Gamma iron even after it cooled down

In summary, the 300 series of stainless steel is an austenitic type of steel, meaning that the iron is in its gamma allotrope. The nickel in the steel, which has a cubic close packed crystal structure, tends to stabilize the gamma phase of iron, while chromium, which has a body centred cubic structure, stabilizes the alpha or ferrite phase. This is a common feature in alloy systems and is related to the relative sizes and chemical similarities of the host and solute atoms.
  • #1
caters
229
10
The 300 series of stainless steel is austenitic meaning that the iron in the steel is gamma iron. This means that if it is magnetic it is only the weak magnetism from the nickel.

I read the wikipedia article on allotropes of iron and it says that gamma iron occurs when the iron is heated to 1000K or 730 degrees C. That is the curie temperature for iron.

But how does the nickel in the steel keep the iron in its gamma allotrope unlike ferric stainless steel where there is only chromium, iron, and carbon and it is in its alpha allotrope.
 
Engineering news on Phys.org
  • #2
As a rule of thumb, an alloying element in solid solution will tend to modify its host to its own crystal structure. In this case, pure nickel is cubic close packed and tends to stabilise the cubic close packed phase in iron ie the gamma phase.

The size of the effect is related to the the relative size of the host and solute atoms as well as their chemical similarity.

Similarly, pure chromium is body centred cubic and tends to stabilise the body centred cubic phase of iron ie alpha or ferrite. Above about 15% Cr, there is no gamma phase in an iron-chromium alloy with no nickel.

That's by no means a formally correct answer to your question nor an explanation for why this happens but it's a common feature of alloy systems
 

FAQ: Gamma iron even after it cooled down

What is gamma iron?

Gamma iron is a form of iron that exists at high temperatures, typically above 912 degrees Celsius. It has a face-centered cubic crystal structure and is a non-magnetic phase of iron.

What happens to gamma iron after it cools down?

After cooling down below 912 degrees Celsius, gamma iron transforms into a different phase of iron, such as alpha iron or delta iron, depending on the cooling rate and composition of the iron.

Why does gamma iron sometimes remain even after it has cooled down?

This can occur when the cooling rate is slow, which allows for some of the gamma iron to remain in the structure. Additionally, the presence of certain elements, such as nickel or chromium, can stabilize the gamma iron phase at lower temperatures.

What are the properties of gamma iron at room temperature?

At room temperature, gamma iron is typically unstable and will transform into a more stable form of iron. It has a high ductility and is relatively soft compared to other phases of iron.

How is the presence of gamma iron after cooling down significant in material science?

The presence of gamma iron after cooling down can affect the mechanical and physical properties of the material. It can also indicate the cooling rate and composition of the iron, which can be useful in understanding the manufacturing process and predicting the material's behavior in different environments.

Similar threads

Replies
1
Views
718
Replies
10
Views
927
Replies
17
Views
26K
Replies
1
Views
2K
Replies
1
Views
550
Replies
4
Views
2K
Replies
5
Views
3K
Replies
1
Views
2K
Replies
21
Views
2K
Back
Top