Finding the work function using stop potential

In summary, the conversation discusses a photoelectric-effect experiment and solving for the work function of the cathode. After plugging in all the necessary values into the equation, the resulting value for the work function is 6.21, which does not match any of the available options in the given list. The discrepancy is due to a unit conversion error, as the Planck's constant used was in eV-s instead of SI units. A suggestion is made to change the units to SI and then convert to eV for a more direct approach.
  • #1
Calmeir
3
0
Apologies, but I have another photoelectron question. In this one I get a result that seems reasonable, however it does not show up on my list of work functions that I have available to choose from. The problem is:

A photoelectric-effect experiment finds a stopping potential of 1.93V when light of 200nm is used to illuminate the cathode. What is the cathode made of?

I initially thought this would be an easy problem as Vstop = (hf - Eo) / e

I have all the values except Eo which is what I am trying to solve for.

Vstop = 1.93 V
h = 4.14x10^-15 eV
f = 3x10^8/200x10^-9 = 1.5x10^15
e = 1.6x10^-19

So, I plug all of the values into the equation and solve for Eo

1.93 = ((4.14x10^-15)(1.5x10^15)-Eo)/1.6x10^-19

The resulting value of Eo was 6.21
This seems valid, except the list I have to choose from is:

Potassium: 2.3
Sodium: 2.75
Aluminum: 4.28
Tungsten: 4.55
Copper: 4.65
Iron: 4.7
Gold: 5.1

Likely I am having the same problem as my previous question and not seeing a simple unit difference. Anyhow, I do appreciate your help.
 
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  • #2
Calmeir said:
h = 4.14x10^-15 eV

That is not Planck's constant in SI units. In fact h is not expressed in eV in any system of units.
 
  • #3
Tom Mattson said:
That is not Planck's constant in SI units. In fact h is not expressed in eV in any system of units.

Tom is right and wrong. The problem IS units, but the Planck's constant being used by Calmeir is in eV-s, which is correct. The problem is that he is already working in eV, and so needs to drop the "1.6x10^-19" at the end of his equation.

I reworked it and got e=4.28 eV.

-Dan
 
  • #4
topsquark said:
Tom is right and wrong.

No, Tom is right and right! :biggrin:

The problem IS units, but the Planck's constant being used by Calmeir is in eV-s, which is correct.

While the numerical value of h that he used corresponds to h in eV-s, he did report the units in eV, which is wrong.

The problem is that he is already working in eV, and so needs to drop the "1.6x10^-19" at the end of his equation.

That's one fix, but I was hinting at a different one. Since he put all of his other quantities in SI units I was trying to get him to put h in SI units as well. He would have obtained E0 in Joules and then convert to eV. Changing h to eV-s and leaving the electron charge as e is certainly more direct though...
 

FAQ: Finding the work function using stop potential

What is the work function?

The work function is the minimum amount of energy required to remove an electron from the surface of a material. It is also known as the minimum threshold energy or the binding energy.

How is the work function measured?

The work function can be measured by using a device called a photoelectric effect apparatus, which consists of a light source, a metal surface, and an adjustable voltage source. The voltage is gradually increased until the photoelectric current stops, which indicates that the kinetic energy of the emitted electrons is zero. The voltage at which this happens is known as the stop potential and is equal to the work function.

Why is the work function important?

The work function is an important property of a material as it determines its ability to emit electrons when exposed to light. It is also used to calculate other properties such as the Fermi energy and the Fermi level of a material.

What factors affect the work function?

The work function of a material is affected by its composition, surface conditions, and temperature. It also depends on the frequency and intensity of the incident light.

Can the work function be changed?

Yes, the work function of a material can be changed by altering its surface conditions, such as by applying a coating or changing the temperature. It can also be changed by using a process called doping, where impurities are intentionally added to the material to alter its electronic properties.

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