Fluid flow and characteristics in a vacuum (Cryophorus)

In summary: As this happens the water vapour will travel the tube and enter the cold container where it will condense back to water provided the vacuum is not sufficient to boil the water in the cold container. The cycle should continue until the water is evaporated or temperatures equalise provided there is no leaks and the vacuum holds.In summary, the conversation discusses the concept of a cryophorus, which is a glass device used to transfer heat and create a vacuum. The specific scenario being discussed involves using 40 degree water to create a vacuum by boiling and condensing the water vapor in a closed system. The process is described as a potential method for water desalination, but further details and components are needed to accurately calculate the mass flow
  • #36
russ_watters said:
Nobody has suggested that the idea won't work, and I gave you an approach and offered to walk you through it, but you didn't seem interested. If you really want help, you'll need to put some more focused effort into it and lose the attitude/actually accept the help that is being offered. Your current tack getting you nowhere.

The equations/math of this is really easy. You're just looking for the heat of vaporization/condensation (read from a steam table) on each end, times the flow rate, and the pumping power is volumetric flow rate times pressure (more complicated if you are pumping/compressing a vapor though). The work here is in defining/designing the process steps. I could pick them for you, but then this would be my design, not yours.

So, step/process 1: You said you have/want to use 40 C water and want to distil 1000 liters. Look up the pressure and the heat of vaporization in a steam table. Multiple the heat of vaporization by the mass of water. Also, specify the time. Then divide the energy by time to get the rate at which you need to add heat to boil your 1,000 L.
Ok. I’ll set a few parameters so we can work through it.
1000 ltrs at 20 degrees celcius needs 23.244 kilowatts to reach 40 degrees celcius in 1 hour. Pressure requirement is 55.3 torr Or 27.7473 in hg .
is mass of water equal to 40,000?..

further parameter will be set at cold side temp of 1 degree so pressure will be 4.9 torr or 29.7318 in hg.
 
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  • #37
Tom.G said:
I think your limiting factors will be the evaporation rate and the condensation rate that you can reach, not the boundary layer of the water vapor to the walls of the plumbing; after all, you can use larger diameter plumbing. I understand there are tables for pipe size versus pressure versus flow rate, but I don't have any details.

Counterflow shell-and-tube heat exchangers seem the best bet.

For a cold source, there is always a cooling tower, but it needs a pump; and moderately clean makeup water or frequent cleaning/maintenance. Perhaps there is enough pressure & flow from the artesian well to supply that pumping energy.

Cheers,
Tom
Yes the vaporisation rate has me lost. I’m thinking that will depend on how quickly the vapour above the fluid will be moved away allowing more vaporisation to occur. As others have said as the water turns to vapour the pressure immediately above the water rises and stops the vaporisation process.
The condensation process has me intrigued. I have heard many times that things lose heat in a vacuum. Does this mean that the cold side will continue getting colder if there is no outside source of heat.
the boundary layer seems to be sticking point here. Calculating jet engine mass flows means calculations allow for the boundary layer Otherwise you end up with stalled flow or expansion and therefore cooling of gases in the wrong areas. I’m thinking it’s the same here. If the boundary layer is not known and the calcutions are done just on mass flow and velocity the pipes may be too small and the vapour won’t move quick enough to allow the most efficient vaporisation in the hot side and if the pipes are to big the vapour will have room to expand and condense too early.
 
  • #38
Ripcrow said:
Ok. I’ll set a few parameters so we can work through it.
1000 ltrs at 20 degrees celcius needs 23.244 kilowatts to reach 40 degrees celcius in 1 hour.
Ok, I didn't know about the 20 C to 40 C part of the process, but that is the correct answer.
Pressure requirement is 55.3 torr Or 27.7473 in hg.
Your value in torr is right, the value in inches hg is expressed wrong. It's 27.7473 inches of vacuum, and at this point it would be better to just keep it in absolute pressure; it is 2.18". Also, bar is a more common unit and it is weird to mix American and SI units.
is mass of water equal to 40,000?..
You said above that you wanted to process 1000 liters, and used the mass correctly in a calculation; 1000 liters is 1000 kg.
further parameter will be set at cold side temp of 1 degree so pressure will be 4.9 torr or 29.7318 in hg.
We'll come back to that later. You haven't done the calculation I asked/described in post #34, and we need it.
Ripcrow said:
Yes the vaporisation rate has me lost.
You've specified the vaporization rate: it is 1000 kg/hr. Now you need to calculate the energy/power input requirement to make that happen, per my description in post #34. Once you know how much energy/power you need, then you can decide how to do the heating.
I’m thinking that will depend on how quickly the vapour above the fluid will be moved away allowing more vaporisation to occur. As others have said as the water turns to vapour the pressure immediately above the water rises and stops the vaporisation process.
You're trying to design a continuous, steady process here. The pressure is whatever you want it to be, and it's constant -- you have to design the device physically to make what you want to happen, happen. But first, you need to design/describe the device/process mathematically. I'm trying to walk you though the calculations. Please do the calculation I asked/described in post #34.

