Heat of vaporization/final temperature

In summary: So when the alcohol is evaporated and temperature is lowered, it results in a decrease in energy for the block of Al. This is why you should subtract in this case.
  • #1
luffyiskind
2
0

Homework Statement


Suppose that 2.05g of rubbing alcohol (60.90g/mol) evaporates from the surface of a 40.0g aluminum block. If the aluminum block is initially at 25 C, what is the final temp of the block after the vaporization of the alcohol?

Heat of vaporization for alcohol: 45.4 kJ/mol
Heat capacity of Al : 0.903 j/g*C

Homework Equations



q=m cs T

The Attempt at a Solution



I finished the problem but I got it wrong. Here are my steps.

Step 1: 2.05g alcohol x 1 mol / 60.09g x 45.4 kJ / 1 mol = 1.55 kJ

I did this step to find out how much energy was needed to vaporize the alcohol.

Step 2: 1550 J = 40 g x 0.903 j/g*c x delta T

solved for delta T and got 42.9 C

since 1.55 kJ was needed, this energy was taken from Al

Step 3: I added 42.9 C to the original 25 C to get 67.9 C

--------------------------------------------------------------------------------------
What did I do wrong?
 
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  • #2
luffyiskind said:
since 1.55 kJ was needed, this energy was taken from Al

Step 3: I added 42.9 C to the original 25 C to get 67.9 C

--------------------------------------------------------------------------------------
What did I do wrong?


Reread these two steps over and over and over and over until you realize your mistake.

Hint:
" taken from Al"
taken
 
  • #3
So I should have subtracted right? If so, I knew it! Dx
 
  • #4
luffyiskind said:
So I should have subtracted right? If so, I knew it! Dx

Correct,
Remember any temperature above 0 K for an object technically has energy.
 
  • #5


Your calculations and approach seem correct. However, in step 2, you have used 1.55 kJ instead of 1.55 kJ/mol. This may have affected your final answer. Also, make sure to use the correct units throughout your calculations (kJ instead of J).
 

FAQ: Heat of vaporization/final temperature

What is heat of vaporization?

The heat of vaporization is the amount of heat energy required to convert a substance from its liquid state to its gas state at a constant temperature and pressure.

How is heat of vaporization measured?

Heat of vaporization is typically measured in units of joules per mole (J/mol) or kilojoules per mole (kJ/mol), which reflect the amount of energy required to vaporize one mole of a substance.

What factors affect the heat of vaporization?

The heat of vaporization of a substance is dependent on several factors, including the temperature and pressure at which vaporization occurs, the type of substance, and the intermolecular forces between the molecules of the substance.

How does heat of vaporization affect the final temperature of a substance?

The heat of vaporization can significantly impact the final temperature of a substance. As the substance absorbs heat energy during vaporization, the temperature of the substance will remain constant until all of the liquid has been converted to gas. Once this occurs, the temperature will begin to rise again.

Can the heat of vaporization be calculated?

Yes, the heat of vaporization can be calculated using the formula q = mL, where q is the heat energy, m is the mass of the substance, and L is the heat of vaporization. This formula is based on the assumption that the substance is undergoing a phase change from liquid to gas at a constant temperature and pressure.

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