Heat of Formation: Is Q Always Positive?

In summary, the conversation discusses the use of the equation Q=ms∆T and whether the heat is always positive. The homework equation for heat of formation is q/mol and the moles used in the lab are positive. The person is working on an energy of magnesium lab and the largest amount of heat of formation they obtained is 386.1 kJ/mol, which is lower than the theoretical value of -461.96 kJ/mol. The variables given are m=100g and s=4.184 J/g Celsius, and the only way for the energy to be negative is if the temperature change is negative, meaning the solution cooled down. The conversation also briefly touches on the definition of exothermic and endothermic
  • #1
angelababyy
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Homework Statement


When using the equation, Q=ms∆T, is the heat always positive?

Homework Equations


heat of formation = q/mol (but of course the moles used in this lab is a positive number)

The Attempt at a Solution


I'm working on the energy of magnesium lab where magnesium ribbon contacts and reacts with hydrochloric acid. The theoretical heat of formation is -461.96 kJ/mol, but I got 386.1 kJ/mol of Mg as the largest amount (I'm turning in three trials).
m & s are given as 100 g and 4.184 J/g Celsius respectively. Therefore, the only variable that would make the energy negative would be the temperature change. However, if the temperature change was negative that means that the temperature cooled down. I don't think an exothermic reaction would have the solution cool down.
 
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  • #2
What's the definition of exothermic?

(Hint: How does exo- differ from endo-thermic?)Also, since you're doing this in a lab - aren't you measuring the temperature of the solution?
 

Related to Heat of Formation: Is Q Always Positive?

1. What is heat of formation?

Heat of formation is a thermodynamic concept that refers to the amount of heat released or absorbed when a compound is formed from its constituent elements under standard conditions.

2. How is heat of formation measured?

Heat of formation is measured in units of energy per mole (kJ/mol or kcal/mol) and is typically determined experimentally using calorimetry.

3. Is Q always positive for heat of formation?

No, Q (heat) can be either positive or negative for heat of formation. A positive Q indicates that the reaction is exothermic, meaning heat is released during the formation of the compound. A negative Q indicates an endothermic reaction, meaning heat is absorbed during formation.

4. Can Q ever be zero for heat of formation?

Yes, Q can be zero for heat of formation if the reaction is carried out under conditions where there is no change in temperature or pressure.

5. What factors affect the heat of formation?

The heat of formation is affected by the elements and compounds involved in the reaction, as well as the temperature and pressure at which the reaction takes place. Additionally, the physical state (solid, liquid, gas) of the reactants and products can also impact the heat of formation.

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