Also; I'm not sure, but the vibe I'm getting from these last few sentences is that you may have a misunderstanding of how boiling works. The process in your device is basically the same as boiling a pot of water on your stove. You apply heat, and the water heats up and boils. The faster you apply heat, the faster it boils. You need to calculate how fast you need to apply heat to boil 1000 kg in in hour. That's the calculation I described for you in post #34.
 
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  • #39
russ_watters said:
Ok, I didn't know about the 20 C to 40 C part of the process, but that is the correct answer.

Your value in torr is right, the value in inches hg is expressed wrong. It's 27.7473 inches of vacuum, and at this point it would be better to just keep it in absolute pressure; it is 2.18". Also, bar is a more common unit and it is weird to mix American and SI units.

You said above that you wanted to process 1000 liters, and used the mass correctly in a calculation; 1000 liters is 1000 kg.

We'll come back to that later. You haven't done the calculation I asked/described in post #34, and we need it.
You've specified the vaporization rate: it is 1000 kg/hr. Now you need to calculate the energy/power input requirement to make that happen, per my description in post #34. Once you know how much energy/power you need, then you can decide how to do the heating.

You're trying to design a continuous, steady process here. The pressure is whatever you want it to be, and it's constant -- you have to design the device physically to make what you want to happen, happen. But first, you need to design/describe the device/process mathematically. I'm trying to walk you though the calculations. Please do the calculation I asked/described in post #34.

Also; I'm not sure, but the vibe I'm getting from these last few sentences is that you may have a misunderstanding of how boiling works. The process in your device is basically the same as boiling a pot of water on your stove. You apply heat, and the water heats up and boils. The faster you apply heat, the faster it boils. You need to calculate how fast you need to apply heat to boil 1000 kg in in hour. That's the calculation I described for you in post #34.
You asked me to calculate the mass of water multiplied by the heat of vaporisation. 1000 litres of water equals 1000 kg multiplied by 40 degrees. I calculated energy input required to reach 40 degrees celcius assuming that the water would have a starting temp Therefore 20 degrees celcius.
The cold side parameter is defined for this equation now. As you said I needed parameters to Work the answer out. Using the right units is definitely vital and its Something I wondered about. When I was taught the right way to calculate jet flows it was an older person who swapped from imperial to metric which didn’t bother me as I grew up with my father and grandfather doing the same.
The system will still be continuous. If you imagine a hot tank and a cold tank connected by a pipe with a tap between them. There can be two different pressures. One of my quirks is to assume that most people think outside the box. I assumed that when people viewed my question they would think about such a system and work out it needed more then temperature to drive the flow from the hot side to cold side. It needs pressure change also therefore a tap or valve to control flow. I only realized last night I hadn’t described this system needing a valve and that it maybe the cause of the negative comments and misunderstanding.

An example of starting the system would be draw a vacuum in the hot side and draw a greater amount of vacuum in the cold side. Heat the water and then open the valve slowly. Provided the rate of evaporation is equal to the amount of condensation. The valve will maintain the pressure difference between the sides. The pressure difference is what causes velocity which is why I asked how to calculate the velocity in a vacuum. The greater the speed at which the water vapour can be moved from the hot to the cold side the less vapour there is affecting the pressure in the hot side which affects vaporisation rates
 
