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my_wan
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DaleSpam said:What do you mean by this? Specifically, "no mechanical compression".
I'm referring to adiabatic compression of the gas itself. When you mechanically compress a gas you are adding external energy from the outside. This means not just that the gas volume has been reduced, but that the mean velocity of the particles has likewise been increased.
Hence mechanical compression non-adiabatic involves 2 forms of decreased entropy for the system in question, often treated as just one. One corresponding to the spatial component, container size, and the other a time component, clock time or velocity component of the molecules. A non-adiabatic mechanically compressed gas will then over time lose the increased mean velocity to the environment through heat, leaving behind only the energy from the first adiabatic form to be permanently contained. We lose most of our inefficiencies in heat engines as a result of the second form, particles velocity reduction though heat loss.
An Adiabatic compression only involves the first form such that the mean velocity remains unchanged. It is this first form only, disregarding stacked weight such as Earths center, that the gravitational contraction of a gas entails. The covariant form of the gravitational potential entails that what one person sees as a particle velocity induced entropy reduction another will say no, it appears to be the result a volume reduction. This pair of observables is also covariant with a second set of observables. That is: One will say the mass of the particles apparently increased while another says it remained constant. Yet the quantitative Δstate defined to be a result anyone of these state variables doesn't leave any room for defining any Δstate in terms of any other state variable. Though it makes no difference which state variable you choose.
@PAllen
Seeing how rampant this mixing of these 2 components of Δentropic state is I think I need to be paying a lot more attention to the literature on this topic. I will take my time to go over those documents you linked in detail, and do some document searching on the matter myself. It appears there might possibly even be endemic incongruencies going back to at least Poincare's proof of reversibility.
Consider the claim that Poincare's reversibility proof only applies to enclosed systems. When a gas canister divided between a vacuum and a gas which is then released into the vacuum, Poincare calculated the odds of a spontaneous reversal. This is inherently an adiabatic expansion. Now it is said that reversibility is contingent upon this system being enclosed. But what happens when we let it absorb heat from an external environment keeping the individual particles strictly segregated? If we take the initial state in terms of positions only this increased heat, from a purely mechanical point of view, merely increases the rate at which possible positions are transitioned through. Hence, on its surface, an increased velocity appears to entail that since the position states that occur per unit time has increased then the odds of a reversal occurring (in terms of position space only) in some set unit of time (however large) has increased.
There's another possible issue with Poincare's probabilities. In effect it takes the number of possible equivalent resulting states as a ratio of the number of possible initial states. Yet a direct transition from state A to state B cannot mechanistically involve a single state transition, rather a large number of transitions each with separable odds. In other words it fails to account for the systems mechanistic constraints due to the fact that no two particle can posses the same position moment at the same time. So just because you have odds X of any particle possessing position X does not entail the physical possibility of any two or more particles actually possessing moment state X.
An analogy with dice says that the odds of rolling snake eyes is X. Roll any pair of dice and you have X^2 probability of rolling a pair of snake eyes. Only in the gas law case if the first dice is snake eyes the probability of snake eyes on the second dice goes to zero. So Poincare's reversibility odds is contingent upon how many equal length paths are either non-interfered with by other particles, or contingent upon mutual mechanistic interference, that are not destroyed by even a single rogue particle. A simple count of position state ratios is likely vastly underestimating the number of possible paths to get from state A to state B on simple mechanical interference in the transition sequence. Perhaps infinitely underestimated, given the number of individual states and interactions (collisions) required to actually get from state A to state B. Suppose the distance between two ideal particle during some point in expansion is infinitesimal. What then when a reversal involves only infinitesimal variations? Merely assuming the mechanistic path constraints are linear with the differing ratios of resulting possible states separated by time and space does not constitute a proof.
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