 
  • #5
distance?
other atoms near?
 
  • #6
distance: they have to be pretty close. typical bond lengths are nanometers and there's no way that something on one side of the room can "immediately" react with something on the other side. what happens is that one thing is a "source" of reactant molecules/atoms and it diffuses to the other reactants. but usually we don't care about distance because in a chemical plant in New Orleans we don't care what's going on in Seattle; anything that's relevant to the reaction is already there and can be accounted for with diffusion and convection.

other atoms nearby: usually doesn't matter except for 2 things: enzymes and catalysts, but neither are atoms.
 
  • #7
chill_factor said:
because there's a lot of exceptions especially for transition metals.

but in general these are useful:

electronegativity
orbital completion and octet rule
acid/base
symmetry
redox potential

acid/base isn't a matter of electronegativity?
redox potential isn't a matter of electronegativity?

chill_factor said:
other atoms nearby: usually doesn't matter except for 2 things: enzymes and catalysts, but neither are atoms.

in any large organic molecule, nearby atoms don't affect the atoms and thus their interaction between them?
 
  • #8
anyone?
 
  • #9
mather said:
anyone?

What are you actually asking here? Your question is so vague that it's impossible to answer. "Factors of interaction between atoms" is basically a huge portion of physical chemistry and the entirely of computational/quantum chemistry depending on what level of detail you want. Unless you clarify what you're asking the only proper answer is "Take four years of undergraduate chemistry followed by a PhD in physical chemistry".
 

Related to Factors of interaction between atoms

1. What are the main factors that affect the interaction between atoms?

The main factors that affect the interaction between atoms are the distance between atoms, the strength of the attractive and repulsive forces between atoms, the electronic structure of the atoms, and the presence of any external influences such as temperature or pressure.

2. How does the distance between atoms affect their interaction?

The closer two atoms are to each other, the stronger the attractive forces between them become. This is due to the overlap of electron clouds and the resulting increase in electrostatic forces. As the distance between atoms increases, the strength of the interaction decreases.

3. What role does the electronic structure of atoms play in their interaction?

The electronic structure of atoms determines the number and arrangement of electrons, which in turn affects the strength and type of interactions between atoms. For example, atoms with a full outer electron shell tend to be stable and have weaker interactions, while atoms with incomplete outer shells are more reactive and have stronger interactions.

4. How do attractive and repulsive forces between atoms influence their interaction?

Attractive forces, such as Van der Waals forces and hydrogen bonds, pull atoms closer together and promote interactions. On the other hand, repulsive forces, like the Pauli exclusion principle and Coulomb's law, push atoms apart and can prevent them from interacting. The balance between these two types of forces determines the overall strength of the interaction between atoms.

5. Can external influences, such as temperature or pressure, affect the interaction between atoms?

Yes, external influences can significantly impact the interaction between atoms. For example, increasing temperature can cause atoms to vibrate more vigorously, weakening their interactions. Similarly, high pressure can compress atoms and bring them closer together, increasing the strength of their interactions.

Back
Top