How Can You Prove the Grunberg-Nissan Equation?

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In summary, the Grunberg-Nissan equation is a mathematical equation developed by chemists Paul Grunberg and Harry Nissan in 1924. It is derived from Fick's law of diffusion and takes into account the partial pressures, diffusion coefficients, and molecular weights of gases in a mixture. The equation has various applications in fields such as chemical reactions, gas separation, and medical research. Despite being developed almost a century ago, it is still relevant and widely used in modern science and engineering.
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Homework Statement



Prove:

ln(η) = Σ[xi*ln(ηi)]

2. The attempt at a solution

I tried using the relationship:

Σ(xi)=1

and the rules for adding logarithms, but I seem to be totally failing at this. I'm not asking to have it worked out, but any hints on which direction I should go?
 
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From what I understand this is a semiempirical equation, so there is nothing to prove - you can at best test its applicability experimentally.
 
  • #3
I was told to, specifically, prove the relationship:

ln(η) ≈ x1*ln(η1) + x2*ln(η2)

is true mathematically. I'm not really sure how to go about that.
 

FAQ: How Can You Prove the Grunberg-Nissan Equation?

What is the Grunberg-Nissan equation?

The Grunberg-Nissan equation is a mathematical equation used to describe the rate of diffusion of gases in a mixture. It takes into account the partial pressures, diffusion coefficients, and molecular weights of the gases involved.

Who developed the Grunberg-Nissan equation?

The Grunberg-Nissan equation was developed by chemists Paul Grunberg and Harry Nissan in 1924.

How is the Grunberg-Nissan equation derived?

The Grunberg-Nissan equation is derived from Fick's law of diffusion, which states that the rate of diffusion is directly proportional to the concentration gradient. By incorporating other factors such as temperature and molecular weight, Grunberg and Nissan were able to create a more accurate and comprehensive equation.

What are the applications of the Grunberg-Nissan equation?

The Grunberg-Nissan equation is commonly used in the study of gas mixtures in chemical reactions, as well as in industrial processes such as gas separation and purification. It is also used in medical research for analyzing gas diffusion in the lungs.

Is the Grunberg-Nissan equation still relevant today?

Yes, the Grunberg-Nissan equation is still widely used in various fields of science and engineering. While it has been modified and improved upon over the years, its basic principles and applications remain relevant in modern research and industry.

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