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  • #40
Ripcrow said:
You asked me to calculate the mass of water multiplied by the heat of vaporisation. 1000 litres of water equals 1000 kg multiplied by 40 degrees. I calculated energy input required to reach 40 degrees celcius assuming that the water would have a starting temp Therefore 20 degrees celcius.
No, "heat of vaporization" is the amount of energy (heat) required to turn liquid water into vapor, at a specific temperature and pressure. You take water at 40 C and 55 torr and turn it into vapor at 40 C and 55 torr. It's the "enthalpy -- evaporated" number in a steam table like this one:
https://www.efunda.com/materials/water/steamtable_sat.cfm
 
  • #41
russ_watters said:
No, "heat of vaporization" is the amount of energy (heat) required to turn liquid water into vapor, at a specific temperature and pressure. You take water at 40 C and 55 torr and turn it into vapor at 40 C and 55 torr. It's the "enthalpy -- evaporated" number in a steam table like this one:
https://www.efunda.com/materials/water/steamtable_sat.cfm
Hopefully I have this right now. 2,406,100 kJ per hour to vaporise 1000 kg of water
 
  • #42
Ripcrow said:
Hopefully I have this right now. 2,406,100 kJ per hour to vaporise 1000 kg of water
Yes. And in terms of power, that's 668 kW.
If you imagine a hot tank and a cold tank connected by a pipe with a tap between them. There can be two different pressures... I only realized last night I hadn’t described this system needing a valve...
I assumed you would want a valve between the tanks. It's a good idea because it is adjustable and you don't have to be as precise about sizing the pipe (which is very difficult).
[previous post] ...using a cooling tank to supply the cold side at about 30 degrees Celsius the tables suggest the example is valid Provided the vacuum is kept above the boiling point of 30 degrees Celsius water.
So, if the condenser operates at 30C, repeat the exercise you just did to find the pressure and the heat removal requirement. Then you'll have the process fully defined and we can start figuring out how to create a device to make it happen.

A preview:
Hopefully you recognize at this point that the heating and cooling requirements of this process are enormous, and have put some thought into how you want to do the heating and cooling...
 
  • #43
Yes the Energy requirement surprised me. Is total energy required equal to the heating energy plus the enthalpy energy therefore total energy to heat and vaporise 1000 litres of 40 degree celcius water is 691 kw. Or does the enthalpy value equal the total energy.
To heat 1000 litres of water from 20 degrees to 100 degrees celcius in 1 hour at atmospheric pressure takes 93.33 kw and the enthalpy value is 626 kw.
The energy requirements between the two don’t seem logical given the 60 degree temperature difference and the pressure difference. From what I read atmospheric pressure dictated how much heat was needed to cause phase changes in water. But it doesn’t seem linear with these numbers.
 
  • #44
russ_watters said:
Yes. And in terms of power, that's 668 kW.

I assumed you would want a valve between the tanks. It's a good idea because it is adjustable and you don't have to be as precise about sizing the pipe (which is very difficult).

So, if the condenser operates at 30C, repeat the exercise you just did to find the pressure and the heat removal requirement. Then you'll have the process fully defined and we can start figuring out how to create a device to make it happen.

A preview:
Hopefully you recognize at this point that the heating and cooling requirements of this process are enormous, and have put some thought into how you want to do the heating and cooling...
Tried the cooling calculation. Used the efunda link and found the evaporation energy and pressure required but something is wrong. It worked out at 675 kw which is more then what is required to evaporate at higher temps. I assumed that the heat of vaporisation had to be removed from the vapour to cause condensation so the maths would have been the heat of vaporisation of water at 40 degrees celcius minus the heat of vaporisation of water at 30 degrees Celsius and the answer would have represented the amount of heat needed to be removed. At this stage I have 668 -675= -7 kw. I adjusted the vaporisation pressure in the calculator so the pressure was the same as the 40 degree water and it still worked out at 668 kw which would indicate that the Heat values are the same.
 
  • #45
Ok I found the right equations. Bernoulli gives flow rates and I found the reynolds number and calculated the boundary layer of the fluid.
Some Numbers I have are a mass flow rate 0.0129 kg per second at velocity of 512 metres per second. This is using a pressure difference of 6719 pascal and a pipe diameter of 25 mm ignoring boundary layer. Thanks to those who clarified the power requirement to vaporise the water per second in the other thread. I have a kinetic energy output of 1690 joules and require 31kw to vaporise the water per second.
This is what got me interested in the equations. It’s a long video (30 mins ) but it was an interesting concept. According to the maths here this might work but there is very little efficiency in the system. Am I missing something
 
  • #46
Wrong video.
 
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