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Why isn't this unitary? You just have the usual S-matrix of QED to describe this process, and that's unitary.
To say that in a single measurement, the outcome is random is not to have explained the outcome.vanhees71 said:QT explains what happens in a single measurement, according to what's observed. The outcome of the measurement is in general random,
If you only observe a single measurement, you cannot observe whether the outcome is random. Instead you just observe a number.vanhees71 said:and that's what's observed (e.g., in the paradigmatic double-slit experiment with single particles or photons).
The field always exists. Observed is a state of the electromagnetic field containing a superposition of 0 and 1 photon. After the observation this state collapsed to the 0-photon state.vanhees71 said:But afterwards there's no photon. The usual collapse assumption means that after the measurement the photon's state is in an eigenstate of the measured observable. However, in this case you have the QED vacuum and no single-photon state.
Even heralded photons have a significant nondetection rate, hence are superpositions of 0 and 1 particle states. In any case, photons are part of QED, hence photon states are actually states of the electromagnetic fields, and not states from a 2-dimensional helicity space.vanhees71 said:Nowadays there are true one-photon preparations ("heralded photons"), and thus it's no longer an "informal statement".
Like all of quantum mechanics, since the unsimplified theory is an interacting relativistic quantum field theory.vanhees71 said:The collapse hypothesis is at best an oversimplification.
Whether a photon has been absorbed is immaterial to the properties of the state.vanhees71 said:if you have a coherent state (maybe of low intensity such as to have an average number of photons below 1): The measurement of the photon doesn't prepare a single-photon state as claimed by the collapse postulate, because this measured photon has been absorbed.
The S-matrix describes the probabilities of various possible final states given an initial state: in other words, the unitary process that the S-matrix describes starts from the initial state and gives you a probability-weighted superposition of final states.vanhees71 said:Why isn't this unitary? You just have the usual S-matrix of QED to describe this process, and that's unitary.
Yes, but it does not happen with 100% probability. Nor is it guaranteed to happen with one particular atom. The unitary process involved has an amplitude for no absorption, and amplitudes for absorption by each of multiple atoms. The unitary process does not tell you which of those possibilities will actually happen. But the state transition you wrote down was to one particular outcome. If you are claiming that that one particular outcome is the result of a unitary process, I challenge you to write down the explicit unitary operator that realizes it.vanhees71 said:Photoabsorption is the prozess photon+atom -> excited atom.
None of these treatments answer the question I posed above. All of them produce predictions of probabilities using unitary operators. None of them predict the one particular outcome that actually happens using a unitary operator.vanhees71 said:The semicpassical treatment can be found in many QM textbooks as application of time-dependent 1st-order perturbation theory, e.g., in Sakurai or Landau-Lifshitz vol. 3.
Since we are in the interpretations forum, I will point out that there is an interpretation of QM that does say that the dynamics is always unitary: the MWI. But in the MWI, a process like the one you describe does not have a single outcome. All possible outcomes occur, each with their appropriate amplitudes. The final wave function is an entangled superposition of all of them. But that isn't what you wrote down.vanhees71 said:It is of course such a process.
vanhees71 said:Of course they have well-defined quantum states, i.e., the reduced statistical operators, who follow some kind of master equation rather than a unitary time evolution.
If we denote the unitary S-matrix operator with ##S##, the process is not unitary in the sense that ##|{\rm excited\, atom} \rangle \neq S |{\rm process\; photon+atom \rangle}##.vanhees71 said:It is of course such a process. Photoabsorption is the prozess photon+atom -> excited atom. The semicpassical treatment can be found in many QM textbooks as application of time-dependent 1st-order perturbation theory, e.g., in Sakurai or Landau-Lifshitz vol. 3.
You keep making this assertion without ever actually addressing the repeated responses about it. For example, see post #46 by @Demystifier. If you are claiming that the equation he wrote down in that post is wrong, i.e., that ##\ket{\text{excited atom}} = S \ket{\text{process photon plus atom}}##, then please show your work. Everyone else except you appears to recognize that what you actually get from ##S \ket{\text{process photon plus atom}}## is a superposition of things like ##\ket{\text{atom 1 excited}}##, ##\ket{\text{atom 2 excited}}##, etc., as well as ##\ket{\text{no atom excited, photon not absorbed}}##. That superposition is not the same as ##\ket{\text{excited atom}}## for any specific atom. You cannot simply keep ignoring this and make the assertion you are making.vanhees71 said:Of course it is!
Yes, but that probability-weighted sum of alternatives is not the same as any particular alternative. But we only observe one particular alternative as the actual result. You have repeatedly claimed that we can somehow get just one particular alternative as the actual result from a unitary process; yet you contradict yourself by admitting that the S-matrix gives only a probability-weighted sum of alternatives. You can't have it both ways.vanhees71 said:All this is included in the unitary S-matrix, which describes the corresponding transition-probability rates as its matrix elements squared.
Yes, you did. That is what the transition you wrote down in post #11 is claiming, whether you want to admit it or not.vanhees71 said:Of course, I didn't claim that,
What you wrote down in post #11 wasn't a probability. It was a definite transition between definite states.vanhees71 said:I only claim that these probability (rates) is all that is relevant to describe all these experiments
Apparently you couldn't keep this up for very long. You responded to @A. Neumaier only 24 minutes after you posted what I quoted above, and that subthread has now gone on for three days, at which point we are where I described in my last post.vanhees71 said:I try not to participate anymore in these discussions.