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lightarrow
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Sorry if this question has already been asked but I didn't find it in this forum.
Which is the acidity constant of water in itself?
Ka of a weak acid HA in water dilute solution is defined considering the aequilibrium:
HA + H2O ↔ H3O+ + A- (1)
then:
Ka(HA) = [H3O+]⋅[A-] / [HA]
this, for what I know, because in dilute solution [H2O] is constant and can then be "incorporated" in the aequilibrium constant Keq:
Keq. = [H3O+]⋅[A-] / [HA]⋅[H2O]
Ka = Keq⋅[H2O] = constant1⋅constant2.
So, my "natural" guess to how Ka(H2O) can be defined, would be to replace HA with H2O in the aequilibrium (1) and then as follow.
Let's consider the aequilibrium:
H2O + H2O ↔ H3O+ + OH-
then:
Ka(H2O) = [H3O+]⋅[OH-] / [H2O] = Kw/[H2O] = 10-14/(1000/18) = 10-15.7.
But there is a problem: can I here really consider the acid H2O as in "dilute solution"? It seems meaningless...
How would you define the acidity constant of water in itself, in case is definible?
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lightarrow
Which is the acidity constant of water in itself?
Ka of a weak acid HA in water dilute solution is defined considering the aequilibrium:
HA + H2O ↔ H3O+ + A- (1)
then:
Ka(HA) = [H3O+]⋅[A-] / [HA]
this, for what I know, because in dilute solution [H2O] is constant and can then be "incorporated" in the aequilibrium constant Keq:
Keq. = [H3O+]⋅[A-] / [HA]⋅[H2O]
Ka = Keq⋅[H2O] = constant1⋅constant2.
So, my "natural" guess to how Ka(H2O) can be defined, would be to replace HA with H2O in the aequilibrium (1) and then as follow.
Let's consider the aequilibrium:
H2O + H2O ↔ H3O+ + OH-
then:
Ka(H2O) = [H3O+]⋅[OH-] / [H2O] = Kw/[H2O] = 10-14/(1000/18) = 10-15.7.
But there is a problem: can I here really consider the acid H2O as in "dilute solution"? It seems meaningless...
How would you define the acidity constant of water in itself, in case is definible?
--
lightarrow